Polysiloxanes containing polyhedral oligomeric silsesquioxane groups in the side chains; synthesis and properties
Linear polysiloxanes having different amounts of polyhedral oligomeric silsequioxane (POSS) side groups were prepared from the hydrosilylation reaction of poly(ethylhydrosiloxane) with different amount of POSS and 1-octene using platinum(0)-divinyl tetramethyldisiloxane as a catayst. 1-Octene and pl...
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| Veröffentlicht in: | Polymer (Guilford) 2010-05, Vol.51 (11), p.2296-2304 |
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| creator | Ryu, Hyun-Soo Kim, Dong-Gyun Lee, Jong-Chan |
| description | Linear polysiloxanes having different amounts of polyhedral oligomeric silsequioxane (POSS) side groups were prepared from the hydrosilylation reaction of poly(ethylhydrosiloxane) with different amount of POSS and 1-octene using platinum(0)-divinyl tetramethyldisiloxane as a catayst. 1-Octene and platinum(0)-divinyl tetramethyldisiloxane were found to be very important for the preparation of the linear polymer without any cross-linked structures. The linear polysiloxanes with POSS side groups are soluble in various organic solvents. When the content of POSS-containing monomeric unit is larger than 10 mol%, free standing films can be prepared from a routine solution casting method, although this polysiloxane is not cross-linked.
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| doi_str_mv | 10.1016/j.polymer.2010.01.066 |
| format | Article |
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[Display omitted]</description><subject>Applied sciences</subject><subject>Chains (polymeric)</subject><subject>Chemical modifications</subject><subject>Crosslinking</subject><subject>Exact sciences and technology</subject><subject>Hydrosilylation</subject><subject>Inorganic and organomineral polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polyhedral oligomeric silsesquioxane</subject><subject>Polyhedral oligomeric silsesquioxane (POSS)</subject><subject>Polysiloxanes</subject><subject>Routines</subject><subject>Solvents</subject><subject>Synthesis</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqFkM2rEzEUxYMoWJ_-CUI24mpqvmaa4kLk8fyAB7rQdcgkd9qUaTLNnYr9771ji1tXgZtzfufew9hrKdZSyO7dYT2V8XKEulaCZkKuRdc9YStpN7pRaiufspUQWjXadvI5e4F4EEKoVpkVO30nK6ax_PYZkIeSZ59yyju-MPcQqx95GdOuED8FTlIEPJ3TXwPf1XKekKfM5z3QZwQe9gTA9xwvmWaYkPsc-VTLBHVOgC_Zs8ET5NXtvWM_Pz38uP_SPH77_PX-42MTjN7MTSt03w4QbYDeSu2N8Fb1ArzujLW294KOHWKnw1aZaAxENWiQojV92EZy37G3Vy5Fn86AszsmDDCOtHc5o9t0RDDCKlK2V2WoBbHC4Kaajr5enBRuadgd3K1htzTshHTUMPne3BI8Bj8O1eeQ8J95ad5Ku2zy4aoDOvdXIgqGBDlATBXC7GJJ_0n6A68hl-A</recordid><startdate>20100514</startdate><enddate>20100514</enddate><creator>Ryu, Hyun-Soo</creator><creator>Kim, Dong-Gyun</creator><creator>Lee, Jong-Chan</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope></search><sort><creationdate>20100514</creationdate><title>Polysiloxanes containing polyhedral oligomeric silsesquioxane groups in the side chains; synthesis and properties</title><author>Ryu, Hyun-Soo ; Kim, Dong-Gyun ; Lee, Jong-Chan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c437t-503b5fed8ceb813a40a82b0ea364888ba0201fd63c924d44ed2f3e1054bc9d503</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Applied sciences</topic><topic>Chains (polymeric)</topic><topic>Chemical modifications</topic><topic>Crosslinking</topic><topic>Exact sciences and technology</topic><topic>Hydrosilylation</topic><topic>Inorganic and organomineral polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polyhedral oligomeric silsesquioxane</topic><topic>Polyhedral oligomeric silsesquioxane (POSS)</topic><topic>Polysiloxanes</topic><topic>Routines</topic><topic>Solvents</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ryu, Hyun-Soo</creatorcontrib><creatorcontrib>Kim, Dong-Gyun</creatorcontrib><creatorcontrib>Lee, Jong-Chan</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer (Guilford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ryu, Hyun-Soo</au><au>Kim, Dong-Gyun</au><au>Lee, Jong-Chan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polysiloxanes containing polyhedral oligomeric silsesquioxane groups in the side chains; synthesis and properties</atitle><jtitle>Polymer (Guilford)</jtitle><date>2010-05-14</date><risdate>2010</risdate><volume>51</volume><issue>11</issue><spage>2296</spage><epage>2304</epage><pages>2296-2304</pages><issn>0032-3861</issn><eissn>1873-2291</eissn><coden>POLMAG</coden><abstract>Linear polysiloxanes having different amounts of polyhedral oligomeric silsequioxane (POSS) side groups were prepared from the hydrosilylation reaction of poly(ethylhydrosiloxane) with different amount of POSS and 1-octene using platinum(0)-divinyl tetramethyldisiloxane as a catayst. 1-Octene and platinum(0)-divinyl tetramethyldisiloxane were found to be very important for the preparation of the linear polymer without any cross-linked structures. The linear polysiloxanes with POSS side groups are soluble in various organic solvents. When the content of POSS-containing monomeric unit is larger than 10 mol%, free standing films can be prepared from a routine solution casting method, although this polysiloxane is not cross-linked.
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| source | Elsevier ScienceDirect Journals |
| subjects | Applied sciences Chains (polymeric) Chemical modifications Crosslinking Exact sciences and technology Hydrosilylation Inorganic and organomineral polymers Physicochemistry of polymers Polyhedral oligomeric silsesquioxane Polyhedral oligomeric silsesquioxane (POSS) Polysiloxanes Routines Solvents Synthesis |
| title | Polysiloxanes containing polyhedral oligomeric silsesquioxane groups in the side chains; synthesis and properties |
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