Very low temperature formaldehyde reactions and the build-up of organic molecules in comets and interstellar ices
We have investigated thermally promoted reactions of formaldehyde (H 2CO) in very low temperature ices. No such reactions occurred in ices of pure formaldehyde. However, addition of trace amounts of ammonia (NH 3) were sufficient to catalyze reactions at temperatures as low as 40 K. Similar reaction...
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Veröffentlicht in: | Advances in space research 1995-03, Vol.15 (3), p.401-406 |
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creator | Schutte, W.A. Allamandola, L.J. Sandford, S.A. |
description | We have investigated thermally promoted reactions of formaldehyde (H
2CO) in very low temperature ices. No such reactions occurred in ices of pure formaldehyde. However, addition of trace amounts of ammonia (NH
3) were sufficient to catalyze reactions at temperatures as low as 40 K. Similar reactions could take place in interstellar ices and in Comets and produce considerable amounts of organic molecules. |
doi_str_mv | 10.1016/S0273-1177(99)80110-0 |
format | Article |
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2CO) in very low temperature ices. No such reactions occurred in ices of pure formaldehyde. However, addition of trace amounts of ammonia (NH
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2CO) in very low temperature ices. No such reactions occurred in ices of pure formaldehyde. However, addition of trace amounts of ammonia (NH
3) were sufficient to catalyze reactions at temperatures as low as 40 K. Similar reactions could take place in interstellar ices and in Comets and produce considerable amounts of organic molecules.</description><subject>Ammonia - chemistry</subject><subject>Evolution, Chemical</subject><subject>Extraterrestrial Environment</subject><subject>Formaldehyde - chemistry</subject><subject>Ice - analysis</subject><subject>Life Sciences (General)</subject><subject>Meteoroids</subject><subject>Resins, Synthetic - chemistry</subject><subject>Space life sciences</subject><subject>Spectroscopy, Fourier Transform Infrared</subject><subject>Temperature</subject><issn>0273-1177</issn><issn>1879-1948</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1995</creationdate><recordtype>article</recordtype><sourceid>CYI</sourceid><sourceid>EIF</sourceid><recordid>eNqFkU9v1DAQxS0EotvCNwDkE4JDwGMncXxCqKKAVIkDf66WY4-pUWJvbQe0355ss4JjT3N4vzfzNI-Q58DeAIP-7VfGpWgApHyl1OuBAbCGPSA7GKRqQLXDQ7L7h5yR81J-MQZcSvaYnAF0QvFO7MjtD8wHOqU_tOK8x2zqkpH6lGczObw5OKQZja0hxUJNdLTeIB2XMLlm2dPkaco_TQyWzmlCu0xYaIjUphnrxodYMZeK02QyDRbLE_LIm6ng09O8IN-vPny7_NRcf_n4-fL9dWMFH2oj-w4N7xlCiwyHVhhkIwp0nkM3tl5JYxC89P3AuVfGwCik7DyX3QitdOKCvNz27nO6XbBUPYdijzkipqVoKVUPshX3gmuItpVqWMFuA21OpWT0ep_DbPJBA9PHUvRdKfr4ca2UvitFs9X34nRgGWd0_12nFlbg2QZEU4yONRcNSnWMiY6zo_xuk3F91--AWRcbMFp0IaOt2qVwT4K_AzqmOw</recordid><startdate>199503</startdate><enddate>199503</enddate><creator>Schutte, W.A.</creator><creator>Allamandola, L.J.</creator><creator>Sandford, S.A.</creator><general>Elsevier Ltd</general><scope>CYE</scope><scope>CYI</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>199503</creationdate><title>Very low temperature formaldehyde reactions and the build-up of organic molecules in comets and interstellar ices</title><author>Schutte, W.A. ; Allamandola, L.J. ; Sandford, S.A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c328t-765ea260e14e0e843ae0be3edf215b4f97aae1f7f6822f9aa1b3775f275b147d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1995</creationdate><topic>Ammonia - chemistry</topic><topic>Evolution, Chemical</topic><topic>Extraterrestrial Environment</topic><topic>Formaldehyde - chemistry</topic><topic>Ice - analysis</topic><topic>Life Sciences (General)</topic><topic>Meteoroids</topic><topic>Resins, Synthetic - chemistry</topic><topic>Space life sciences</topic><topic>Spectroscopy, Fourier Transform Infrared</topic><topic>Temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Schutte, W.A.</creatorcontrib><creatorcontrib>Allamandola, L.J.</creatorcontrib><creatorcontrib>Sandford, S.A.</creatorcontrib><collection>NASA Scientific and Technical Information</collection><collection>NASA Technical Reports Server</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Advances in space research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Schutte, W.A.</au><au>Allamandola, L.J.</au><au>Sandford, S.A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Very low temperature formaldehyde reactions and the build-up of organic molecules in comets and interstellar ices</atitle><jtitle>Advances in space research</jtitle><addtitle>Adv Space Res</addtitle><date>1995-03</date><risdate>1995</risdate><volume>15</volume><issue>3</issue><spage>401</spage><epage>406</epage><pages>401-406</pages><issn>0273-1177</issn><eissn>1879-1948</eissn><abstract>We have investigated thermally promoted reactions of formaldehyde (H
2CO) in very low temperature ices. No such reactions occurred in ices of pure formaldehyde. However, addition of trace amounts of ammonia (NH
3) were sufficient to catalyze reactions at temperatures as low as 40 K. Similar reactions could take place in interstellar ices and in Comets and produce considerable amounts of organic molecules.</abstract><cop>Legacy CDMS</cop><pub>Elsevier Ltd</pub><pmid>11539253</pmid><doi>10.1016/S0273-1177(99)80110-0</doi><tpages>6</tpages></addata></record> |
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source | MEDLINE; ScienceDirect Journals (5 years ago - present); NASA Technical Reports Server |
subjects | Ammonia - chemistry Evolution, Chemical Extraterrestrial Environment Formaldehyde - chemistry Ice - analysis Life Sciences (General) Meteoroids Resins, Synthetic - chemistry Space life sciences Spectroscopy, Fourier Transform Infrared Temperature |
title | Very low temperature formaldehyde reactions and the build-up of organic molecules in comets and interstellar ices |
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