Structural and biochemical properties of bidentate tetraaquarhodium(III) complexes of inorganic pyrophosphate and adenosine 5'-diphosphate

The structural and biochemical properties of the alpha,beta-bidentate tetraaquarhodium(III) complexes of inorganic pyrophosphate [Rh(H2O)4PP] and adenosine diphosphate [Rh(H2O)4ADP] are examined. These Rh(III) complexes are exchange-inert analogues of the corresponding physiologically important MgII...

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Veröffentlicht in:	Biochemistry (Easton) 1987-04, Vol.26 (7), p.2060-2066
Hauptverfasser:	Shorter, Andrew L, Haromy, Tuli P, Scalzo-Brush, Theresa, Knight, Wilson B, Dunaway-Mariano, Debra, Sundaralingam, Muttaiya
Format:	Artikel
Sprache:	eng
Schlagworte:	550201 - Biochemistry- Tracer Techniques Adenosine Diphosphate - analogs & derivatives Adenosine Diphosphate - chemical synthesis Adenosine Diphosphate - pharmacology ADP BASIC BIOLOGICAL SCIENCES BIOCHEMICAL REACTION KINETICS Biological and medical sciences Chemical Phenomena CHEMICAL PROPERTIES CHEMICAL SHIFT Chemistry COMPLEXES Diphosphates - pharmacology ELEMENTS ENZYMES Fundamental and applied biological sciences. Psychology ISOTOPES KINETICS LIGHT NUCLEI MAGNETIC RESONANCE Magnetic Resonance Spectroscopy METALS Models, Molecular Molecular biophysics Molecular Conformation MOLECULAR STRUCTURE NMR SPECTRA NUCLEAR MAGNETIC RESONANCE NUCLEI NUCLEOTIDES ODD-EVEN NUCLEI ORGANIC COMPOUNDS Organophosphorus Compounds - chemical synthesis Organophosphorus Compounds - pharmacology OXYGEN COMPOUNDS OXYGEN ISOTOPES PHOSPHORUS 31 PHOSPHORUS COMPOUNDS PHOSPHORUS ISOTOPES Phosphorus Radioisotopes PHOSPHORUS-GROUP TRANSFERASES PHOSPHOTRANSFERASES Phosphotransferases - antagonists & inhibitors PLATINUM METALS PYROPHOSPHATES REACTION KINETICS RESONANCE RHODIUM Rhodium - pharmacology SPECTRA STABLE ISOTOPES Structure in molecular biology TRANSFERASES TRANSITION ELEMENTS Tridimensional structure
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