Gas-phase ion thermochemistry in organometallic systems
I. Introduction 408 II. Techniques Employed to Measure Binding Energies 409 A. Continuous‐Ejection Technique (CE) 409 B. Equilibrium Measurements 409 C. Kinetic Method 410 D. Radiative Association (RA) Kinetics Method 410 E. Threshold‐CID Experiments 410 F. Zero‐Pressure Thermal Radiation‐Indu...
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| Veröffentlicht in: | Mass spectrometry reviews 2003-11, Vol.22 (6), p.407-428 |
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| creator | Operti, Lorenza Rabezzana, Roberto |
| description | I.
Introduction
408
II.
Techniques Employed to Measure Binding Energies
409
A. Continuous‐Ejection Technique (CE)
409
B. Equilibrium Measurements
409
C. Kinetic Method
410
D. Radiative Association (RA) Kinetics Method
410
E. Threshold‐CID Experiments
410
F. Zero‐Pressure Thermal Radiation‐Induced Dissociation Technique (ZTRID)
411
III.
Metal Ion—Ligand Binding Energies
411
A. Lithium
411
B. Sodium
412
C. Magnesium
413
D. Aluminum
414
E. Silicon
414
F. Potassium
414
G. Calcium, Strontium
415
H. Scandium
415
I. Titanium
415
J. Vanadium
415
K. Chromium
416
L. Manganese
416
M. Iron
416
N. Cobalt, Nickel
419
O. Copper
419
P. Zinc
421
Q. Rubidium, Cesium
421
R. Molibdenum, Tungsten
423
S. Silver, Cadmium
423
T. Platinum
425
References
425
This review represents a general overview on the determination of bond energies in gas‐phase organometallic systems. The paper focuses on articles published in the last 7 years, whose main scope was to experimentally measure metal ion–ligand binding energies. Therefore, studies of reactivity and characterization of ion complexes are not included, even if some of them display bond energies among the data measured. Bond energies are presented according to the metal ion complexed, in increasing order of atomic number. Periodic trends of binding energies and correlations among the various ligand are discussed. A brief summary of the most used techniques specifically devoted to gather bond energies is also provided. © 2003 Wiley Periodicals, Inc., Mass Spec Rev 22:407–428, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/mas.10065 |
| doi_str_mv | 10.1002/mas.10065 |
| format | Article |
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Introduction
408
II.
Techniques Employed to Measure Binding Energies
409
A. Continuous‐Ejection Technique (CE)
409
B. Equilibrium Measurements
409
C. Kinetic Method
410
D. Radiative Association (RA) Kinetics Method
410
E. Threshold‐CID Experiments
410
F. Zero‐Pressure Thermal Radiation‐Induced Dissociation Technique (ZTRID)
411
III.
Metal Ion—Ligand Binding Energies
411
A. Lithium
411
B. Sodium
412
C. Magnesium
413
D. Aluminum
414
E. Silicon
414
F. Potassium
414
G. Calcium, Strontium
415
H. Scandium
415
I. Titanium
415
J. Vanadium
415
K. Chromium
416
L. Manganese
416
M. Iron
416
N. Cobalt, Nickel
419
O. Copper
419
P. Zinc
421
Q. Rubidium, Cesium
421
R. Molibdenum, Tungsten
423
S. Silver, Cadmium
423
T. Platinum
425
References
425
This review represents a general overview on the determination of bond energies in gas‐phase organometallic systems. The paper focuses on articles published in the last 7 years, whose main scope was to experimentally measure metal ion–ligand binding energies. Therefore, studies of reactivity and characterization of ion complexes are not included, even if some of them display bond energies among the data measured. Bond energies are presented according to the metal ion complexed, in increasing order of atomic number. Periodic trends of binding energies and correlations among the various ligand are discussed. A brief summary of the most used techniques specifically devoted to gather bond energies is also provided. © 2003 Wiley Periodicals, Inc., Mass Spec Rev 22:407–428, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/mas.10065</description><identifier>ISSN: 0277-7037</identifier><identifier>EISSN: 1098-2787</identifier><identifier>DOI: 10.1002/mas.10065</identifier><identifier>PMID: 14528494</identifier><identifier>CODEN: MSRVD3</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>bond energies ; Chemistry ; Coordination compounds ; Exact sciences and technology ; gas-phase ion chemistry ; Gases - chemistry ; Inorganic chemistry and origins of life ; ion thermochemistry ; Ions - chemistry ; Ligands ; Mass Spectrometry - instrumentation ; Mass Spectrometry - methods ; Metals - chemistry ; Organometallic Compounds - chemistry ; organometallic systems ; Preparations and properties ; Thermodynamics</subject><ispartof>Mass spectrometry reviews, 2003-11, Vol.22 (6), p.407-428</ispartof><rights>Copyright © 2003 Wiley Periodicals, Inc., A Wiley Company</rights><rights>2004 INIST-CNRS</rights><rights>Copyright 2003 Wiley Periodicals, Inc., Mass Spec Rev 22:407-428, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/mas.10065</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3895-d68a81237c08efd5bc04cb3c4e41a958b7e840778d329901ee75b8436bed127c3</citedby><cites>FETCH-LOGICAL-c3895-d68a81237c08efd5bc04cb3c4e41a958b7e840778d329901ee75b8436bed127c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fmas.10065$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmas.10065$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=15210253$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/14528494$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Operti, Lorenza</creatorcontrib><creatorcontrib>Rabezzana, Roberto</creatorcontrib><title>Gas-phase ion thermochemistry in organometallic systems</title><title>Mass spectrometry reviews</title><addtitle>Mass Spectrom. Rev</addtitle><description>I.
Introduction
408
II.
Techniques Employed to Measure Binding Energies
409
A. Continuous‐Ejection Technique (CE)
409
B. Equilibrium Measurements
409
C. Kinetic Method
410
D. Radiative Association (RA) Kinetics Method
410
E. Threshold‐CID Experiments
410
F. Zero‐Pressure Thermal Radiation‐Induced Dissociation Technique (ZTRID)
411
III.
Metal Ion—Ligand Binding Energies
411
A. Lithium
411
B. Sodium
412
C. Magnesium
413
D. Aluminum
414
E. Silicon
414
F. Potassium
414
G. Calcium, Strontium
415
H. Scandium
415
I. Titanium
415
J. Vanadium
415
K. Chromium
416
L. Manganese
416
M. Iron
416
N. Cobalt, Nickel
419
O. Copper
419
P. Zinc
421
Q. Rubidium, Cesium
421
R. Molibdenum, Tungsten
423
S. Silver, Cadmium
423
T. Platinum
425
References
425
This review represents a general overview on the determination of bond energies in gas‐phase organometallic systems. The paper focuses on articles published in the last 7 years, whose main scope was to experimentally measure metal ion–ligand binding energies. Therefore, studies of reactivity and characterization of ion complexes are not included, even if some of them display bond energies among the data measured. Bond energies are presented according to the metal ion complexed, in increasing order of atomic number. Periodic trends of binding energies and correlations among the various ligand are discussed. A brief summary of the most used techniques specifically devoted to gather bond energies is also provided. © 2003 Wiley Periodicals, Inc., Mass Spec Rev 22:407–428, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/mas.10065</description><subject>bond energies</subject><subject>Chemistry</subject><subject>Coordination compounds</subject><subject>Exact sciences and technology</subject><subject>gas-phase ion chemistry</subject><subject>Gases - chemistry</subject><subject>Inorganic chemistry and origins of life</subject><subject>ion thermochemistry</subject><subject>Ions - chemistry</subject><subject>Ligands</subject><subject>Mass Spectrometry - instrumentation</subject><subject>Mass Spectrometry - methods</subject><subject>Metals - chemistry</subject><subject>Organometallic Compounds - chemistry</subject><subject>organometallic systems</subject><subject>Preparations and properties</subject><subject>Thermodynamics</subject><issn>0277-7037</issn><issn>1098-2787</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp1kLlOw0AQhlcIBCFQ8ALIDUgUhj28nnWJOAIKR5EgytV6PSYGH2HXEeTtcYiBimqm-P45PkIOGD1llPKzyvhVE8sNMmA0USEHBZtkQDlACFTADtn1_pVSxiRj22SHRZKrKIkGBEbGh_OZ8RgUTR20M3RVY2dYFb51y6Cog8a9mLqpsDVlWdjAL32Lld8jW7kpPe73dUierq-mFzfh3ePo9uL8LrRCJTLMYmUU4wIsVZhnMrU0sqmwEUbMJFKlgCqiACoTPEkoQwSZqkjEKWaMgxVDcryeO3fN-wJ9q7vLLJalqbFZeA0Suj8AOvBkDVrXeO8w13NXVMYtNaN6ZUl3lvS3pY497Icu0gqzP7LX0gFHPWC8NWXuTG0L_8dJziiXouPO1txHUeLy_436_nzyszpcJzq_-PmbMO5NxyBA6ueHkR5PJteX42msR-ILTYCMkA</recordid><startdate>200311</startdate><enddate>200311</enddate><creator>Operti, Lorenza</creator><creator>Rabezzana, Roberto</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>200311</creationdate><title>Gas-phase ion thermochemistry in organometallic systems</title><author>Operti, Lorenza ; Rabezzana, Roberto</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3895-d68a81237c08efd5bc04cb3c4e41a958b7e840778d329901ee75b8436bed127c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>bond energies</topic><topic>Chemistry</topic><topic>Coordination compounds</topic><topic>Exact sciences and technology</topic><topic>gas-phase ion chemistry</topic><topic>Gases - chemistry</topic><topic>Inorganic chemistry and origins of life</topic><topic>ion thermochemistry</topic><topic>Ions - chemistry</topic><topic>Ligands</topic><topic>Mass Spectrometry - instrumentation</topic><topic>Mass Spectrometry - methods</topic><topic>Metals - chemistry</topic><topic>Organometallic Compounds - chemistry</topic><topic>organometallic systems</topic><topic>Preparations and properties</topic><topic>Thermodynamics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Operti, Lorenza</creatorcontrib><creatorcontrib>Rabezzana, Roberto</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Mass spectrometry reviews</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Operti, Lorenza</au><au>Rabezzana, Roberto</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Gas-phase ion thermochemistry in organometallic systems</atitle><jtitle>Mass spectrometry reviews</jtitle><addtitle>Mass Spectrom. Rev</addtitle><date>2003-11</date><risdate>2003</risdate><volume>22</volume><issue>6</issue><spage>407</spage><epage>428</epage><pages>407-428</pages><issn>0277-7037</issn><eissn>1098-2787</eissn><coden>MSRVD3</coden><abstract>I.
Introduction
408
II.
Techniques Employed to Measure Binding Energies
409
A. Continuous‐Ejection Technique (CE)
409
B. Equilibrium Measurements
409
C. Kinetic Method
410
D. Radiative Association (RA) Kinetics Method
410
E. Threshold‐CID Experiments
410
F. Zero‐Pressure Thermal Radiation‐Induced Dissociation Technique (ZTRID)
411
III.
Metal Ion—Ligand Binding Energies
411
A. Lithium
411
B. Sodium
412
C. Magnesium
413
D. Aluminum
414
E. Silicon
414
F. Potassium
414
G. Calcium, Strontium
415
H. Scandium
415
I. Titanium
415
J. Vanadium
415
K. Chromium
416
L. Manganese
416
M. Iron
416
N. Cobalt, Nickel
419
O. Copper
419
P. Zinc
421
Q. Rubidium, Cesium
421
R. Molibdenum, Tungsten
423
S. Silver, Cadmium
423
T. Platinum
425
References
425
This review represents a general overview on the determination of bond energies in gas‐phase organometallic systems. The paper focuses on articles published in the last 7 years, whose main scope was to experimentally measure metal ion–ligand binding energies. Therefore, studies of reactivity and characterization of ion complexes are not included, even if some of them display bond energies among the data measured. Bond energies are presented according to the metal ion complexed, in increasing order of atomic number. Periodic trends of binding energies and correlations among the various ligand are discussed. A brief summary of the most used techniques specifically devoted to gather bond energies is also provided. © 2003 Wiley Periodicals, Inc., Mass Spec Rev 22:407–428, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/mas.10065</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><pmid>14528494</pmid><doi>10.1002/mas.10065</doi><tpages>22</tpages></addata></record> |
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| ispartof | Mass spectrometry reviews, 2003-11, Vol.22 (6), p.407-428 |
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| subjects | bond energies Chemistry Coordination compounds Exact sciences and technology gas-phase ion chemistry Gases - chemistry Inorganic chemistry and origins of life ion thermochemistry Ions - chemistry Ligands Mass Spectrometry - instrumentation Mass Spectrometry - methods Metals - chemistry Organometallic Compounds - chemistry organometallic systems Preparations and properties Thermodynamics |
| title | Gas-phase ion thermochemistry in organometallic systems |
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