Iron-Facilitated Direct Oxidative C−H Transformation of Allylarenes or Alkenes to Alkenyl Nitriles

This paper describes the first direct approach to alkenyl nitriles from allylarenes or alkenes facilitated by an inexpensive homogeneous iron catalyst. Three C−H bond cleavages occur under the mild conditions during this process. Mechanistic studies indicate that the cleavage of the allyl C(sp3)−H b...

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Veröffentlicht in:	Journal of the American Chemical Society 2010-11, Vol.132 (45), p.15893-15895
Hauptverfasser:	Qin, Chong, Jiao, Ning
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes - chemistry Carbon - chemistry Catalysis Hydrogen - chemistry Iron - chemistry Nitriles - chemical synthesis Oxidation-Reduction
Online-Zugang:	Volltext
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