Real-Space Imaging of Nucleation and Growth in Colloidal Crystallization
Crystallization of concentrated colloidal suspensions was studied in real space with laser scanning confocal microscopy. Direct imaging in three dimensions allowed identification and observation of both nucleation and growth of crystalline regions, providing an experimental measure of properties of...
Gespeichert in:
| Veröffentlicht in: | Science (American Association for the Advancement of Science) 2001-04, Vol.292 (5515), p.258-262 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 262 |
|---|---|
| container_issue | 5515 |
| container_start_page | 258 |
| container_title | Science (American Association for the Advancement of Science) |
| container_volume | 292 |
| creator | Gasser, U. Weeks, Eric R. Schofield, Andrew Pusey, P. N. Weitz, D. A. |
| description | Crystallization of concentrated colloidal suspensions was studied in real space with laser scanning confocal microscopy. Direct imaging in three dimensions allowed identification and observation of both nucleation and growth of crystalline regions, providing an experimental measure of properties of the nucleating crystallites. By following their evolution, we identified critical nuclei, determined nucleation rates, and measured the average surface tension of the crystal-liquid interface. The structure of the nuclei was the same as the bulk solid phase, random hexagonal close-packed, and their average shape was rather nonspherical, with rough rather than faceted surfaces. |
| doi_str_mv | 10.1126/science.1058457 |
| format | Article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_miscellaneous_77049555</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A73828070</galeid><jstor_id>3082728</jstor_id><sourcerecordid>A73828070</sourcerecordid><originalsourceid>FETCH-LOGICAL-c772t-9bd885800ff266650f24f0573bf371c92963a9b261c0fa740b25dd8d7df6b36a3</originalsourceid><addsrcrecordid>eNqN0s9rFDEUB_BBFLtWz15EBgX10GnzYzJJju2i24WlC1a9DplMMmbJJttkBlv_elN3qKwsuuQQkvfJg_C-WfYSglMIUXUWpVFOqlMICCsJfZRNIOCk4Ajgx9kEAFwVDFBylD2LcQVAqnH8NDuCEAOcDpPs8rMStrjeCKny-Vp0xnW51_nVIK0SvfEuF67NZ8H_6L_nxuVTb603rbD5NNzFXlhrfv52z7MnWtioXoz7cfb108cv08tisZzNp-eLQlKK-oI3LWOEAaA1qqqKAI1KDQjFjcYUSo54hQVvUAUl0IKWoEGkbVlLW101uBL4OHu37bsJ_mZQsa_XJkplrXDKD7GmFJScEJLg-3_DEpeQcoD-2xJVvIQM37d88xdc-SG49N0aQUwo44wldLJFnbCqNk77PgjZKaeCsN4pbdL1OcUMpcmAxIs9PK1WrY3c5z_s-ER6ddt3Yoixnl9fHUyX3w6mF7NDKZstdujJPipThlSn6pSL6XKHn225DD7GoHS9CWYtwl0NQX0f93qMez3GPb14PQ5kaNaq_ePHfCfwdgQiSmF1EE6a-OA4gyWsknq1VavY-_BQxYAhihj-BdKJCu8</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>213578988</pqid></control><display><type>article</type><title>Real-Space Imaging of Nucleation and Growth in Colloidal Crystallization</title><source>American Association for the Advancement of Science</source><source>Jstor Complete Legacy</source><creator>Gasser, U. ; Weeks, Eric R. ; Schofield, Andrew ; Pusey, P. N. ; Weitz, D. A.</creator><creatorcontrib>Gasser, U. ; Weeks, Eric R. ; Schofield, Andrew ; Pusey, P. N. ; Weitz, D. A.</creatorcontrib><description>Crystallization of concentrated colloidal suspensions was studied in real space with laser scanning confocal microscopy. Direct imaging in three dimensions allowed identification and observation of both nucleation and growth of crystalline regions, providing an experimental measure of properties of the nucleating crystallites. By following their evolution, we identified critical nuclei, determined nucleation rates, and measured the average surface tension of the crystal-liquid interface. The structure of the nuclei was the same as the bulk solid phase, random hexagonal close-packed, and their average shape was rather nonspherical, with rough rather than faceted surfaces.</description><identifier>ISSN: 0036-8075</identifier><identifier>EISSN: 1095-9203</identifier><identifier>DOI: 10.1126/science.1058457</identifier><identifier>PMID: 11303095</identifier><identifier>CODEN: SCIEAS</identifier><language>eng</language><publisher>Washington, DC: American Society for the Advancement of Science</publisher><subject>Colloids ; Cross-disciplinary physics: materials science; rheology ; Crystal structure ; Crystallites ; Crystallization ; Crystallography ; Crystals ; Exact sciences and technology ; Hexagonal crystals ; Histograms ; Interfacial tension ; Liquids ; Materials science ; Methods of crystal growth; physics of crystal growth ; Molecules ; Nucleation ; Physics ; Structure ; Theory and models of crystal growth; physics of crystal growth, crystal morphology and orientation</subject><ispartof>Science (American Association for the Advancement of Science), 2001-04, Vol.292 (5515), p.258-262</ispartof><rights>Copyright 2001 American Association for the Advancement of Science</rights><rights>2001 INIST-CNRS</rights><rights>COPYRIGHT 2001 American Association for the Advancement of Science</rights><rights>COPYRIGHT 2001 American Association for the Advancement of Science</rights><rights>Copyright American Association for the Advancement of Science Apr 13, 2001</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c772t-9bd885800ff266650f24f0573bf371c92963a9b261c0fa740b25dd8d7df6b36a3</citedby><cites>FETCH-LOGICAL-c772t-9bd885800ff266650f24f0573bf371c92963a9b261c0fa740b25dd8d7df6b36a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.jstor.org/stable/pdf/3082728$$EPDF$$P50$$Gjstor$$H</linktopdf><linktohtml>$$Uhttps://www.jstor.org/stable/3082728$$EHTML$$P50$$Gjstor$$H</linktohtml><link.rule.ids>314,776,780,799,2871,2872,27901,27902,57992,58225</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=981416$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/11303095$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Gasser, U.</creatorcontrib><creatorcontrib>Weeks, Eric R.</creatorcontrib><creatorcontrib>Schofield, Andrew</creatorcontrib><creatorcontrib>Pusey, P. N.</creatorcontrib><creatorcontrib>Weitz, D. A.</creatorcontrib><title>Real-Space Imaging of Nucleation and Growth in Colloidal Crystallization</title><title>Science (American Association for the Advancement of Science)</title><addtitle>Science</addtitle><description>Crystallization of concentrated colloidal suspensions was studied in real space with laser scanning confocal microscopy. Direct imaging in three dimensions allowed identification and observation of both nucleation and growth of crystalline regions, providing an experimental measure of properties of the nucleating crystallites. By following their evolution, we identified critical nuclei, determined nucleation rates, and measured the average surface tension of the crystal-liquid interface. The structure of the nuclei was the same as the bulk solid phase, random hexagonal close-packed, and their average shape was rather nonspherical, with rough rather than faceted surfaces.</description><subject>Colloids</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Crystal structure</subject><subject>Crystallites</subject><subject>Crystallization</subject><subject>Crystallography</subject><subject>Crystals</subject><subject>Exact sciences and technology</subject><subject>Hexagonal crystals</subject><subject>Histograms</subject><subject>Interfacial tension</subject><subject>Liquids</subject><subject>Materials science</subject><subject>Methods of crystal growth; physics of crystal growth</subject><subject>Molecules</subject><subject>Nucleation</subject><subject>Physics</subject><subject>Structure</subject><subject>Theory and models of crystal growth; physics of crystal growth, crystal morphology and orientation</subject><issn>0036-8075</issn><issn>1095-9203</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><sourceid>8G5</sourceid><sourceid>BEC</sourceid><sourceid>BENPR</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNqN0s9rFDEUB_BBFLtWz15EBgX10GnzYzJJju2i24WlC1a9DplMMmbJJttkBlv_elN3qKwsuuQQkvfJg_C-WfYSglMIUXUWpVFOqlMICCsJfZRNIOCk4Ajgx9kEAFwVDFBylD2LcQVAqnH8NDuCEAOcDpPs8rMStrjeCKny-Vp0xnW51_nVIK0SvfEuF67NZ8H_6L_nxuVTb603rbD5NNzFXlhrfv52z7MnWtioXoz7cfb108cv08tisZzNp-eLQlKK-oI3LWOEAaA1qqqKAI1KDQjFjcYUSo54hQVvUAUl0IKWoEGkbVlLW101uBL4OHu37bsJ_mZQsa_XJkplrXDKD7GmFJScEJLg-3_DEpeQcoD-2xJVvIQM37d88xdc-SG49N0aQUwo44wldLJFnbCqNk77PgjZKaeCsN4pbdL1OcUMpcmAxIs9PK1WrY3c5z_s-ER6ddt3Yoixnl9fHUyX3w6mF7NDKZstdujJPipThlSn6pSL6XKHn225DD7GoHS9CWYtwl0NQX0f93qMez3GPb14PQ5kaNaq_ePHfCfwdgQiSmF1EE6a-OA4gyWsknq1VavY-_BQxYAhihj-BdKJCu8</recordid><startdate>20010413</startdate><enddate>20010413</enddate><creator>Gasser, U.</creator><creator>Weeks, Eric R.</creator><creator>Schofield, Andrew</creator><creator>Pusey, P. N.</creator><creator>Weitz, D. A.</creator><general>American Society for the Advancement of Science</general><general>American Association for the Advancement of Science</general><general>The American Association for the Advancement of Science</general><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8GL</scope><scope>IBG</scope><scope>IOV</scope><scope>ISN</scope><scope>0-V</scope><scope>3V.</scope><scope>7QF</scope><scope>7QG</scope><scope>7QL</scope><scope>7QP</scope><scope>7QQ</scope><scope>7QR</scope><scope>7SC</scope><scope>7SE</scope><scope>7SN</scope><scope>7SP</scope><scope>7SR</scope><scope>7SS</scope><scope>7T7</scope><scope>7TA</scope><scope>7TB</scope><scope>7TK</scope><scope>7TM</scope><scope>7U5</scope><scope>7U9</scope><scope>7X2</scope><scope>7X7</scope><scope>7XB</scope><scope>88A</scope><scope>88B</scope><scope>88E</scope><scope>88I</scope><scope>8AF</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FH</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>8G5</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>ALSLI</scope><scope>ARAPS</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BBNVY</scope><scope>BEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>C1K</scope><scope>CCPQU</scope><scope>CJNVE</scope><scope>D1I</scope><scope>DWQXO</scope><scope>F28</scope><scope>FR3</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>H8D</scope><scope>H8G</scope><scope>H94</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>JQ2</scope><scope>K9-</scope><scope>K9.</scope><scope>KB.</scope><scope>KR7</scope><scope>L6V</scope><scope>L7M</scope><scope>LK8</scope><scope>L~C</scope><scope>L~D</scope><scope>M0K</scope><scope>M0P</scope><scope>M0R</scope><scope>M0S</scope><scope>M1P</scope><scope>M2O</scope><scope>M2P</scope><scope>M7N</scope><scope>M7P</scope><scope>M7S</scope><scope>MBDVC</scope><scope>P5Z</scope><scope>P62</scope><scope>P64</scope><scope>PATMY</scope><scope>PCBAR</scope><scope>PDBOC</scope><scope>PQEDU</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>R05</scope><scope>RC3</scope><scope>7X8</scope></search><sort><creationdate>20010413</creationdate><title>Real-Space Imaging of Nucleation and Growth in Colloidal Crystallization</title><author>Gasser, U. ; Weeks, Eric R. ; Schofield, Andrew ; Pusey, P. N. ; Weitz, D. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c772t-9bd885800ff266650f24f0573bf371c92963a9b261c0fa740b25dd8d7df6b36a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2001</creationdate><topic>Colloids</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Crystal structure</topic><topic>Crystallites</topic><topic>Crystallization</topic><topic>Crystallography</topic><topic>Crystals</topic><topic>Exact sciences and technology</topic><topic>Hexagonal crystals</topic><topic>Histograms</topic><topic>Interfacial tension</topic><topic>Liquids</topic><topic>Materials science</topic><topic>Methods of crystal growth; physics of crystal growth</topic><topic>Molecules</topic><topic>Nucleation</topic><topic>Physics</topic><topic>Structure</topic><topic>Theory and models of crystal growth; physics of crystal growth, crystal morphology and orientation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gasser, U.</creatorcontrib><creatorcontrib>Weeks, Eric R.</creatorcontrib><creatorcontrib>Schofield, Andrew</creatorcontrib><creatorcontrib>Pusey, P. N.</creatorcontrib><creatorcontrib>Weitz, D. A.</creatorcontrib><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Gale In Context: High School</collection><collection>Gale In Context: Biography</collection><collection>Gale In Context: Opposing Viewpoints</collection><collection>Gale In Context: Canada</collection><collection>ProQuest Social Sciences Premium Collection</collection><collection>ProQuest Central (Corporate)</collection><collection>Aluminium Industry Abstracts</collection><collection>Animal Behavior Abstracts</collection><collection>Bacteriology Abstracts (Microbiology B)</collection><collection>Calcium & Calcified Tissue Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Chemoreception Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Ecology Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Entomology Abstracts (Full archive)</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Neurosciences Abstracts</collection><collection>Nucleic Acids Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Virology and AIDS Abstracts</collection><collection>Agricultural Science Collection</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Biology Database (Alumni Edition)</collection><collection>Education Database (Alumni Edition)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>STEM Database</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Research Library (Alumni Edition)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>Social Science Premium Collection</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>Biological Science Collection</collection><collection>eLibrary</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ProQuest One Community College</collection><collection>Education Collection</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>Research Library Prep</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>AIDS and Cancer Research Abstracts</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Consumer Health Database (Alumni Edition)</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Materials Science Database</collection><collection>Civil Engineering Abstracts</collection><collection>ProQuest Engineering Collection</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>ProQuest Biological Science Collection</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Agricultural Science Database</collection><collection>Education Database</collection><collection>Consumer Health Database</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Research Library</collection><collection>Science Database</collection><collection>Algology Mycology and Protozoology Abstracts (Microbiology C)</collection><collection>Biological Science Database</collection><collection>Engineering Database</collection><collection>Research Library (Corporate)</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environmental Science Database</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Education</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><collection>University of Michigan</collection><collection>Genetics Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Science (American Association for the Advancement of Science)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gasser, U.</au><au>Weeks, Eric R.</au><au>Schofield, Andrew</au><au>Pusey, P. N.</au><au>Weitz, D. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Real-Space Imaging of Nucleation and Growth in Colloidal Crystallization</atitle><jtitle>Science (American Association for the Advancement of Science)</jtitle><addtitle>Science</addtitle><date>2001-04-13</date><risdate>2001</risdate><volume>292</volume><issue>5515</issue><spage>258</spage><epage>262</epage><pages>258-262</pages><issn>0036-8075</issn><eissn>1095-9203</eissn><coden>SCIEAS</coden><abstract>Crystallization of concentrated colloidal suspensions was studied in real space with laser scanning confocal microscopy. Direct imaging in three dimensions allowed identification and observation of both nucleation and growth of crystalline regions, providing an experimental measure of properties of the nucleating crystallites. By following their evolution, we identified critical nuclei, determined nucleation rates, and measured the average surface tension of the crystal-liquid interface. The structure of the nuclei was the same as the bulk solid phase, random hexagonal close-packed, and their average shape was rather nonspherical, with rough rather than faceted surfaces.</abstract><cop>Washington, DC</cop><pub>American Society for the Advancement of Science</pub><pmid>11303095</pmid><doi>10.1126/science.1058457</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0036-8075 |
| ispartof | Science (American Association for the Advancement of Science), 2001-04, Vol.292 (5515), p.258-262 |
| issn | 0036-8075 1095-9203 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_77049555 |
| source | American Association for the Advancement of Science; Jstor Complete Legacy |
| subjects | Colloids Cross-disciplinary physics: materials science rheology Crystal structure Crystallites Crystallization Crystallography Crystals Exact sciences and technology Hexagonal crystals Histograms Interfacial tension Liquids Materials science Methods of crystal growth physics of crystal growth Molecules Nucleation Physics Structure Theory and models of crystal growth physics of crystal growth, crystal morphology and orientation |
| title | Real-Space Imaging of Nucleation and Growth in Colloidal Crystallization |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-31T19%3A33%3A03IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_proqu&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Real-Space%20Imaging%20of%20Nucleation%20and%20Growth%20in%20Colloidal%20Crystallization&rft.jtitle=Science%20(American%20Association%20for%20the%20Advancement%20of%20Science)&rft.au=Gasser,%20U.&rft.date=2001-04-13&rft.volume=292&rft.issue=5515&rft.spage=258&rft.epage=262&rft.pages=258-262&rft.issn=0036-8075&rft.eissn=1095-9203&rft.coden=SCIEAS&rft_id=info:doi/10.1126/science.1058457&rft_dat=%3Cgale_proqu%3EA73828070%3C/gale_proqu%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=213578988&rft_id=info:pmid/11303095&rft_galeid=A73828070&rft_jstor_id=3082728&rfr_iscdi=true |