Application of ionic liquid modified carbon ceramic electrode for the sensitive voltammetric detection of rutin

An ionic liquid (IL) modified carbon ceramic electrode (CCE) was designed and further used for the voltammetric detection of rutin in this paper. IL-CCE was prepared by mixing graphite powder with 1-butyl-3-methylimidazolium tetrafluoroborate (EMIMBF 4) doped silicate sol–gel matrix together and fur...

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Veröffentlicht in:Talanta (Oxford) 2010-10, Vol.82 (5), p.1853-1857
Hauptverfasser: Zhan, Tianrong, Sun, Xiaoying, Wang, Xiuzhen, Sun, Wei, Hou, Wanguo
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container_issue 5
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creator Zhan, Tianrong
Sun, Xiaoying
Wang, Xiuzhen
Sun, Wei
Hou, Wanguo
description An ionic liquid (IL) modified carbon ceramic electrode (CCE) was designed and further used for the voltammetric detection of rutin in this paper. IL-CCE was prepared by mixing graphite powder with 1-butyl-3-methylimidazolium tetrafluoroborate (EMIMBF 4) doped silicate sol–gel matrix together and further characterized by different methods. Then electrochemical behaviors of rutin on the IL-CCE were investigated by different electrochemical methods such as cyclic voltammetry and differential pulse voltammetry (DPV). Due to the presence of IL in the CCE, an enhanced electrochemical response of rutin appeared with a pair of well-defined redox peaks in pH 2.5 phosphate buffer solution (PBS). The electrochemical behaviors of rutin on the IL-CCE were carefully investigated. Under the selected conditions the oxidation peak currents exhibited good linear relationship with the rutin concentration in the range from 0.3 to 100.0 μmol/L with the detection limit as 0.09 μmol/L (3σ). The proposed method was further applied to the rutin tablets sample detection with satisfactory results.
doi_str_mv 10.1016/j.talanta.2010.07.083
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IL-CCE was prepared by mixing graphite powder with 1-butyl-3-methylimidazolium tetrafluoroborate (EMIMBF 4) doped silicate sol–gel matrix together and further characterized by different methods. Then electrochemical behaviors of rutin on the IL-CCE were investigated by different electrochemical methods such as cyclic voltammetry and differential pulse voltammetry (DPV). Due to the presence of IL in the CCE, an enhanced electrochemical response of rutin appeared with a pair of well-defined redox peaks in pH 2.5 phosphate buffer solution (PBS). The electrochemical behaviors of rutin on the IL-CCE were carefully investigated. Under the selected conditions the oxidation peak currents exhibited good linear relationship with the rutin concentration in the range from 0.3 to 100.0 μmol/L with the detection limit as 0.09 μmol/L (3σ). 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IL-CCE was prepared by mixing graphite powder with 1-butyl-3-methylimidazolium tetrafluoroborate (EMIMBF 4) doped silicate sol–gel matrix together and further characterized by different methods. Then electrochemical behaviors of rutin on the IL-CCE were investigated by different electrochemical methods such as cyclic voltammetry and differential pulse voltammetry (DPV). Due to the presence of IL in the CCE, an enhanced electrochemical response of rutin appeared with a pair of well-defined redox peaks in pH 2.5 phosphate buffer solution (PBS). The electrochemical behaviors of rutin on the IL-CCE were carefully investigated. Under the selected conditions the oxidation peak currents exhibited good linear relationship with the rutin concentration in the range from 0.3 to 100.0 μmol/L with the detection limit as 0.09 μmol/L (3σ). 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subjects Analytical chemistry
Buffers
Carbon
Carbon - chemistry
Carbon ceramic electrode
Ceramics
Ceramics - chemistry
Chemistry
Cyclic voltammetry
Differential pulse voltammetry
Electrochemical methods
Electrochemical Techniques - instrumentation
Electrochemical Techniques - methods
Electrodes
Exact sciences and technology
Graphite
Graphite - chemistry
Imidazoles - chemistry
Ionic liquid
Ionic liquids
Ionic Liquids - chemistry
Limit of Detection
Rutin
Rutin - analysis
Silicates
Tablets
Tablets - analysis
Voltammetry
title Application of ionic liquid modified carbon ceramic electrode for the sensitive voltammetric detection of rutin
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