Very low temperature formaldehyde reactions and the build-up of organic molecules in comets and interstellar ices

We have investigated thermally promoted reactions of formaldehyde (H 2CO) in very low temperature ices. No such reactions occurred in ices of pure formaldehyde. However, addition of trace amounts of ammonia (NH 3) were sufficient to catalyze reactions at temperatures as low as 40 K. Similar reaction...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Advances in space research 1995-03, Vol.15 (3), p.401-406
Hauptverfasser: Schutte, W.A., Allamandola, L.J., Sandford, S.A.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 406
container_issue 3
container_start_page 401
container_title Advances in space research
container_volume 15
creator Schutte, W.A.
Allamandola, L.J.
Sandford, S.A.
description We have investigated thermally promoted reactions of formaldehyde (H 2CO) in very low temperature ices. No such reactions occurred in ices of pure formaldehyde. However, addition of trace amounts of ammonia (NH 3) were sufficient to catalyze reactions at temperatures as low as 40 K. Similar reactions could take place in interstellar ices and in Comets and produce considerable amounts of organic molecules.
doi_str_mv 10.1016/S0273-1177(99)80110-0
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_77961743</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0273117799801100</els_id><sourcerecordid>26044798</sourcerecordid><originalsourceid>FETCH-LOGICAL-c328t-765ea260e14e0e843ae0be3edf215b4f97aae1f7f6822f9aa1b3775f275b147d3</originalsourceid><addsrcrecordid>eNqFkU9v1DAQxS0EotvCNwDkE4JDwGMncXxCqKKAVIkDf66WY4-pUWJvbQe0355ss4JjT3N4vzfzNI-Q58DeAIP-7VfGpWgApHyl1OuBAbCGPSA7GKRqQLXDQ7L7h5yR81J-MQZcSvaYnAF0QvFO7MjtD8wHOqU_tOK8x2zqkpH6lGczObw5OKQZja0hxUJNdLTeIB2XMLlm2dPkaco_TQyWzmlCu0xYaIjUphnrxodYMZeK02QyDRbLE_LIm6ng09O8IN-vPny7_NRcf_n4-fL9dWMFH2oj-w4N7xlCiwyHVhhkIwp0nkM3tl5JYxC89P3AuVfGwCik7DyX3QitdOKCvNz27nO6XbBUPYdijzkipqVoKVUPshX3gmuItpVqWMFuA21OpWT0ep_DbPJBA9PHUvRdKfr4ca2UvitFs9X34nRgGWd0_12nFlbg2QZEU4yONRcNSnWMiY6zo_xuk3F91--AWRcbMFp0IaOt2qVwT4K_AzqmOw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>26044798</pqid></control><display><type>article</type><title>Very low temperature formaldehyde reactions and the build-up of organic molecules in comets and interstellar ices</title><source>MEDLINE</source><source>ScienceDirect Journals (5 years ago - present)</source><source>NASA Technical Reports Server</source><creator>Schutte, W.A. ; Allamandola, L.J. ; Sandford, S.A.</creator><creatorcontrib>Schutte, W.A. ; Allamandola, L.J. ; Sandford, S.A.</creatorcontrib><description>We have investigated thermally promoted reactions of formaldehyde (H 2CO) in very low temperature ices. No such reactions occurred in ices of pure formaldehyde. However, addition of trace amounts of ammonia (NH 3) were sufficient to catalyze reactions at temperatures as low as 40 K. Similar reactions could take place in interstellar ices and in Comets and produce considerable amounts of organic molecules.</description><identifier>ISSN: 0273-1177</identifier><identifier>EISSN: 1879-1948</identifier><identifier>DOI: 10.1016/S0273-1177(99)80110-0</identifier><identifier>PMID: 11539253</identifier><language>eng</language><publisher>Legacy CDMS: Elsevier Ltd</publisher><subject>Ammonia - chemistry ; Evolution, Chemical ; Extraterrestrial Environment ; Formaldehyde - chemistry ; Ice - analysis ; Life Sciences (General) ; Meteoroids ; Resins, Synthetic - chemistry ; Space life sciences ; Spectroscopy, Fourier Transform Infrared ; Temperature</subject><ispartof>Advances in space research, 1995-03, Vol.15 (3), p.401-406</ispartof><rights>1994</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c328t-765ea260e14e0e843ae0be3edf215b4f97aae1f7f6822f9aa1b3775f275b147d3</citedby><cites>FETCH-LOGICAL-c328t-765ea260e14e0e843ae0be3edf215b4f97aae1f7f6822f9aa1b3775f275b147d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/S0273-1177(99)80110-0$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/11539253$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Schutte, W.A.</creatorcontrib><creatorcontrib>Allamandola, L.J.</creatorcontrib><creatorcontrib>Sandford, S.A.</creatorcontrib><title>Very low temperature formaldehyde reactions and the build-up of organic molecules in comets and interstellar ices</title><title>Advances in space research</title><addtitle>Adv Space Res</addtitle><description>We have investigated thermally promoted reactions of formaldehyde (H 2CO) in very low temperature ices. No such reactions occurred in ices of pure formaldehyde. However, addition of trace amounts of ammonia (NH 3) were sufficient to catalyze reactions at temperatures as low as 40 K. Similar reactions could take place in interstellar ices and in Comets and produce considerable amounts of organic molecules.</description><subject>Ammonia - chemistry</subject><subject>Evolution, Chemical</subject><subject>Extraterrestrial Environment</subject><subject>Formaldehyde - chemistry</subject><subject>Ice - analysis</subject><subject>Life Sciences (General)</subject><subject>Meteoroids</subject><subject>Resins, Synthetic - chemistry</subject><subject>Space life sciences</subject><subject>Spectroscopy, Fourier Transform Infrared</subject><subject>Temperature</subject><issn>0273-1177</issn><issn>1879-1948</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1995</creationdate><recordtype>article</recordtype><sourceid>CYI</sourceid><sourceid>EIF</sourceid><recordid>eNqFkU9v1DAQxS0EotvCNwDkE4JDwGMncXxCqKKAVIkDf66WY4-pUWJvbQe0355ss4JjT3N4vzfzNI-Q58DeAIP-7VfGpWgApHyl1OuBAbCGPSA7GKRqQLXDQ7L7h5yR81J-MQZcSvaYnAF0QvFO7MjtD8wHOqU_tOK8x2zqkpH6lGczObw5OKQZja0hxUJNdLTeIB2XMLlm2dPkaco_TQyWzmlCu0xYaIjUphnrxodYMZeK02QyDRbLE_LIm6ng09O8IN-vPny7_NRcf_n4-fL9dWMFH2oj-w4N7xlCiwyHVhhkIwp0nkM3tl5JYxC89P3AuVfGwCik7DyX3QitdOKCvNz27nO6XbBUPYdijzkipqVoKVUPshX3gmuItpVqWMFuA21OpWT0ep_DbPJBA9PHUvRdKfr4ca2UvitFs9X34nRgGWd0_12nFlbg2QZEU4yONRcNSnWMiY6zo_xuk3F91--AWRcbMFp0IaOt2qVwT4K_AzqmOw</recordid><startdate>199503</startdate><enddate>199503</enddate><creator>Schutte, W.A.</creator><creator>Allamandola, L.J.</creator><creator>Sandford, S.A.</creator><general>Elsevier Ltd</general><scope>CYE</scope><scope>CYI</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>199503</creationdate><title>Very low temperature formaldehyde reactions and the build-up of organic molecules in comets and interstellar ices</title><author>Schutte, W.A. ; Allamandola, L.J. ; Sandford, S.A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c328t-765ea260e14e0e843ae0be3edf215b4f97aae1f7f6822f9aa1b3775f275b147d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1995</creationdate><topic>Ammonia - chemistry</topic><topic>Evolution, Chemical</topic><topic>Extraterrestrial Environment</topic><topic>Formaldehyde - chemistry</topic><topic>Ice - analysis</topic><topic>Life Sciences (General)</topic><topic>Meteoroids</topic><topic>Resins, Synthetic - chemistry</topic><topic>Space life sciences</topic><topic>Spectroscopy, Fourier Transform Infrared</topic><topic>Temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Schutte, W.A.</creatorcontrib><creatorcontrib>Allamandola, L.J.</creatorcontrib><creatorcontrib>Sandford, S.A.</creatorcontrib><collection>NASA Scientific and Technical Information</collection><collection>NASA Technical Reports Server</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Advances in space research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Schutte, W.A.</au><au>Allamandola, L.J.</au><au>Sandford, S.A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Very low temperature formaldehyde reactions and the build-up of organic molecules in comets and interstellar ices</atitle><jtitle>Advances in space research</jtitle><addtitle>Adv Space Res</addtitle><date>1995-03</date><risdate>1995</risdate><volume>15</volume><issue>3</issue><spage>401</spage><epage>406</epage><pages>401-406</pages><issn>0273-1177</issn><eissn>1879-1948</eissn><abstract>We have investigated thermally promoted reactions of formaldehyde (H 2CO) in very low temperature ices. No such reactions occurred in ices of pure formaldehyde. However, addition of trace amounts of ammonia (NH 3) were sufficient to catalyze reactions at temperatures as low as 40 K. Similar reactions could take place in interstellar ices and in Comets and produce considerable amounts of organic molecules.</abstract><cop>Legacy CDMS</cop><pub>Elsevier Ltd</pub><pmid>11539253</pmid><doi>10.1016/S0273-1177(99)80110-0</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0273-1177
ispartof Advances in space research, 1995-03, Vol.15 (3), p.401-406
issn 0273-1177
1879-1948
language eng
recordid cdi_proquest_miscellaneous_77961743
source MEDLINE; ScienceDirect Journals (5 years ago - present); NASA Technical Reports Server
subjects Ammonia - chemistry
Evolution, Chemical
Extraterrestrial Environment
Formaldehyde - chemistry
Ice - analysis
Life Sciences (General)
Meteoroids
Resins, Synthetic - chemistry
Space life sciences
Spectroscopy, Fourier Transform Infrared
Temperature
title Very low temperature formaldehyde reactions and the build-up of organic molecules in comets and interstellar ices
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T16%3A35%3A22IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Very%20low%20temperature%20formaldehyde%20reactions%20and%20the%20build-up%20of%20organic%20molecules%20in%20comets%20and%20interstellar%20ices&rft.jtitle=Advances%20in%20space%20research&rft.au=Schutte,%20W.A.&rft.date=1995-03&rft.volume=15&rft.issue=3&rft.spage=401&rft.epage=406&rft.pages=401-406&rft.issn=0273-1177&rft.eissn=1879-1948&rft_id=info:doi/10.1016/S0273-1177(99)80110-0&rft_dat=%3Cproquest_cross%3E26044798%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=26044798&rft_id=info:pmid/11539253&rft_els_id=S0273117799801100&rfr_iscdi=true