Effect of water quality parameters on the migration of vinyl chloride monomer from unplasticized PVC pipes

The migration of vinyl chloride monomer (VCM) from unplasticizedpolyvinyl chloride (uPVC) pipes was investigated using locallymanufactured pipes. Specimens of 33 cm long were used throughoutthe research. The investigation was carried out under differentconditions of water temperature, pH and total d...

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Veröffentlicht in:Water, air, and soil pollution air, and soil pollution, 2000-05, Vol.120 (1-2), p.195-208
Hauptverfasser: AL-MALACK, M. H, SHEIKHELDIN, S. Y, FAYAD, N. M, KHAJA, N
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container_issue 1-2
container_start_page 195
container_title Water, air, and soil pollution
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creator AL-MALACK, M. H
SHEIKHELDIN, S. Y
FAYAD, N. M
KHAJA, N
description The migration of vinyl chloride monomer (VCM) from unplasticizedpolyvinyl chloride (uPVC) pipes was investigated using locallymanufactured pipes. Specimens of 33 cm long were used throughoutthe research. The investigation was carried out under differentconditions of water temperature, pH and total dissolved solidsconcentration and at different durations of exposure. The VCMconcentration in the water was evaluated using the gaschromotography (GC)/head-space technique. A VCM concentration ofmore than 2.5 ppb was detected after 30 days of exposure at45 C. The initial VCM concentration in the uPVC pipewas predicted using equations derived from Fick's first law ofdiffusion. Water tenperature did not affect the migration ofVCM, unless it was raised to high values (i.e. 45 C).Total dissolved solids (TDS) and pH of water were found toaffect the release of VCM from uPVC pipes. Diffusion rate of VCMwas predicted as a function of pH or TDS values.
doi_str_mv 10.1023/A:1005249808374
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H ; SHEIKHELDIN, S. Y ; FAYAD, N. M ; KHAJA, N</creator><creatorcontrib>AL-MALACK, M. H ; SHEIKHELDIN, S. Y ; FAYAD, N. M ; KHAJA, N</creatorcontrib><description>The migration of vinyl chloride monomer (VCM) from unplasticizedpolyvinyl chloride (uPVC) pipes was investigated using locallymanufactured pipes. Specimens of 33 cm long were used throughoutthe research. The investigation was carried out under differentconditions of water temperature, pH and total dissolved solidsconcentration and at different durations of exposure. The VCMconcentration in the water was evaluated using the gaschromotography (GC)/head-space technique. A VCM concentration ofmore than 2.5 ppb was detected after 30 days of exposure at45 C. The initial VCM concentration in the uPVC pipewas predicted using equations derived from Fick's first law ofdiffusion. Water tenperature did not affect the migration ofVCM, unless it was raised to high values (i.e. 45 C).Total dissolved solids (TDS) and pH of water were found toaffect the release of VCM from uPVC pipes. Diffusion rate of VCMwas predicted as a function of pH or TDS values.</description><identifier>ISSN: 0049-6979</identifier><identifier>EISSN: 1573-2932</identifier><identifier>DOI: 10.1023/A:1005249808374</identifier><identifier>CODEN: WAPLAC</identifier><language>eng</language><publisher>Dordrecht: Springer</publisher><subject>Applied sciences ; Chemical industry ; Chlorides ; Dissolution ; Drinking water and swimming-pool water. 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The initial VCM concentration in the uPVC pipewas predicted using equations derived from Fick's first law ofdiffusion. Water tenperature did not affect the migration ofVCM, unless it was raised to high values (i.e. 45 C).Total dissolved solids (TDS) and pH of water were found toaffect the release of VCM from uPVC pipes. Diffusion rate of VCMwas predicted as a function of pH or TDS values.</description><subject>Applied sciences</subject><subject>Chemical industry</subject><subject>Chlorides</subject><subject>Dissolution</subject><subject>Drinking water and swimming-pool water. 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A VCM concentration ofmore than 2.5 ppb was detected after 30 days of exposure at45 C. The initial VCM concentration in the uPVC pipewas predicted using equations derived from Fick's first law ofdiffusion. Water tenperature did not affect the migration ofVCM, unless it was raised to high values (i.e. 45 C).Total dissolved solids (TDS) and pH of water were found toaffect the release of VCM from uPVC pipes. Diffusion rate of VCMwas predicted as a function of pH or TDS values.</abstract><cop>Dordrecht</cop><pub>Springer</pub><doi>10.1023/A:1005249808374</doi><tpages>14</tpages></addata></record>
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identifier ISSN: 0049-6979
ispartof Water, air, and soil pollution, 2000-05, Vol.120 (1-2), p.195-208
issn 0049-6979
1573-2932
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source SpringerLink Journals - AutoHoldings
subjects Applied sciences
Chemical industry
Chlorides
Dissolution
Drinking water and swimming-pool water. Desalination
Environmental monitoring
Exact sciences and technology
Mathematical analysis
Migration
Monomers
pH effects
Pipe
Pipes
Pollution
Polyvinyl chloride
Soil pollution
Total dissolved solids
Vinyl chloride
Water quality
Water temperature
Water treatment and pollution
title Effect of water quality parameters on the migration of vinyl chloride monomer from unplasticized PVC pipes
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