2'-C-branched ribonucleosides. 2. Synthesis of 2'-C-beta-trifluoromethyl pyrimidine ribonucleosides

[structure: see text]. The first synthesis of 2'-C-beta-trifluoromethyl pyrimidine ribonucleosides is described. 1,2,3,5-Tetra-O-benzoyl-2-C-beta-trifluoromethyl-alpha-D-ribofuranose (3) is prepared from 1,3,5-tri-O-benzoyl-alpha-D-ribofuranose (1) in three steps and converted to 3,5-di-O-benzo...

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Veröffentlicht in:	Organic letters 2001-04, Vol.3 (7), p.1025-1028
Hauptverfasser:	Li, N S, Tang, X Q, Piccirilli, J A
Format:	Artikel
Sprache:	eng
Schlagworte:	Glycosylation Molecular Conformation Molecular Structure Pyrimidines - chemical synthesis Pyrimidines - chemistry Ribonucleosides - chemical synthesis Ribonucleosides - chemistry
Online-Zugang:	Volltext
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