The effect of different solvents on the performance of zeolite-filled composite pervaporation membranes
The aim of this research is to study effect of different solvents on the membrane morphology and on the performance of zeolite-filled composite pervaporation membranes. PAN (polyacrylonitrile) was used as a base polymer and zeolite 13× (32 wt.%) was used as the filler. The solvents considered were D...
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| Veröffentlicht in: | Desalination 2010-10, Vol.261 (1), p.181-185 |
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| creator | Şener, Tansel Okumuş, Emin Gürkan, Türker Yilmaz, Levent |
| description | The aim of this research is to study effect of different solvents on the membrane morphology and on the performance of zeolite-filled composite pervaporation membranes. PAN (polyacrylonitrile) was used as a base polymer and zeolite 13× (32
wt.%) was used as the filler. The solvents considered were DMF (dimethyl formamide), DMSO (dimethyl sulfoxide), DMAc (dimethyl acedamide) and THF (tetrahydrofuran). The cross-sectional morphology of manufactured membranes shows three layers: a zeolite-free polymer layer, a zeolite-filled polymer layer and a skin layer. However, at the same casting content (5.4% PAN, 2.6% zeolite 13×, 92
wt.% solvent) the ratio of the thickness of these layers to total membrane thickness varies with the solvent used. The most homogeneous zeolite distribution in the polymer network is obtained with solvent DMSO. |
| doi_str_mv | 10.1016/j.desal.2010.04.059 |
| format | Article |
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wt.%) was used as the filler. The solvents considered were DMF (dimethyl formamide), DMSO (dimethyl sulfoxide), DMAc (dimethyl acedamide) and THF (tetrahydrofuran). The cross-sectional morphology of manufactured membranes shows three layers: a zeolite-free polymer layer, a zeolite-filled polymer layer and a skin layer. However, at the same casting content (5.4% PAN, 2.6% zeolite 13×, 92
wt.% solvent) the ratio of the thickness of these layers to total membrane thickness varies with the solvent used. The most homogeneous zeolite distribution in the polymer network is obtained with solvent DMSO.</description><subject>Applied sciences</subject><subject>Chemical engineering</subject><subject>Cross sections</subject><subject>Dimethyl</subject><subject>Dimethyl sulfoxide</subject><subject>Ethanol–water separation</subject><subject>Exact sciences and technology</subject><subject>Membrane separation (reverse osmosis, dialysis...)</subject><subject>Membranes</subject><subject>Mixed-matrix membranes</subject><subject>Morphology</subject><subject>PAN</subject><subject>Pervaporation</subject><subject>Pollution</subject><subject>Polyacrylonitriles</subject><subject>Solvent type</subject><subject>Solvents</subject><subject>Zeolites</subject><issn>0011-9164</issn><issn>1873-4464</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNp9kT9v2zAQxYkiBeo4_QRdtATtIof_RFJDhiJImwABsqQzQVPHlgZlKqRioP30PcVGxkx3PP6Oj3iPkC-Mbhhl6mq3GaC6tOEUJ1RuaNd_ICtmtGilVPKMrChlrO2Zkp_Iea07PPJeiBX5_fQHGggB_Nzk0AwR2wL7uak5HbDWJu-bGZkJSshldHsPC_gPcooztCGmBEPj8zjlioOFO7gpFzdH3Bxh3Ba3h3pBPgaXKnw-1TX59eP26eaufXj8eX_z_aH1ojdzqwI1wLQeuAzYUK-GoJ3se8ep7gwbuKFee-BCdcZ0W-8ZLDcdN8FDMGJNvh7fnUp-foE62zFWDynhJ_JLtVpxrhRVGslv75JMadb1CgURFUfUl1xrgWCnEkdX_lpG7RKA3dnXAOwSgKXSYgC4dXkScNW7FNAHH-vbKhfUCCYVctdHDtCXQ4Riq4-APg-xYCx2yPFdnf87mJ2v</recordid><startdate>20101015</startdate><enddate>20101015</enddate><creator>Şener, Tansel</creator><creator>Okumuş, Emin</creator><creator>Gürkan, Türker</creator><creator>Yilmaz, Levent</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>FR3</scope><scope>KR7</scope></search><sort><creationdate>20101015</creationdate><title>The effect of different solvents on the performance of zeolite-filled composite pervaporation membranes</title><author>Şener, Tansel ; Okumuş, Emin ; Gürkan, Türker ; Yilmaz, Levent</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c398t-6f08e177d24f8e10c6df7a499a207581d280c7ce2365885bcc1e2075528fcef83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Applied sciences</topic><topic>Chemical engineering</topic><topic>Cross sections</topic><topic>Dimethyl</topic><topic>Dimethyl sulfoxide</topic><topic>Ethanol–water separation</topic><topic>Exact sciences and technology</topic><topic>Membrane separation (reverse osmosis, dialysis...)</topic><topic>Membranes</topic><topic>Mixed-matrix membranes</topic><topic>Morphology</topic><topic>PAN</topic><topic>Pervaporation</topic><topic>Pollution</topic><topic>Polyacrylonitriles</topic><topic>Solvent type</topic><topic>Solvents</topic><topic>Zeolites</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Şener, Tansel</creatorcontrib><creatorcontrib>Okumuş, Emin</creatorcontrib><creatorcontrib>Gürkan, Türker</creatorcontrib><creatorcontrib>Yilmaz, Levent</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><jtitle>Desalination</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Şener, Tansel</au><au>Okumuş, Emin</au><au>Gürkan, Türker</au><au>Yilmaz, Levent</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The effect of different solvents on the performance of zeolite-filled composite pervaporation membranes</atitle><jtitle>Desalination</jtitle><date>2010-10-15</date><risdate>2010</risdate><volume>261</volume><issue>1</issue><spage>181</spage><epage>185</epage><pages>181-185</pages><issn>0011-9164</issn><eissn>1873-4464</eissn><coden>DSLNAH</coden><abstract>The aim of this research is to study effect of different solvents on the membrane morphology and on the performance of zeolite-filled composite pervaporation membranes. PAN (polyacrylonitrile) was used as a base polymer and zeolite 13× (32
wt.%) was used as the filler. The solvents considered were DMF (dimethyl formamide), DMSO (dimethyl sulfoxide), DMAc (dimethyl acedamide) and THF (tetrahydrofuran). The cross-sectional morphology of manufactured membranes shows three layers: a zeolite-free polymer layer, a zeolite-filled polymer layer and a skin layer. However, at the same casting content (5.4% PAN, 2.6% zeolite 13×, 92
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| ispartof | Desalination, 2010-10, Vol.261 (1), p.181-185 |
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| source | Elsevier ScienceDirect Journals |
| subjects | Applied sciences Chemical engineering Cross sections Dimethyl Dimethyl sulfoxide Ethanol–water separation Exact sciences and technology Membrane separation (reverse osmosis, dialysis...) Membranes Mixed-matrix membranes Morphology PAN Pervaporation Pollution Polyacrylonitriles Solvent type Solvents Zeolites |
| title | The effect of different solvents on the performance of zeolite-filled composite pervaporation membranes |
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