Structure and Ultrafast Dynamics of the Charge-Transfer Excited State and Redox Activity of the Ground State of Mono- and Binuclear Platinum(II) Diimine Catecholate and Bis-catecholate Complexes: A Transient Absorption, TRIR, DFT, and Electrochemical Study

A series of mononuclear complexes of the type [Pt(Bu2cat)(4,4′-R2-bipy)] [where Bu2cat is the dianion of 3,5- t Bu2-catechol and R = H, t Bu, or C(O)NEt2] and analogous dinuclear complexes based on the “back-to-back” bis-catechol ligand 3,3′,4,4′-tetrahydroxybiphenyl have been studied in detail in b...

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Veröffentlicht in:	Inorganic chemistry 2010-11, Vol.49 (21), p.10041-10056
Hauptverfasser:	Best, Jonathan, Sazanovich, Igor V, Adams, Harry, Bennett, Robert D, Davies, E. Stephen, Meijer, Anthony J. H. M, Towrie, Michael, Tikhomirov, Sergei A, Bouganov, Oleg V, Ward, Michael D, Weinstein, Julia A
Format:	Artikel
Sprache:	eng
Schlagworte:	Catechols - chemical synthesis Catechols - chemistry Crystallography, X-Ray Electrochemistry Models, Molecular Molecular Structure Organoplatinum Compounds - chemical synthesis Organoplatinum Compounds - chemistry Oxidation-Reduction Quantum Theory Spectrophotometry, Infrared Time Factors Vibration
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