Observations and Comments on the Mechanism of Epoxidation of Alkenes by Manganese(III) Porphyrins with Hypochlorite

The kinetics of olefin epoxidation in a methylene chloride/water biphase containing a phase-transfer agent with hypochlorite as oxygen transfer reagent and manganese(III) tetraphenylporphyrin catalysts has been reinvestigated. The results do not support the accumulation of an intermediate composed o...

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Veröffentlicht in:	Proceedings of the National Academy of Sciences - PNAS 1988-02, Vol.85 (3), p.641-644
Hauptverfasser:	Lee, Robert W., Nakagaki, Paul C., Balasubramanian, P. N., Bruice, Thomas C.
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes Catalysts Chemistry Chlorides Epoxidation Epoxy compounds Epoxy Compounds - chemical synthesis Ethers, Cyclic - chemical synthesis Exact sciences and technology Hypochlorite Hypochlorous Acid Kinetics Kinetics and mechanisms Manganese - metabolism Metalloporphyrins Organic chemistry Oxides Oxygen Porphyrins Reactivity and mechanisms
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