Persistent Metal Bis(Hexafluoroacetylacetonato) Complexes Featuring a 2,2′-Bipyridine Substituted Triarylamminium Radical Cation

Herein, we describe the preparation of a 2,2′-bipyridine derivative containing a redox-active N,N′-(4,4′-dimethoxydiphenylamino) substituent (1), which readily coordinates M(hfac)2 salts [M = Mn (2), Ni (3), Cu (4)] to generate stable, neutral, and pseudo-octahedral coordination complexes, which hav...

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Veröffentlicht in:	Inorganic chemistry 2010-11, Vol.49 (21), p.10183-10190
Hauptverfasser:	Adugna, Sharew, Revunova, Kseniya, Djukic, Brandon, Gorelsky, Serge I, Jenkins, Hilary A, Lemaire, Martin T
Format:	Artikel
Sprache:	eng
Schlagworte:	2,2'-Dipyridyl - chemistry Cations - chemistry Crystallography, X-Ray Free Radicals - chemistry Hydrocarbons, Fluorinated - chemistry Models, Molecular Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Pentanones - chemistry Stereoisomerism
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