Influence of secondary formation on atmospheric occurrences of oxygenated polycyclic aromatic hydrocarbons in airborne particles

Temporal and spatial variations in concentrations of particle-associated polycyclic aromatic hydrocarbons (PAHs) and their nitrated and oxygenated derivatives (nitro-PAHs and oxy-PAHs) were investigated to assess the influence of secondary formation on atmospheric occurrences of oxy-PAHs associated...

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Veröffentlicht in:Atmospheric environment (1994) 2010-08, Vol.44 (24), p.2873-2880
Hauptverfasser: Kojima, Yuki, Inazu, Koji, Hisamatsu, Yoshiharu, Okochi, Hiroshi, Baba, Toshihide, Nagoya, Toshio
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container_end_page 2880
container_issue 24
container_start_page 2873
container_title Atmospheric environment (1994)
container_volume 44
creator Kojima, Yuki
Inazu, Koji
Hisamatsu, Yoshiharu
Okochi, Hiroshi
Baba, Toshihide
Nagoya, Toshio
description Temporal and spatial variations in concentrations of particle-associated polycyclic aromatic hydrocarbons (PAHs) and their nitrated and oxygenated derivatives (nitro-PAHs and oxy-PAHs) were investigated to assess the influence of secondary formation on atmospheric occurrences of oxy-PAHs associated with particulate matter in downtown Tokyo, Japan. The daily variation in concentration of 1,8-naphthalic anhydride (1,8-NA) in summer 2007 was similar to that for 2-nitrofluoranthene (2-NF), a representative secondary formed nitro-PAH, while the variation for benzanthrone (BA) was similar to PAHs. In addition, the concentrations of polycyclic aromatic compounds (PACs) associated with airborne particulate matter decreased in the order of PAHs > BA > 9-fluorenone (9-FO) or 9,10-anthraquinone (9,10-AQ) > 1,8-NA with an increase in distance from the roadside, whereas 2-NF was constant. These results suggest that a considerable fraction of some oxy-PAHs such as 1,8-NA associated with airborne particulate matter in downtown Tokyo originates from atmospheric secondary formation.
doi_str_mv 10.1016/j.atmosenv.2010.04.048
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subjects Airborne particles
Anhydrides
Applied sciences
Atmospheric pollution
Atmospherics
Derivatives
Exact sciences and technology
Nitro-PAHs
Oxy-PAHs
Oxygenated
PAHs
Pollutants physicochemistry study: properties, effects, reactions, transport and distribution
Pollution
Polyallylamine hydrochloride
Polycyclic aromatic hydrocarbons
Roadsides
Summer
Temporal logic
Tokyo
title Influence of secondary formation on atmospheric occurrences of oxygenated polycyclic aromatic hydrocarbons in airborne particles
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