Communication: The application of the global isomorphism to the study of liquid-vapor equilibrium in two and three-dimensional Lennard-Jones fluids

Communication: The application of the global isomorphism to the study of liquid-vapor equilibrium in two and three-dimensional Lennard-Jones fluids

We analyze the interrelation between the coexistence curve of the Lennard-Jones fluid and the Ising model in two and three dimensions within the global isomorphism approach proposed earlier [V. L. Kulinskii, J. Phys. Chem. B 114, 2852 (2010)]. In case of two dimensions, we use the exact Onsager resu...

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Veröffentlicht in:The Journal of chemical physics 2010-10, Vol.133 (13), p.131102-131102
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description We analyze the interrelation between the coexistence curve of the Lennard-Jones fluid and the Ising model in two and three dimensions within the global isomorphism approach proposed earlier [V. L. Kulinskii, J. Phys. Chem. B 114, 2852 (2010)]. In case of two dimensions, we use the exact Onsager result to construct the binodal of the corresponding Lennard-Jones fluid and compare it with the results of the simulations. In the three-dimensional case, we use available numerical results for the Ising model for the corresponding mapping. The possibility to observe the singularity of the binodal diameter is discussed.
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title Communication: The application of the global isomorphism to the study of liquid-vapor equilibrium in two and three-dimensional Lennard-Jones fluids
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