One-Pot Synthesis of Optically Active Allyl Esters via Lipase−Vanadium Combo Catalysis

The combination of vanadium-oxo compounds (3 or 4) with a lipase produced the regio- and enantioconvergent transformation of racemic allyl alcohols (1 or 2) into optically active allyl esters. In this system, the vanadium compounds catalyzed the continuous racemization of the alcohols along with the...

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Veröffentlicht in:	Organic letters 2010-11, Vol.12 (21), p.4900-4903
Hauptverfasser:	Akai, Shuji, Hanada, Ryosuke, Fujiwara, Noboru, Kita, Yasuyuki, Egi, Masahiro
Format:	Artikel
Sprache:	eng
Schlagworte:	Biocatalysis Catalysis Esters - chemical synthesis Esters - metabolism Lipase - metabolism Molecular Structure Stereoisomerism Vanadium - chemistry
Online-Zugang:	Volltext
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