Phosphorus Retention Mechanisms of a Water Treatment Residual
ABSTRACT Water treatment residuals (WTRs) are a by‐product of municipal drinking water treatment plants and can have the capacity to adsorb tremendous amounts of P. Understanding the WTR phosphorus adsorption process is important for discerning the mechanism and tenacity of P retention. We studied P...
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Veröffentlicht in: | Journal of environmental quality 2003-09, Vol.32 (5), p.1857-1864 |
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description | ABSTRACT
Water treatment residuals (WTRs) are a by‐product of municipal drinking water treatment plants and can have the capacity to adsorb tremendous amounts of P. Understanding the WTR phosphorus adsorption process is important for discerning the mechanism and tenacity of P retention. We studied P adsorbing mechanism(s) of an aluminum‐based [Al2(SO4)3·14H2O] WTR from Englewood, CO. In a laboratory study, we shook mixtures of P‐loaded WTR for 1 to 211 d followed by solution pH analysis, and solution Ca, Al, and P analysis via inductively coupled plasma atomic emission spectroscopy. After shaking periods, we also examined the solids fraction by X‐ray diffraction (XRD) and electron microprobe analysis using wavelength dispersive spectroscopy (EMPA–WDS). The shaking results indicated an increase in pH from 7.2 to 8.2, an increase in desorbed Ca and Al concentrations, and a decrease in desorbed P concentration. The pH and desorbed Ca concentration increases suggested that CaCO3 controlled Ca solubility. Increased desorbed Al concentration may have been due to Al OH −4 formation. Decreased P content, in conjunction with the pH increase, was consistent with calcium phosphate formation or precipitation. The system appeared to be undersaturated with respect to dicalcium phosphate (DCP; CaHPO4) and supersaturated with respect to octacalcium phosphate [OCP; Ca4H(PO4)3·2.5H2O]. The Ca and Al increases, as well as OCP formation, were supported by MINTEQA2 modeling. The XRD and EMPA–WDS results for all shaking times, however, suggested surface P chemisorption as an amorphous Al–P mineral phase. |
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Water treatment residuals (WTRs) are a by‐product of municipal drinking water treatment plants and can have the capacity to adsorb tremendous amounts of P. Understanding the WTR phosphorus adsorption process is important for discerning the mechanism and tenacity of P retention. We studied P adsorbing mechanism(s) of an aluminum‐based [Al2(SO4)3·14H2O] WTR from Englewood, CO. In a laboratory study, we shook mixtures of P‐loaded WTR for 1 to 211 d followed by solution pH analysis, and solution Ca, Al, and P analysis via inductively coupled plasma atomic emission spectroscopy. After shaking periods, we also examined the solids fraction by X‐ray diffraction (XRD) and electron microprobe analysis using wavelength dispersive spectroscopy (EMPA–WDS). The shaking results indicated an increase in pH from 7.2 to 8.2, an increase in desorbed Ca and Al concentrations, and a decrease in desorbed P concentration. The pH and desorbed Ca concentration increases suggested that CaCO3 controlled Ca solubility. Increased desorbed Al concentration may have been due to Al OH −4 formation. Decreased P content, in conjunction with the pH increase, was consistent with calcium phosphate formation or precipitation. The system appeared to be undersaturated with respect to dicalcium phosphate (DCP; CaHPO4) and supersaturated with respect to octacalcium phosphate [OCP; Ca4H(PO4)3·2.5H2O]. The Ca and Al increases, as well as OCP formation, were supported by MINTEQA2 modeling. The XRD and EMPA–WDS results for all shaking times, however, suggested surface P chemisorption as an amorphous Al–P mineral phase.</description><identifier>ISSN: 0047-2425</identifier><identifier>EISSN: 1537-2537</identifier><identifier>DOI: 10.2134/jeq2003.1857</identifier><identifier>PMID: 14535330</identifier><identifier>CODEN: JEVQAA</identifier><language>eng</language><publisher>Madison: American Society of Agronomy, Crop Science Society of America, Soil Science Society</publisher><subject>Adsorption ; Agronomy. Soil science and plant productions ; Aluminum ; Aluminum - chemistry ; Aluminum sulfate ; Applied sciences ; Biological and medical sciences ; Calcium Carbonate - chemistry ; Calcium phosphates ; Chemical industry and chemicals ; Drinking water ; Drinking water and swimming-pool water. Desalination ; Emission spectroscopy ; Exact sciences and technology ; Fertilisers ; Fundamental and applied biological sciences. Psychology ; General agronomy. Plant production ; Hydrogen-Ion Concentration ; Industrial chemicals ; Nitrogen, phosphorus, potassium fertilizations ; Phosphates - chemistry ; Phosphorus - analysis ; Phosphorus - isolation & purification ; Phosphorus fertilization ; Pollution ; Retention ; Soil-plant relationships. Soil fertility. Fertilization. Amendments ; Solubility ; Waste Disposal, Fluid - methods ; Water Supply ; Water treatment ; Water treatment and pollution ; Water treatment plants ; X-ray diffraction</subject><ispartof>Journal of environmental quality, 2003-09, Vol.32 (5), p.1857-1864</ispartof><rights>ASA, CSSA, SSSA</rights><rights>2004 INIST-CNRS</rights><rights>Copyright American Society of Agronomy Sep/Oct 2003</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4897-b3f4414a4109aa868401b9af9c9db78bbabdc8479c903267b0e6893eced049733</citedby><cites>FETCH-LOGICAL-c4897-b3f4414a4109aa868401b9af9c9db78bbabdc8479c903267b0e6893eced049733</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.2134%2Fjeq2003.1857$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.2134%2Fjeq2003.1857$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,782,786,1419,27931,27932,45581,45582</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=15130107$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/14535330$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ippolito, J. A.</creatorcontrib><creatorcontrib>Barbarick, K. A.</creatorcontrib><creatorcontrib>Heil, D. M.</creatorcontrib><creatorcontrib>Chandler, J. P.</creatorcontrib><creatorcontrib>Redente, E. F.</creatorcontrib><title>Phosphorus Retention Mechanisms of a Water Treatment Residual</title><title>Journal of environmental quality</title><addtitle>J Environ Qual</addtitle><description>ABSTRACT
Water treatment residuals (WTRs) are a by‐product of municipal drinking water treatment plants and can have the capacity to adsorb tremendous amounts of P. Understanding the WTR phosphorus adsorption process is important for discerning the mechanism and tenacity of P retention. We studied P adsorbing mechanism(s) of an aluminum‐based [Al2(SO4)3·14H2O] WTR from Englewood, CO. In a laboratory study, we shook mixtures of P‐loaded WTR for 1 to 211 d followed by solution pH analysis, and solution Ca, Al, and P analysis via inductively coupled plasma atomic emission spectroscopy. After shaking periods, we also examined the solids fraction by X‐ray diffraction (XRD) and electron microprobe analysis using wavelength dispersive spectroscopy (EMPA–WDS). The shaking results indicated an increase in pH from 7.2 to 8.2, an increase in desorbed Ca and Al concentrations, and a decrease in desorbed P concentration. The pH and desorbed Ca concentration increases suggested that CaCO3 controlled Ca solubility. Increased desorbed Al concentration may have been due to Al OH −4 formation. Decreased P content, in conjunction with the pH increase, was consistent with calcium phosphate formation or precipitation. The system appeared to be undersaturated with respect to dicalcium phosphate (DCP; CaHPO4) and supersaturated with respect to octacalcium phosphate [OCP; Ca4H(PO4)3·2.5H2O]. The Ca and Al increases, as well as OCP formation, were supported by MINTEQA2 modeling. The XRD and EMPA–WDS results for all shaking times, however, suggested surface P chemisorption as an amorphous Al–P mineral phase.</description><subject>Adsorption</subject><subject>Agronomy. Soil science and plant productions</subject><subject>Aluminum</subject><subject>Aluminum - chemistry</subject><subject>Aluminum sulfate</subject><subject>Applied sciences</subject><subject>Biological and medical sciences</subject><subject>Calcium Carbonate - chemistry</subject><subject>Calcium phosphates</subject><subject>Chemical industry and chemicals</subject><subject>Drinking water</subject><subject>Drinking water and swimming-pool water. Desalination</subject><subject>Emission spectroscopy</subject><subject>Exact sciences and technology</subject><subject>Fertilisers</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>General agronomy. Plant production</subject><subject>Hydrogen-Ion Concentration</subject><subject>Industrial chemicals</subject><subject>Nitrogen, phosphorus, potassium fertilizations</subject><subject>Phosphates - chemistry</subject><subject>Phosphorus - analysis</subject><subject>Phosphorus - isolation & purification</subject><subject>Phosphorus fertilization</subject><subject>Pollution</subject><subject>Retention</subject><subject>Soil-plant relationships. Soil fertility. Fertilization. Amendments</subject><subject>Solubility</subject><subject>Waste Disposal, Fluid - methods</subject><subject>Water Supply</subject><subject>Water treatment</subject><subject>Water treatment and pollution</subject><subject>Water treatment plants</subject><subject>X-ray diffraction</subject><issn>0047-2425</issn><issn>1537-2537</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><sourceid>8G5</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNqF0Utr3DAUBWARWpJpkl3XxRTSVZ1cSVeWtcgiDGnTkpIHCVkKWZYZD37MSDYl_75yxhDIollYlsTHkcQh5DOFU0Y5nq3dlgHwU5oLuUcWVHCZsjh8IAsAjHNk4oB8CmENQBnIbJ8cUBRccA4Lcn676sNm1fsxJPducN1Q913yx9mV6erQhqSvEpM8mcH55ME7M7SRRBnqcjTNEflYmSa44_l_SB5_XD4sr9Lrm5-_lhfXqcVcybTgFSJFgxSUMXmWI9BCmUpZVRYyLwpTlDZHGdfAWSYLcFmuuLOuBFSS80PybZe78f12dGHQbR2saxrTuX4MWgopENj7kGY0U0yw9yFmkivECL--get-9F18raZKIkjJp7TvO2R9H4J3ld74ujX-WVPQU0t6bklPLUX-Zc4ci9aVr3iuJYKTGZhgTVN509k6vDpBOVCYgtTO_a0b9_zfQ_Xvyzs2fXHj5RL_AEP3qMI</recordid><startdate>200309</startdate><enddate>200309</enddate><creator>Ippolito, J. A.</creator><creator>Barbarick, K. A.</creator><creator>Heil, D. M.</creator><creator>Chandler, J. P.</creator><creator>Redente, E. 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A. ; Barbarick, K. A. ; Heil, D. M. ; Chandler, J. P. ; Redente, E. F.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4897-b3f4414a4109aa868401b9af9c9db78bbabdc8479c903267b0e6893eced049733</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>Adsorption</topic><topic>Agronomy. Soil science and plant productions</topic><topic>Aluminum</topic><topic>Aluminum - chemistry</topic><topic>Aluminum sulfate</topic><topic>Applied sciences</topic><topic>Biological and medical sciences</topic><topic>Calcium Carbonate - chemistry</topic><topic>Calcium phosphates</topic><topic>Chemical industry and chemicals</topic><topic>Drinking water</topic><topic>Drinking water and swimming-pool water. Desalination</topic><topic>Emission spectroscopy</topic><topic>Exact sciences and technology</topic><topic>Fertilisers</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>General agronomy. Plant production</topic><topic>Hydrogen-Ion Concentration</topic><topic>Industrial chemicals</topic><topic>Nitrogen, phosphorus, potassium fertilizations</topic><topic>Phosphates - chemistry</topic><topic>Phosphorus - analysis</topic><topic>Phosphorus - isolation & purification</topic><topic>Phosphorus fertilization</topic><topic>Pollution</topic><topic>Retention</topic><topic>Soil-plant relationships. Soil fertility. Fertilization. Amendments</topic><topic>Solubility</topic><topic>Waste Disposal, Fluid - methods</topic><topic>Water Supply</topic><topic>Water treatment</topic><topic>Water treatment and pollution</topic><topic>Water treatment plants</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ippolito, J. A.</creatorcontrib><creatorcontrib>Barbarick, K. A.</creatorcontrib><creatorcontrib>Heil, D. M.</creatorcontrib><creatorcontrib>Chandler, J. 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A.</au><au>Barbarick, K. A.</au><au>Heil, D. M.</au><au>Chandler, J. P.</au><au>Redente, E. F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Phosphorus Retention Mechanisms of a Water Treatment Residual</atitle><jtitle>Journal of environmental quality</jtitle><addtitle>J Environ Qual</addtitle><date>2003-09</date><risdate>2003</risdate><volume>32</volume><issue>5</issue><spage>1857</spage><epage>1864</epage><pages>1857-1864</pages><issn>0047-2425</issn><eissn>1537-2537</eissn><coden>JEVQAA</coden><abstract>ABSTRACT
Water treatment residuals (WTRs) are a by‐product of municipal drinking water treatment plants and can have the capacity to adsorb tremendous amounts of P. Understanding the WTR phosphorus adsorption process is important for discerning the mechanism and tenacity of P retention. We studied P adsorbing mechanism(s) of an aluminum‐based [Al2(SO4)3·14H2O] WTR from Englewood, CO. In a laboratory study, we shook mixtures of P‐loaded WTR for 1 to 211 d followed by solution pH analysis, and solution Ca, Al, and P analysis via inductively coupled plasma atomic emission spectroscopy. After shaking periods, we also examined the solids fraction by X‐ray diffraction (XRD) and electron microprobe analysis using wavelength dispersive spectroscopy (EMPA–WDS). The shaking results indicated an increase in pH from 7.2 to 8.2, an increase in desorbed Ca and Al concentrations, and a decrease in desorbed P concentration. The pH and desorbed Ca concentration increases suggested that CaCO3 controlled Ca solubility. Increased desorbed Al concentration may have been due to Al OH −4 formation. Decreased P content, in conjunction with the pH increase, was consistent with calcium phosphate formation or precipitation. The system appeared to be undersaturated with respect to dicalcium phosphate (DCP; CaHPO4) and supersaturated with respect to octacalcium phosphate [OCP; Ca4H(PO4)3·2.5H2O]. The Ca and Al increases, as well as OCP formation, were supported by MINTEQA2 modeling. The XRD and EMPA–WDS results for all shaking times, however, suggested surface P chemisorption as an amorphous Al–P mineral phase.</abstract><cop>Madison</cop><pub>American Society of Agronomy, Crop Science Society of America, Soil Science Society</pub><pmid>14535330</pmid><doi>10.2134/jeq2003.1857</doi><tpages>8</tpages></addata></record> |
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subjects | Adsorption Agronomy. Soil science and plant productions Aluminum Aluminum - chemistry Aluminum sulfate Applied sciences Biological and medical sciences Calcium Carbonate - chemistry Calcium phosphates Chemical industry and chemicals Drinking water Drinking water and swimming-pool water. Desalination Emission spectroscopy Exact sciences and technology Fertilisers Fundamental and applied biological sciences. Psychology General agronomy. Plant production Hydrogen-Ion Concentration Industrial chemicals Nitrogen, phosphorus, potassium fertilizations Phosphates - chemistry Phosphorus - analysis Phosphorus - isolation & purification Phosphorus fertilization Pollution Retention Soil-plant relationships. Soil fertility. Fertilization. Amendments Solubility Waste Disposal, Fluid - methods Water Supply Water treatment Water treatment and pollution Water treatment plants X-ray diffraction |
title | Phosphorus Retention Mechanisms of a Water Treatment Residual |
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