Chiral Hydroperoxides as Oxygen Source in the Catalytic Stereoselective Epoxidation of Allylic Alcohols by Sandwich-Type Polyoxometalates:  Control of Enantioselectivity through a Metal-Coordinated Template

The epoxidation of allylic alcohols is shown to be efficiently and selectively catalyzed by the oxidatively resistant sandwich-type polyoxometalates, POMs, namely [WZnM2(ZnW9O34)2] q - [M = OV(IV), Mn(II), Ru(III), Fe(III), Pd(II), Pt(II), Zn(II); q = 10−12], with organic hydroperoxides as oxygen so...

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Veröffentlicht in:	Journal of organic chemistry 2003-10, Vol.68 (21), p.8222-8231
Hauptverfasser:	Adam, Waldemar, Alsters, Paul L, Neumann, Ronny, Saha-Möller, Chantu R, Seebach, Dieter, Beck, Albert K, Zhang, Rui
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Catalytic reactions Chemistry Exact sciences and technology General and physical chemistry Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Online-Zugang:	Volltext
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