Electronic and Optical Properties in the Solid-State Molecular Assemblies of Anion-Responsive Pyrrole-Based π-Conjugated Systems
On the basis of the chemistry in solution, the solid‐state structures and the corresponding electronic and optical properties of dipyrrolyldiketone boron complexes as π‐conjugated acyclic anion receptors have been investigated. Solid‐state assemblies of the receptors exhibit anion‐dependent properti...
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| Veröffentlicht in: | Chemistry : a European journal 2010-09, Vol.16 (36), p.10994-11002 |
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| creator | Maeda, Hiromitsu Bando, Yuya Haketa, Yohei Honsho, Yoshihito Seki, Shu Nakajima, Hiromi Tohnai, Norimitsu |
| description | On the basis of the chemistry in solution, the solid‐state structures and the corresponding electronic and optical properties of dipyrrolyldiketone boron complexes as π‐conjugated acyclic anion receptors have been investigated. Solid‐state assemblies of the receptors exhibit anion‐dependent properties that are in sharp contrast to those in the solution state. Anion complexation, along with structural differences in the pyrrole subunits such as a benzo‐fused pyrrole, plays an essential role not only in the formation of the assembled modes but also in determining electronic and optical properties, as well as the charge‐carrier mobilities. In addition, by anion complexation, inclusion of the counter cations into the crystals has also been found to be one of the essential factors to determine the properties.
Any old (an)ion? Solid‐state assemblies of π‐conjugated acyclic anion receptors exhibit anion‐dependent properties that are in sharp contrast to those in the solution state. Anion complexation, along with structural differences in the pyrrole subunits, such as a benzo‐fused pyrrole, plays an essential role not only in the formation of the assembled modes, but also in determining the electronic and optical properties, as well as the charge‐carrier mobilities (see graphic). |
| doi_str_mv | 10.1002/chem.201001852 |
| format | Article |
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Any old (an)ion? Solid‐state assemblies of π‐conjugated acyclic anion receptors exhibit anion‐dependent properties that are in sharp contrast to those in the solution state. Anion complexation, along with structural differences in the pyrrole subunits, such as a benzo‐fused pyrrole, plays an essential role not only in the formation of the assembled modes, but also in determining the electronic and optical properties, as well as the charge‐carrier mobilities (see graphic).</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201001852</identifier><identifier>PMID: 20821768</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>anions ; Anions - chemistry ; Boron Compounds - chemistry ; crystal engineering ; Crystallography, X-Ray ; Electronics ; heterocycles ; Heterocyclic Compounds - chemistry ; Models, Molecular ; Molecular Structure ; Pyrroles - chemistry ; receptors ; self-assembly ; Solutions</subject><ispartof>Chemistry : a European journal, 2010-09, Vol.16 (36), p.10994-11002</ispartof><rights>Copyright © 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2972-e29dfd076c3a1bf55670a0398adaa1225b05676fafd74b85acf96482e7995b5c3</citedby><cites>FETCH-LOGICAL-c2972-e29dfd076c3a1bf55670a0398adaa1225b05676fafd74b85acf96482e7995b5c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201001852$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201001852$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/20821768$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Maeda, Hiromitsu</creatorcontrib><creatorcontrib>Bando, Yuya</creatorcontrib><creatorcontrib>Haketa, Yohei</creatorcontrib><creatorcontrib>Honsho, Yoshihito</creatorcontrib><creatorcontrib>Seki, Shu</creatorcontrib><creatorcontrib>Nakajima, Hiromi</creatorcontrib><creatorcontrib>Tohnai, Norimitsu</creatorcontrib><title>Electronic and Optical Properties in the Solid-State Molecular Assemblies of Anion-Responsive Pyrrole-Based π-Conjugated Systems</title><title>Chemistry : a European journal</title><addtitle>Chemistry - A European Journal</addtitle><description>On the basis of the chemistry in solution, the solid‐state structures and the corresponding electronic and optical properties of dipyrrolyldiketone boron complexes as π‐conjugated acyclic anion receptors have been investigated. Solid‐state assemblies of the receptors exhibit anion‐dependent properties that are in sharp contrast to those in the solution state. Anion complexation, along with structural differences in the pyrrole subunits such as a benzo‐fused pyrrole, plays an essential role not only in the formation of the assembled modes but also in determining electronic and optical properties, as well as the charge‐carrier mobilities. In addition, by anion complexation, inclusion of the counter cations into the crystals has also been found to be one of the essential factors to determine the properties.
Any old (an)ion? Solid‐state assemblies of π‐conjugated acyclic anion receptors exhibit anion‐dependent properties that are in sharp contrast to those in the solution state. Anion complexation, along with structural differences in the pyrrole subunits, such as a benzo‐fused pyrrole, plays an essential role not only in the formation of the assembled modes, but also in determining the electronic and optical properties, as well as the charge‐carrier mobilities (see graphic).</description><subject>anions</subject><subject>Anions - chemistry</subject><subject>Boron Compounds - chemistry</subject><subject>crystal engineering</subject><subject>Crystallography, X-Ray</subject><subject>Electronics</subject><subject>heterocycles</subject><subject>Heterocyclic Compounds - chemistry</subject><subject>Models, Molecular</subject><subject>Molecular Structure</subject><subject>Pyrroles - chemistry</subject><subject>receptors</subject><subject>self-assembly</subject><subject>Solutions</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkEFv0zAYhi3ExMrgyhH5xsmd48R2fCxV6ZA6NiiIo-U4X5iHE2d2AvQGv3B_iVTdKm6c_Ml63ufwIPQqo_OMUnZub6CdMzrdWcnZEzTLOMtILgV_imZUFZIInqtT9DylW0qpEnn-DJ0yWrJMinKG_qw82CGGzllsuhpf9YOzxuPrGHqIg4OEXYeHG8Db4F1NtoMZAF-GaTV6E_EiJWgrv-dCgxedCx35BKkPXXI_AF_vYpxY8tYkqPH9b7IM3e34bXLUeLtLA7TpBTppjE_w8uE9Q1_erT4vL8jmav1-udgQy5RkBJiqm5pKYXOTVQ3nQlJDc1Wa2piMMV7R6Us0pqllUZXc2EaJomQgleIVt_kZenPw9jHcjZAG3bpkwXvTQRiTlpwXlJdcTOT8QNoYUorQ6D661sSdzqjeV9f76vpYfRq8flCPVQv1EX_MPAHqAPx0Hnb_0enlxeryXzk5bN2U69dxa-J3LWQuuf76Ya2ZKov1hm70x_wv846fzQ</recordid><startdate>20100924</startdate><enddate>20100924</enddate><creator>Maeda, Hiromitsu</creator><creator>Bando, Yuya</creator><creator>Haketa, Yohei</creator><creator>Honsho, Yoshihito</creator><creator>Seki, Shu</creator><creator>Nakajima, Hiromi</creator><creator>Tohnai, Norimitsu</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20100924</creationdate><title>Electronic and Optical Properties in the Solid-State Molecular Assemblies of Anion-Responsive Pyrrole-Based π-Conjugated Systems</title><author>Maeda, Hiromitsu ; Bando, Yuya ; Haketa, Yohei ; Honsho, Yoshihito ; Seki, Shu ; Nakajima, Hiromi ; Tohnai, Norimitsu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2972-e29dfd076c3a1bf55670a0398adaa1225b05676fafd74b85acf96482e7995b5c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>anions</topic><topic>Anions - chemistry</topic><topic>Boron Compounds - chemistry</topic><topic>crystal engineering</topic><topic>Crystallography, X-Ray</topic><topic>Electronics</topic><topic>heterocycles</topic><topic>Heterocyclic Compounds - chemistry</topic><topic>Models, Molecular</topic><topic>Molecular Structure</topic><topic>Pyrroles - chemistry</topic><topic>receptors</topic><topic>self-assembly</topic><topic>Solutions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Maeda, Hiromitsu</creatorcontrib><creatorcontrib>Bando, Yuya</creatorcontrib><creatorcontrib>Haketa, Yohei</creatorcontrib><creatorcontrib>Honsho, Yoshihito</creatorcontrib><creatorcontrib>Seki, Shu</creatorcontrib><creatorcontrib>Nakajima, Hiromi</creatorcontrib><creatorcontrib>Tohnai, Norimitsu</creatorcontrib><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Maeda, Hiromitsu</au><au>Bando, Yuya</au><au>Haketa, Yohei</au><au>Honsho, Yoshihito</au><au>Seki, Shu</au><au>Nakajima, Hiromi</au><au>Tohnai, Norimitsu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electronic and Optical Properties in the Solid-State Molecular Assemblies of Anion-Responsive Pyrrole-Based π-Conjugated Systems</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chemistry - A European Journal</addtitle><date>2010-09-24</date><risdate>2010</risdate><volume>16</volume><issue>36</issue><spage>10994</spage><epage>11002</epage><pages>10994-11002</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><abstract>On the basis of the chemistry in solution, the solid‐state structures and the corresponding electronic and optical properties of dipyrrolyldiketone boron complexes as π‐conjugated acyclic anion receptors have been investigated. Solid‐state assemblies of the receptors exhibit anion‐dependent properties that are in sharp contrast to those in the solution state. Anion complexation, along with structural differences in the pyrrole subunits such as a benzo‐fused pyrrole, plays an essential role not only in the formation of the assembled modes but also in determining electronic and optical properties, as well as the charge‐carrier mobilities. In addition, by anion complexation, inclusion of the counter cations into the crystals has also been found to be one of the essential factors to determine the properties.
Any old (an)ion? Solid‐state assemblies of π‐conjugated acyclic anion receptors exhibit anion‐dependent properties that are in sharp contrast to those in the solution state. Anion complexation, along with structural differences in the pyrrole subunits, such as a benzo‐fused pyrrole, plays an essential role not only in the formation of the assembled modes, but also in determining the electronic and optical properties, as well as the charge‐carrier mobilities (see graphic).</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>20821768</pmid><doi>10.1002/chem.201001852</doi><tpages>9</tpages></addata></record> |
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| subjects | anions Anions - chemistry Boron Compounds - chemistry crystal engineering Crystallography, X-Ray Electronics heterocycles Heterocyclic Compounds - chemistry Models, Molecular Molecular Structure Pyrroles - chemistry receptors self-assembly Solutions |
| title | Electronic and Optical Properties in the Solid-State Molecular Assemblies of Anion-Responsive Pyrrole-Based π-Conjugated Systems |
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