Reusable polystyrene-supported Pd catalyst for Mizoroki-Heck reactions with extremely low amounts of supported Pd

Reusable polystyrene-supported Pd catalyst for Mizoroki-Heck reactions with extremely low amounts of supported Pd

In this communication, we report that by running Mizoroki-Heck reactions of various aryl iodides in toluene-DMF, only extremely low amounts of supported Pd (0.04 mequiv.) are required to obtain almost quantitative yields. The catalyst was reused successfully up to three times.

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Veröffentlicht in:Organic & biomolecular chemistry 2010-11, Vol.8 (21), p.4834-4836
Hauptverfasser: Diebold, Carine, Schweizer, Stéphane, Becht, Jean-Michel, Le Drian, Claude
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container_issue 21
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container_title Organic & biomolecular chemistry
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creator Diebold, Carine
Schweizer, Stéphane
Becht, Jean-Michel
Le Drian, Claude
description In this communication, we report that by running Mizoroki-Heck reactions of various aryl iodides in toluene-DMF, only extremely low amounts of supported Pd (0.04 mequiv.) are required to obtain almost quantitative yields. The catalyst was reused successfully up to three times.
doi_str_mv 10.1039/c0ob00523a
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title Reusable polystyrene-supported Pd catalyst for Mizoroki-Heck reactions with extremely low amounts of supported Pd
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