Liberation of Cellulose from the Lignin Cage: A Catalytic Pretreatment Method for the Production of Cellulosic Ethanol
Catalytic pretreatment of lignocellulosic materials with a copper(II) phenanthroline catalyst is an efficient and selective method for the isolation of cellulose. The method loosens the wood matrix and liberates cellulose with high yields. The use of a catalyst, water as solvent, and oxygen as oxida...
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| Veröffentlicht in: | ChemSusChem 2010-10, Vol.3 (10), p.1142-1145 |
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| creator | Hakola, Maija Kallioinen, Anne Kemell, Marianna Lahtinen, Petro Lankinen, Elina Leskelä, Markku Repo, Timo Riekkola, Tiina Siika-aho, Matti Uusitalo, Jaana Vuorela, Satu von Weymarn, Niklas |
| description | Catalytic pretreatment of lignocellulosic materials with a copper(II) phenanthroline catalyst is an efficient and selective method for the isolation of cellulose. The method loosens the wood matrix and liberates cellulose with high yields. The use of a catalyst, water as solvent, and oxygen as oxidant make this process a promising and sustainable method to obtain biofuels. |
| doi_str_mv | 10.1002/cssc.201000217 |
| format | Article |
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The use of a catalyst, water as solvent, and oxygen as oxidant make this process a promising and sustainable method to obtain biofuels.</description><subject>Biocatalysis</subject><subject>Biofuels</subject><subject>biomass</subject><subject>Biotechnology - methods</subject><subject>catalysis</subject><subject>Cellulose - chemistry</subject><subject>Copper - chemistry</subject><subject>Energy-Generating Resources</subject><subject>Ethanol - chemical synthesis</subject><subject>Ethanol - chemistry</subject><subject>hydrolysis</subject><subject>Lignin - chemistry</subject><subject>Organometallic Compounds - chemistry</subject><subject>oxidation</subject><subject>Oxygen - chemistry</subject><subject>Phenanthrolines - chemistry</subject><subject>Solvents - chemistry</subject><subject>Water - chemistry</subject><subject>Wood</subject><issn>1864-5631</issn><issn>1864-564X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkE1v1DAURS0EoqWwZYm8Y5WpHX_F7ErUTiumMFJBsLMc57kTSOJiO9D5902ZMqrYsHp3cc7V00XoNSULSkh57FJyi5LMmZRUPUGHtJK8EJJ_e7rPjB6gFyl9J0QSLeVzdFCSSjCmy0P0a9U1EG3uwoiDxzX0_dSHBNjHMOC8AbzqrsduxLW9hnf4ZL7Z9tvcObyOkCPYPMCY8SXkTWixD_GPtI6hndy_rbN0mjd2DP1L9MzbPsGrh3uEvpydfq7Pi9Wn5UV9siocr4QqlOdKCuFd2bSttE2lW-6YVlooCk0DHrTXLZVMtboVlltdyZKRkgMl2nrOjtDbXe9NDD8nSNkMXXLzO3aEMCWjhK6UZJLM5GJHuhhSiuDNTewGG7eGEnM_tbmf2uynnoU3D9VTM0C7x_9uOwN6B_zuetj-p87UV1f14_Ji53Ypw-3etfGHkYopYb5-XBpyuZb8_fKDOWN30YmbDw</recordid><startdate>20101025</startdate><enddate>20101025</enddate><creator>Hakola, Maija</creator><creator>Kallioinen, Anne</creator><creator>Kemell, Marianna</creator><creator>Lahtinen, Petro</creator><creator>Lankinen, Elina</creator><creator>Leskelä, Markku</creator><creator>Repo, Timo</creator><creator>Riekkola, Tiina</creator><creator>Siika-aho, Matti</creator><creator>Uusitalo, Jaana</creator><creator>Vuorela, Satu</creator><creator>von Weymarn, Niklas</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20101025</creationdate><title>Liberation of Cellulose from the Lignin Cage: A Catalytic Pretreatment Method for the Production of Cellulosic Ethanol</title><author>Hakola, Maija ; 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| source | MEDLINE; Wiley Online Library Journals Frontfile Complete |
| subjects | Biocatalysis Biofuels biomass Biotechnology - methods catalysis Cellulose - chemistry Copper - chemistry Energy-Generating Resources Ethanol - chemical synthesis Ethanol - chemistry hydrolysis Lignin - chemistry Organometallic Compounds - chemistry oxidation Oxygen - chemistry Phenanthrolines - chemistry Solvents - chemistry Water - chemistry Wood |
| title | Liberation of Cellulose from the Lignin Cage: A Catalytic Pretreatment Method for the Production of Cellulosic Ethanol |
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