Synthesis of Cortol 3-Glucuronides and Cortolone 3-Glucuronides

The synthesis of the 3-glucuronides of 20α-cortolone and their 20β-epimers is described. The cortol 20, 21-diacetates (3, 10) and cortolone 20, 21-diacetates (6, 12) were the key intermediates. Sodium borohydride reduction of the carbonyl group at C-20 in 21-acetoxy-3α, 11β, 17α-trihydroxy-5β-pregna...

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Veröffentlicht in:	Chemical & pharmaceutical bulletin 1984/10/25, Vol.32(10), pp.4023-4028
Hauptverfasser:	HOSODA, HIROSHI, YOKOHAMA, HIROMITSU, NAMBARA, TOSHIO
Format:	Artikel
Sprache:	eng
Schlagworte:	Alicyclic compounds, terpenoids, prostaglandins, steroids Chemical Phenomena Chemistry Exact sciences and technology Glucuronates - chemical synthesis Koenigs-Knorr reaction Organic chemistry Pregnanes - chemical synthesis Preparations and properties Steroids
Online-Zugang:	Volltext
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