Unprecedented Solution-Stable Silver(I) Ethynediyl Clusters
Rise of the silver surfer: A novel solution‐stable silver ethynediyl complex [Ag7(C2)(CF3CO2)5(bpy)5]⋅MeCN⋅ 0.5 MeOH (bpy=2,2′‐bipyridine) was prepared by reacting Me3SiCCH with [Ag(bpy)CF3CO2] in methanol (see figure). This complex represents the first example of a solution‐stable silver ethynediy...
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| Veröffentlicht in: | Chemistry : a European journal 2010-11, Vol.16 (41), p.12321-12323 |
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| container_issue | 41 |
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| container_title | Chemistry : a European journal |
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| creator | Wu, Hua-Bin Huang, Zhi-Jun Wang, Quan-Ming |
| description | Rise of the silver surfer: A novel solution‐stable silver ethynediyl complex [Ag7(C2)(CF3CO2)5(bpy)5]⋅MeCN⋅ 0.5 MeOH (bpy=2,2′‐bipyridine) was prepared by reacting Me3SiCCH with [Ag(bpy)CF3CO2] in methanol (see figure). This complex represents the first example of a solution‐stable silver ethynediyl cluster, and it is yellow emissive in MeCN/MeOH at 77 K. |
| doi_str_mv | 10.1002/chem.201001985 |
| format | Article |
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This complex represents the first example of a solution‐stable silver ethynediyl cluster, and it is yellow emissive in MeCN/MeOH at 77 K.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201001985</identifier><identifier>PMID: 20853296</identifier><identifier>CODEN: CEUJED</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Chemistry ; cluster compounds ; diimine ligands ; ethynediyl ligands ; luminescence ; silver</subject><ispartof>Chemistry : a European journal, 2010-11, Vol.16 (41), p.12321-12323</ispartof><rights>Copyright © 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2010 WILEY-VCH Verlag GmbH & Co. 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Eur. J</addtitle><description>Rise of the silver surfer: A novel solution‐stable silver ethynediyl complex [Ag7(C2)(CF3CO2)5(bpy)5]⋅MeCN⋅ 0.5 MeOH (bpy=2,2′‐bipyridine) was prepared by reacting Me3SiCCH with [Ag(bpy)CF3CO2] in methanol (see figure). This complex represents the first example of a solution‐stable silver ethynediyl cluster, and it is yellow emissive in MeCN/MeOH at 77 K.</description><subject>Chemistry</subject><subject>cluster compounds</subject><subject>diimine ligands</subject><subject>ethynediyl ligands</subject><subject>luminescence</subject><subject>silver</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqFkEtLI0EURgtx0PjYupSAi3EWHevR9cKVhkzMEF9EcVlUV25ja6U7U9Wt5t9Ph2SCuBEu3Ls438flIHREcI9gTM_cM8x6FLc30YpvoQ7hlCRMCr6NOlinMhGc6V20F-MLxlgLxnbQLsWKM6pFB50_lvMADqZQ1jDtTirf1EVVJpPaZh66k8K_QTgd_eoO6udFCdNi4bt938QaQjxAP3LrIxyu9z56_D146F8l49vhqH8xTlxKME9yYFJjTQWkFmc6p7IdlVJqpUtVRgm3jAlHpbXa6jwXJLOZcip1JBVcAdtHP1e981D9bSDWZlZEB97bEqomGikIZlRg3ZInX8iXqgll-5whUgixtMRbqreiXKhiDJCbeShmNiwMwWZp1Sytmo3VNnC8rm2yGUw3-H-NLaBXwHvhYfFNnelfDa4_lyerbNFK_dhkbXg1QjLJzdPN0Ch1f3c5-YPNmP0DZCKQ6w</recordid><startdate>20101102</startdate><enddate>20101102</enddate><creator>Wu, Hua-Bin</creator><creator>Huang, Zhi-Jun</creator><creator>Wang, Quan-Ming</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope></search><sort><creationdate>20101102</creationdate><title>Unprecedented Solution-Stable Silver(I) Ethynediyl Clusters</title><author>Wu, Hua-Bin ; Huang, Zhi-Jun ; Wang, Quan-Ming</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4105-fe3790926e4a0b9f27f278422a7c48b215a336c27aa9a9ff61bab8c84c14658e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Chemistry</topic><topic>cluster compounds</topic><topic>diimine ligands</topic><topic>ethynediyl ligands</topic><topic>luminescence</topic><topic>silver</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wu, Hua-Bin</creatorcontrib><creatorcontrib>Huang, Zhi-Jun</creatorcontrib><creatorcontrib>Wang, Quan-Ming</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wu, Hua-Bin</au><au>Huang, Zhi-Jun</au><au>Wang, Quan-Ming</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Unprecedented Solution-Stable Silver(I) Ethynediyl Clusters</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chem. Eur. J</addtitle><date>2010-11-02</date><risdate>2010</risdate><volume>16</volume><issue>41</issue><spage>12321</spage><epage>12323</epage><pages>12321-12323</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><coden>CEUJED</coden><abstract>Rise of the silver surfer: A novel solution‐stable silver ethynediyl complex [Ag7(C2)(CF3CO2)5(bpy)5]⋅MeCN⋅ 0.5 MeOH (bpy=2,2′‐bipyridine) was prepared by reacting Me3SiCCH with [Ag(bpy)CF3CO2] in methanol (see figure). This complex represents the first example of a solution‐stable silver ethynediyl cluster, and it is yellow emissive in MeCN/MeOH at 77 K.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>20853296</pmid><doi>10.1002/chem.201001985</doi><tpages>3</tpages></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Chemistry cluster compounds diimine ligands ethynediyl ligands luminescence silver |
| title | Unprecedented Solution-Stable Silver(I) Ethynediyl Clusters |
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