Direct use of allylic alcohols in the allylation of sulfonylimidates

Direct use of allylic alcohols in the allylation of sulfonylimidates

We have developed catalytic allylation reactions of sulfonylimidates using allylic alcohols as allylating reagents. Stoichiometric amounts of neither activators nor bases are required in this reaction.

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Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2010-12, Vol.46 (45), p.8662-8664
Hauptverfasser: Matsubara, Ryosuke, Masuda, Koichiro, Nakano, Jyunya, Kobayashi, Shū
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Esters
Imidoesters - chemistry
Propanols - chemistry
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Zusammenfassung:We have developed catalytic allylation reactions of sulfonylimidates using allylic alcohols as allylating reagents. Stoichiometric amounts of neither activators nor bases are required in this reaction.
ISSN:1359-7345
1364-548X
DOI:10.1039/c0cc03067h