O-(2-tert-Butyl-6-dimethylthiocarbamoyl-4-methylphenyl) N, N-dimethylthiocarbamate dichloromethane solvate
In the title compound, C(17)H(26)N(2)OS(2).CH(2)Cl(2), the C=S distances are 1.650 (4) and 1.679 (3) A, and the torsion angle between the planes of the thiocarbamate and carbonothioyl fragments is 54.4 (2) degrees. The steric and electronic effects that these substituents exert on one another determ...
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| Veröffentlicht in: | Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2003-10, Vol.59 (Pt 10), p.o577-o579 |
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| container_end_page | o579 |
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| container_issue | Pt 10 |
| container_start_page | o577 |
| container_title | Acta crystallographica. Section C, Crystal structure communications |
| container_volume | 59 |
| creator | CASTILLO, Ivan FLORES-FIGUEROA, Aaron HERNANDEZ-ORTEGA, Simon |
| description | In the title compound, C(17)H(26)N(2)OS(2).CH(2)Cl(2), the C=S distances are 1.650 (4) and 1.679 (3) A, and the torsion angle between the planes of the thiocarbamate and carbonothioyl fragments is 54.4 (2) degrees. The steric and electronic effects that these substituents exert on one another determine the observed anti configuration with respect to the phenyl C atoms to which they are attached. |
| doi_str_mv | 10.1107/s010827010301905x |
| format | Article |
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The steric and electronic effects that these substituents exert on one another determine the observed anti configuration with respect to the phenyl C atoms to which they are attached.</description><identifier>ISSN: 0108-2701</identifier><identifier>EISSN: 1600-5759</identifier><identifier>DOI: 10.1107/s010827010301905x</identifier><identifier>PMID: 14532676</identifier><identifier>CODEN: ACSCEE</identifier><language>eng</language><publisher>Oxford: Blackwell</publisher><subject>Aliphatic, non-condensed and condensed benzenic, and alicyclic compounds ; Condensed matter: structure, mechanical and thermal properties ; Exact sciences and technology ; Organic compounds ; Physics ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids</subject><ispartof>Acta crystallographica. 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Section C, Crystal structure communications</title><addtitle>Acta Crystallogr C</addtitle><description>In the title compound, C(17)H(26)N(2)OS(2).CH(2)Cl(2), the C=S distances are 1.650 (4) and 1.679 (3) A, and the torsion angle between the planes of the thiocarbamate and carbonothioyl fragments is 54.4 (2) degrees. The steric and electronic effects that these substituents exert on one another determine the observed anti configuration with respect to the phenyl C atoms to which they are attached.</description><subject>Aliphatic, non-condensed and condensed benzenic, and alicyclic compounds</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Exact sciences and technology</subject><subject>Organic compounds</subject><subject>Physics</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><issn>0108-2701</issn><issn>1600-5759</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><recordid>eNptkF1LwzAUhoMobk5_gDeyG0XBaD6aZL3U4ReM7UIF70qaJrQjXWbSiv33pqwgiDc54X2fc5LzAnCK0Q3GSNwGhNGMiHhShFPEvvfAGHOEIBMs3Qfj3oa9PwJHIawRQoQQeghGOGGUcMHHYL2ClwQ22jfwvm06Czksqlo3ZWebsnJK-lzWLuoJ3KnbUm86ezVdXk-X_6Cy0dOiUqV13vWe3OhpcPYr6sfgwEgb9MlQJ-D98eFt_gwXq6eX-d0CKpIgDgUXeaJmuYqrKS0SxiXGOl4kNmwmlREJkQbnJGUpNVLlqREK00Sk2hSIEjoBF7u5W-8-Wx2arK6C0tbGv7g2ZIIJzjnFEcQ7UHkXgtcm2_qqlr7LMMr6gLPXPwF_xJ6zYXib17r47RgSjcD5AMigpDVeblQVfjlGEO4f_wHEZoP7</recordid><startdate>200310</startdate><enddate>200310</enddate><creator>CASTILLO, Ivan</creator><creator>FLORES-FIGUEROA, Aaron</creator><creator>HERNANDEZ-ORTEGA, Simon</creator><general>Blackwell</general><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>200310</creationdate><title>O-(2-tert-Butyl-6-dimethylthiocarbamoyl-4-methylphenyl) N, N-dimethylthiocarbamate dichloromethane solvate</title><author>CASTILLO, Ivan ; FLORES-FIGUEROA, Aaron ; HERNANDEZ-ORTEGA, Simon</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2406-767b4c8bc082ce7456a11ee74a1f58acf742af1b29593facb9f7c13479efd0323</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>Aliphatic, non-condensed and condensed benzenic, and alicyclic compounds</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Exact sciences and technology</topic><topic>Organic compounds</topic><topic>Physics</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>CASTILLO, Ivan</creatorcontrib><creatorcontrib>FLORES-FIGUEROA, Aaron</creatorcontrib><creatorcontrib>HERNANDEZ-ORTEGA, Simon</creatorcontrib><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Acta crystallographica. 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Section C, Crystal structure communications</jtitle><addtitle>Acta Crystallogr C</addtitle><date>2003-10</date><risdate>2003</risdate><volume>59</volume><issue>Pt 10</issue><spage>o577</spage><epage>o579</epage><pages>o577-o579</pages><issn>0108-2701</issn><eissn>1600-5759</eissn><coden>ACSCEE</coden><abstract>In the title compound, C(17)H(26)N(2)OS(2).CH(2)Cl(2), the C=S distances are 1.650 (4) and 1.679 (3) A, and the torsion angle between the planes of the thiocarbamate and carbonothioyl fragments is 54.4 (2) degrees. The steric and electronic effects that these substituents exert on one another determine the observed anti configuration with respect to the phenyl C atoms to which they are attached.</abstract><cop>Oxford</cop><pub>Blackwell</pub><pmid>14532676</pmid><doi>10.1107/s010827010301905x</doi></addata></record> |
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| identifier | ISSN: 0108-2701 |
| ispartof | Acta crystallographica. Section C, Crystal structure communications, 2003-10, Vol.59 (Pt 10), p.o577-o579 |
| issn | 0108-2701 1600-5759 |
| language | eng |
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| source | Wiley Online Library All Journals |
| subjects | Aliphatic, non-condensed and condensed benzenic, and alicyclic compounds Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Organic compounds Physics Structure of solids and liquids crystallography Structure of specific crystalline solids |
| title | O-(2-tert-Butyl-6-dimethylthiocarbamoyl-4-methylphenyl) N, N-dimethylthiocarbamate dichloromethane solvate |
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