Physico chemical properties of aminated tamarind xyloglucan

Tamarind xyloglucan (XG) has been functionalized with amino group, which forms irreversible hydrogels with blue fluorescence characteristics. Aminated xyloglucan (XG-NH 2) at very low concentration (0.2%, w/v) in aqueous medium, forms self assembled spherical nano-particles of 60 nm size, where as a...

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Veröffentlicht in:Colloids and surfaces, B, Biointerfaces B, Biointerfaces, 2010-12, Vol.81 (2), p.513-520
Hauptverfasser: Simi, Chandroth Kalyad, Abraham, Tholath Emilia
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Abraham, Tholath Emilia
description Tamarind xyloglucan (XG) has been functionalized with amino group, which forms irreversible hydrogels with blue fluorescence characteristics. Aminated xyloglucan (XG-NH 2) at very low concentration (0.2%, w/v) in aqueous medium, forms self assembled spherical nano-particles of 60 nm size, where as at 7% (w/v), it formed a strong hydrogel. The bonding of amino group to the XG polymers was confirmed by FTIR spectra. The XG-NH 2 has same solubility as XG. The XG showed a broad melting point around 78 °C whereas XG-NH 2 was at 115 °C. In addition, aminated xyloglucan (XG-NH 2) exhibited good thermal properties. The XG-NH 2 shows better antimicrobial activity in comparison to chitosan. This modified xyloglucan has potential applications in the medical and biotronics field because it possesses biocompatibility, strong hydrogel behavior with very useful blue fluorescence.
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subjects Amines - chemistry
Blue fluorescence
Chemistry, Physical
Chitosan
Fluorescence
Gelation
Glucans - chemistry
Glucans - isolation & purification
Hydrogel
Hydrogels
Hydrogels - chemical synthesis
Hydrogels - chemistry
Medical
Nanomaterials
Nanostructure
Particle Size
Seeds - chemistry
Self assembly
Tamarind
Tamarind kernel powder
Tamarindus - chemistry
Tamarindus indica
Thermal properties
Xylans - chemistry
Xylans - isolation & purification
Xyloglucan
title Physico chemical properties of aminated tamarind xyloglucan
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