Hydrogen-Bond-Mediated Enantio- and Regioselectivity in a Ru-Catalyzed Epoxidation Reaction

A chiral epoxidation catalyst based on a tricyclic octahydro-1H-4,7-methanoisoindol-1-one scaffold, in which a hydrogen bonding site and the catalytically active ruthenium center are spatially separated, was synthesized. It was shown that epoxidation reactions in such a supramolecular catalyst occur...

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Veröffentlicht in:	Journal of the American Chemical Society 2010-11, Vol.132 (45), p.15911-15913
Hauptverfasser:	Fackler, Philipp, Berthold, Carola, Voss, Felix, Bach, Thorsten
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Epoxy Compounds - chemical synthesis Epoxy Compounds - chemistry Hydrogen Bonding Ruthenium - chemistry
Online-Zugang:	Volltext
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