Speciation of inorganic and organotin compounds in biological samples by liquid chromatography with inductively coupled plasma mass spectrometric detection
This paper described the effect of inorganic tin chloride on the separation of trimethyl-, tributyl- and triphenyltinchlorides by reversed-phase ion-pair high-performance liquid chromatography with detection by inductively coupled plasma mass spectrometry. The detection limits are 1.6 pg, 1.5 pg and...
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| Veröffentlicht in: | Journal of Chromatography 1993-11, Vol.654 (2), p.261-268 |
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| container_title | Journal of Chromatography |
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| creator | Kumar, Uma T. Dorsey, John G. Caruso, Joseph A. Evans, E.Hywel |
| description | This paper described the effect of inorganic tin chloride on the separation of trimethyl-, tributyl- and triphenyltinchlorides by reversed-phase ion-pair high-performance liquid chromatography with detection by inductively coupled plasma mass spectrometry. The detection limits are 1.6 pg, 1.5 pg and 2.3 pg as tin for trimethyltin, tributyltin and triphenyltin, respectively. The relative standard deviation for ten injections of 20 ng of the tin compounds was less than 5%. Inorganic tin was held strongly on the columns used, to a greater extent on the silica column compared to the polymer column. Extraction and determination of tributyltin and triphenyltin as chlorides in fish tissue (certified reference material) and tuna fish (grocery store) were performed. The recovery study from fish tissue showed an efficiency of over 90% for bothy tributyltin and triphenyltin and over 60% recovery for spiked tuna. |
| doi_str_mv | 10.1016/0021-9673(93)83369-4 |
| format | Article |
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The detection limits are 1.6 pg, 1.5 pg and 2.3 pg as tin for trimethyltin, tributyltin and triphenyltin, respectively. The relative standard deviation for ten injections of 20 ng of the tin compounds was less than 5%. Inorganic tin was held strongly on the columns used, to a greater extent on the silica column compared to the polymer column. Extraction and determination of tributyltin and triphenyltin as chlorides in fish tissue (certified reference material) and tuna fish (grocery store) were performed. The recovery study from fish tissue showed an efficiency of over 90% for bothy tributyltin and triphenyltin and over 60% recovery for spiked tuna.</description><identifier>ISSN: 0021-9673</identifier><identifier>DOI: 10.1016/0021-9673(93)83369-4</identifier><identifier>PMID: 8275180</identifier><identifier>CODEN: JOCRAM</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Agnatha. 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The detection limits are 1.6 pg, 1.5 pg and 2.3 pg as tin for trimethyltin, tributyltin and triphenyltin, respectively. The relative standard deviation for ten injections of 20 ng of the tin compounds was less than 5%. Inorganic tin was held strongly on the columns used, to a greater extent on the silica column compared to the polymer column. Extraction and determination of tributyltin and triphenyltin as chlorides in fish tissue (certified reference material) and tuna fish (grocery store) were performed. The recovery study from fish tissue showed an efficiency of over 90% for bothy tributyltin and triphenyltin and over 60% recovery for spiked tuna.</description><subject>Agnatha. Pisces</subject><subject>Animal, plant and microbial ecology</subject><subject>Animals</subject><subject>Applied ecology</subject><subject>Biological and medical sciences</subject><subject>Chromatography, High Pressure Liquid - methods</subject><subject>Ecotoxicology, biological effects of pollution</subject><subject>Effects of pollution and side effects of pesticides on vertebrates</subject><subject>Fishes</subject><subject>Food Analysis</subject><subject>Food industries</subject><subject>Food toxicology</subject><subject>Fundamental and applied biological sciences. 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Pisces</topic><topic>Animal, plant and microbial ecology</topic><topic>Animals</topic><topic>Applied ecology</topic><topic>Biological and medical sciences</topic><topic>Chromatography, High Pressure Liquid - methods</topic><topic>Ecotoxicology, biological effects of pollution</topic><topic>Effects of pollution and side effects of pesticides on vertebrates</topic><topic>Fishes</topic><topic>Food Analysis</topic><topic>Food industries</topic><topic>Food toxicology</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>Mass Spectrometry - methods</topic><topic>Organotin Compounds - analysis</topic><topic>Reproducibility of Results</topic><topic>Tin Compounds - analysis</topic><topic>Tuna</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kumar, Uma T.</creatorcontrib><creatorcontrib>Dorsey, John G.</creatorcontrib><creatorcontrib>Caruso, Joseph A.</creatorcontrib><creatorcontrib>Evans, E.Hywel</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aqualine</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of Chromatography</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kumar, Uma T.</au><au>Dorsey, John G.</au><au>Caruso, Joseph A.</au><au>Evans, E.Hywel</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Speciation of inorganic and organotin compounds in biological samples by liquid chromatography with inductively coupled plasma mass spectrometric detection</atitle><jtitle>Journal of Chromatography</jtitle><addtitle>J Chromatogr A</addtitle><date>1993-11-19</date><risdate>1993</risdate><volume>654</volume><issue>2</issue><spage>261</spage><epage>268</epage><pages>261-268</pages><issn>0021-9673</issn><coden>JOCRAM</coden><abstract>This paper described the effect of inorganic tin chloride on the separation of trimethyl-, tributyl- and triphenyltinchlorides by reversed-phase ion-pair high-performance liquid chromatography with detection by inductively coupled plasma mass spectrometry. The detection limits are 1.6 pg, 1.5 pg and 2.3 pg as tin for trimethyltin, tributyltin and triphenyltin, respectively. The relative standard deviation for ten injections of 20 ng of the tin compounds was less than 5%. Inorganic tin was held strongly on the columns used, to a greater extent on the silica column compared to the polymer column. Extraction and determination of tributyltin and triphenyltin as chlorides in fish tissue (certified reference material) and tuna fish (grocery store) were performed. The recovery study from fish tissue showed an efficiency of over 90% for bothy tributyltin and triphenyltin and over 60% recovery for spiked tuna.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><pmid>8275180</pmid><doi>10.1016/0021-9673(93)83369-4</doi><tpages>8</tpages></addata></record> |
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| subjects | Agnatha. Pisces Animal, plant and microbial ecology Animals Applied ecology Biological and medical sciences Chromatography, High Pressure Liquid - methods Ecotoxicology, biological effects of pollution Effects of pollution and side effects of pesticides on vertebrates Fishes Food Analysis Food industries Food toxicology Fundamental and applied biological sciences. Psychology Mass Spectrometry - methods Organotin Compounds - analysis Reproducibility of Results Tin Compounds - analysis Tuna |
| title | Speciation of inorganic and organotin compounds in biological samples by liquid chromatography with inductively coupled plasma mass spectrometric detection |
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