Sampling Error in Small-bore Sheathless Capillary Electrophoresis/Electrospray-ionization Mass Spectrometry

Two previously unreported sources of systematic error in electrokinetic injection caused by induced (hydrodynamic) flow in sheathless capillary electrophoresis/electrospray have been characterized for an interface constructed from 5 μm i.d. capillary column(s) with a 2–5 μm i.d. electrospray tip(s)....

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Veröffentlicht in:	Rapid communications in mass spectrometry 1996, Vol.10 (7), p.825-828
Hauptverfasser:	Valaskovic, Gary A., McLafferty, Fred W.
Format:	Artikel
Sprache:	eng
Schlagworte:	Animals Buffers Cattle Electrophoresis, Capillary - instrumentation Electrophoresis, Capillary - standards Mass Spectrometry - instrumentation Mass Spectrometry - standards Ubiquitins - chemistry
Online-Zugang:	Volltext
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