Novel Approach to Aminocarboranes by Mild Amidation of Selected Iodo-carboranes

A mild protocol for the palladium-catalyzed Buchwald−Hartwig amidation of icosahedral carboranes is described. Employing 2-dicyclohexylphosphino-2′-(N,N-dimethylamino)biphenyl (1) as a ligand and K3PO4 as a base, benzamide, trifluoroacetamide, acetamide, and formamide were coupled to a series of mon...

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Veröffentlicht in:	Inorganic chemistry 2010-11, Vol.49 (22), p.10627-10634
Hauptverfasser:	Sevryugina, Yulia, Julius, Richard L, Hawthorne, M. Frederick
Format:	Artikel
Sprache:	eng
Schlagworte:	Amides - chemical synthesis Amides - chemistry Boranes - chemical synthesis Boranes - chemistry Catalysis Crystallography, X-Ray Iodine - chemistry Models, Molecular Palladium - chemistry
Online-Zugang:	Volltext
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