Concentration dependent Raman and IR study on salicylaldehyde in binary mixtures
A vibrational spectroscopic study of binary mixtures of salicylaldehyde (SA) in three different solvents (polar and nonpolar) is presented. The vibrational modes ν(CO), hydroxyl stretching mode (COH) and aldehydic (CH) stretching vibration were analyzed. Changes in wavenumber position and full wi...
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| Veröffentlicht in: | Journal of Raman spectroscopy 2007-12, Vol.38 (12), p.1639-1645 |
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| container_title | Journal of Raman spectroscopy |
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| creator | Fathima, A. Anis Umadevi, M. Ramachandran, M. S. Ramakrishnan, V. |
| description | A vibrational spectroscopic study of binary mixtures of salicylaldehyde (SA) in three different solvents (polar and nonpolar) is presented. The vibrational modes ν(CO), hydroxyl stretching mode (COH) and aldehydic (CH) stretching vibration were analyzed. Changes in wavenumber position and full width half maximum have been explained for neat as well as binary mixtures with different volume fractions of the reference system, SA, in terms of inter‐ and intramolecular hydrogen bonding. The IR spectra of these mixtures have also been taken and compared with the Raman data. The spectral changes have been well explained using the concentration fluctuation model and solute–solvent interaction. Copyright © 2007 John Wiley & Sons, Ltd. |
| doi_str_mv | 10.1002/jrs.1883 |
| format | Article |
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Anis ; Umadevi, M. ; Ramachandran, M. S. ; Ramakrishnan, V.</creator><creatorcontrib>Fathima, A. Anis ; Umadevi, M. ; Ramachandran, M. S. ; Ramakrishnan, V.</creatorcontrib><description>A vibrational spectroscopic study of binary mixtures of salicylaldehyde (SA) in three different solvents (polar and nonpolar) is presented. The vibrational modes ν(CO), hydroxyl stretching mode (COH) and aldehydic (CH) stretching vibration were analyzed. Changes in wavenumber position and full width half maximum have been explained for neat as well as binary mixtures with different volume fractions of the reference system, SA, in terms of inter‐ and intramolecular hydrogen bonding. The IR spectra of these mixtures have also been taken and compared with the Raman data. The spectral changes have been well explained using the concentration fluctuation model and solute–solvent interaction. 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The spectral changes have been well explained using the concentration fluctuation model and solute–solvent interaction. Copyright © 2007 John Wiley & Sons, Ltd.</description><subject>Binary mixtures</subject><subject>Carbon monoxide</subject><subject>FWHM</subject><subject>Hydrogen bonding</subject><subject>Infrared radiation</subject><subject>intramolecular hydrogen bonding</subject><subject>IR spectra</subject><subject>Raman spectra</subject><subject>Reference systems</subject><subject>salicylaldehyde</subject><subject>solute-solvent interaction</subject><subject>Spectra</subject><subject>Stretching</subject><subject>Vibration</subject><subject>wavenumber shift</subject><issn>0377-0486</issn><issn>1097-4555</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNp90EtLxDAQB_AgCq4P8CPkpF66Jk3z6FEX36JSFY8hr2LWbromXdx-e7usCB70NAzzY5j5A3CA0RgjlJ9MYxpjIcgGGGFU8qyglG6CESKcZ6gQbBvspDRFCJUlwyPwOGmDcaGLqvNtgNbNXbBDDys1UwGqYOF1BVO3sD0c5kk13vSNaqx7662DPkDtg4o9nPllt4gu7YGtWjXJ7X_XXfBycf48ucruHi6vJ6d3mSGMkYwWpqiFZjVmXNWE6IJbVOTDsZip3GohcpvTUhgnsEDGEq25KDXjhhKrtSW74Gi9dx7bj4VLnZz5ZFzTqODaRZJccCRKmotBHv4rySonylfweA1NbFOKrpbz6GfDcxIjuQpXDuHKVbgDzdb00zeu_9PJm-rpt_epc8sfr-K7ZJxwKl_vL2U1qc6uckbkLfkCm42KUw</recordid><startdate>200712</startdate><enddate>200712</enddate><creator>Fathima, A. 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S.</creatorcontrib><creatorcontrib>Ramakrishnan, V.</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of Raman spectroscopy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fathima, A. Anis</au><au>Umadevi, M.</au><au>Ramachandran, M. S.</au><au>Ramakrishnan, V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Concentration dependent Raman and IR study on salicylaldehyde in binary mixtures</atitle><jtitle>Journal of Raman spectroscopy</jtitle><addtitle>J. Raman Spectrosc</addtitle><date>2007-12</date><risdate>2007</risdate><volume>38</volume><issue>12</issue><spage>1639</spage><epage>1645</epage><pages>1639-1645</pages><issn>0377-0486</issn><eissn>1097-4555</eissn><abstract>A vibrational spectroscopic study of binary mixtures of salicylaldehyde (SA) in three different solvents (polar and nonpolar) is presented. The vibrational modes ν(CO), hydroxyl stretching mode (COH) and aldehydic (CH) stretching vibration were analyzed. Changes in wavenumber position and full width half maximum have been explained for neat as well as binary mixtures with different volume fractions of the reference system, SA, in terms of inter‐ and intramolecular hydrogen bonding. The IR spectra of these mixtures have also been taken and compared with the Raman data. The spectral changes have been well explained using the concentration fluctuation model and solute–solvent interaction. Copyright © 2007 John Wiley & Sons, Ltd.</abstract><cop>Chichester, UK</cop><pub>John Wiley & Sons, Ltd</pub><doi>10.1002/jrs.1883</doi><tpages>7</tpages></addata></record> |
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| ispartof | Journal of Raman spectroscopy, 2007-12, Vol.38 (12), p.1639-1645 |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Binary mixtures Carbon monoxide FWHM Hydrogen bonding Infrared radiation intramolecular hydrogen bonding IR spectra Raman spectra Reference systems salicylaldehyde solute-solvent interaction Spectra Stretching Vibration wavenumber shift |
| title | Concentration dependent Raman and IR study on salicylaldehyde in binary mixtures |
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