Effect of water quality parameters on the migration of vinyl chloride monomer from unplasticized PVC pipes
The migration of vinyl chloride monomer (VCM) from unplasticizedpolyvinyl chloride (uPVC) pipes was investigated using locallymanufactured pipes. Specimens of 33 cm long were used throughoutthe research. The investigation was carried out under differentconditions of water temperature, pH and total d...
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Veröffentlicht in: | Water, air, and soil pollution air, and soil pollution, 2000-05, Vol.120 (1-2), p.195-208 |
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creator | AL-MALACK, M. H SHEIKHELDIN, S. Y FAYAD, N. M KHAJA, N |
description | The migration of vinyl chloride monomer (VCM) from unplasticizedpolyvinyl chloride (uPVC) pipes was investigated using locallymanufactured pipes. Specimens of 33 cm long were used throughoutthe research. The investigation was carried out under differentconditions of water temperature, pH and total dissolved solidsconcentration and at different durations of exposure. The VCMconcentration in the water was evaluated using the gaschromotography (GC)/head-space technique. A VCM concentration ofmore than 2.5 ppb was detected after 30 days of exposure at45 C. The initial VCM concentration in the uPVC pipewas predicted using equations derived from Fick's first law ofdiffusion. Water tenperature did not affect the migration ofVCM, unless it was raised to high values (i.e. 45 C).Total dissolved solids (TDS) and pH of water were found toaffect the release of VCM from uPVC pipes. Diffusion rate of VCMwas predicted as a function of pH or TDS values. |
doi_str_mv | 10.1023/A:1005249808374 |
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H ; SHEIKHELDIN, S. Y ; FAYAD, N. M ; KHAJA, N</creator><creatorcontrib>AL-MALACK, M. H ; SHEIKHELDIN, S. Y ; FAYAD, N. M ; KHAJA, N</creatorcontrib><description>The migration of vinyl chloride monomer (VCM) from unplasticizedpolyvinyl chloride (uPVC) pipes was investigated using locallymanufactured pipes. Specimens of 33 cm long were used throughoutthe research. The investigation was carried out under differentconditions of water temperature, pH and total dissolved solidsconcentration and at different durations of exposure. The VCMconcentration in the water was evaluated using the gaschromotography (GC)/head-space technique. A VCM concentration ofmore than 2.5 ppb was detected after 30 days of exposure at45 C. The initial VCM concentration in the uPVC pipewas predicted using equations derived from Fick's first law ofdiffusion. Water tenperature did not affect the migration ofVCM, unless it was raised to high values (i.e. 45 C).Total dissolved solids (TDS) and pH of water were found toaffect the release of VCM from uPVC pipes. Diffusion rate of VCMwas predicted as a function of pH or TDS values.</description><identifier>ISSN: 0049-6979</identifier><identifier>EISSN: 1573-2932</identifier><identifier>DOI: 10.1023/A:1005249808374</identifier><identifier>CODEN: WAPLAC</identifier><language>eng</language><publisher>Dordrecht: Springer</publisher><subject>Applied sciences ; Chemical industry ; Chlorides ; Dissolution ; Drinking water and swimming-pool water. Desalination ; Environmental monitoring ; Exact sciences and technology ; Mathematical analysis ; Migration ; Monomers ; pH effects ; Pipe ; Pipes ; Pollution ; Polyvinyl chloride ; Soil pollution ; Total dissolved solids ; Vinyl chloride ; Water quality ; Water temperature ; Water treatment and pollution</subject><ispartof>Water, air, and soil pollution, 2000-05, Vol.120 (1-2), p.195-208</ispartof><rights>2000 INIST-CNRS</rights><rights>Kluwer Academic Publishers 2000</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c351t-830c1ae7b1ded92d9125a69806b24d5b4222358662e49146cd752ad3afd23fc93</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=1365989$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>AL-MALACK, M. H</creatorcontrib><creatorcontrib>SHEIKHELDIN, S. Y</creatorcontrib><creatorcontrib>FAYAD, N. M</creatorcontrib><creatorcontrib>KHAJA, N</creatorcontrib><title>Effect of water quality parameters on the migration of vinyl chloride monomer from unplasticized PVC pipes</title><title>Water, air, and soil pollution</title><description>The migration of vinyl chloride monomer (VCM) from unplasticizedpolyvinyl chloride (uPVC) pipes was investigated using locallymanufactured pipes. Specimens of 33 cm long were used throughoutthe research. The investigation was carried out under differentconditions of water temperature, pH and total dissolved solidsconcentration and at different durations of exposure. The VCMconcentration in the water was evaluated using the gaschromotography (GC)/head-space technique. A VCM concentration ofmore than 2.5 ppb was detected after 30 days of exposure at45 C. The initial VCM concentration in the uPVC pipewas predicted using equations derived from Fick's first law ofdiffusion. Water tenperature did not affect the migration ofVCM, unless it was raised to high values (i.e. 45 C).Total dissolved solids (TDS) and pH of water were found toaffect the release of VCM from uPVC pipes. Diffusion rate of VCMwas predicted as a function of pH or TDS values.</description><subject>Applied sciences</subject><subject>Chemical industry</subject><subject>Chlorides</subject><subject>Dissolution</subject><subject>Drinking water and swimming-pool water. Desalination</subject><subject>Environmental monitoring</subject><subject>Exact sciences and technology</subject><subject>Mathematical analysis</subject><subject>Migration</subject><subject>Monomers</subject><subject>pH effects</subject><subject>Pipe</subject><subject>Pipes</subject><subject>Pollution</subject><subject>Polyvinyl chloride</subject><subject>Soil pollution</subject><subject>Total dissolved solids</subject><subject>Vinyl chloride</subject><subject>Water quality</subject><subject>Water temperature</subject><subject>Water treatment and pollution</subject><issn>0049-6979</issn><issn>1573-2932</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2000</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNqFj7tPwzAQxi0EEuUxs1oIAUvAb8dsVcVLqgQDsEau7YCrJE7tBFT-eozoxAC3nO7ud9_dB8ARRhcYEXo5vcIIccJUiUoq2RaYYC5pQRQl22CCEFOFUFLtgr2UliiHKuUELK_r2pkBhhp-6MFFuBp144c17HXUrcudBEMHhzcHW_8a9eBzleF3360baN6aEL3Ns9CFNm_XMbRw7PpGp8Eb_-ksfHyZwd73Lh2AnVo3yR1u8j54vrl-mt0V84fb-9l0XhjK8VCUFBmsnVxg66wiVmHCtciuxIIwyxeMEEJ5KQRxTGEmjJWcaEt1bQmtjaL74OxHt49hNbo0VK1PxjWN7lwYUyU5x1QQRjN5_ieJpZQYSS6_RU__QYUkAqMMHv8Cl2GMXTZcSSa4kCX_PnyygXQyuqmj7oxPVR99q-O6yu9xVSr6BfeUj4I</recordid><startdate>20000501</startdate><enddate>20000501</enddate><creator>AL-MALACK, M. 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Desalination</topic><topic>Environmental monitoring</topic><topic>Exact sciences and technology</topic><topic>Mathematical analysis</topic><topic>Migration</topic><topic>Monomers</topic><topic>pH effects</topic><topic>Pipe</topic><topic>Pipes</topic><topic>Pollution</topic><topic>Polyvinyl chloride</topic><topic>Soil pollution</topic><topic>Total dissolved solids</topic><topic>Vinyl chloride</topic><topic>Water quality</topic><topic>Water temperature</topic><topic>Water treatment and pollution</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>AL-MALACK, M. H</creatorcontrib><creatorcontrib>SHEIKHELDIN, S. Y</creatorcontrib><creatorcontrib>FAYAD, N. 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H</au><au>SHEIKHELDIN, S. Y</au><au>FAYAD, N. M</au><au>KHAJA, N</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of water quality parameters on the migration of vinyl chloride monomer from unplasticized PVC pipes</atitle><jtitle>Water, air, and soil pollution</jtitle><date>2000-05-01</date><risdate>2000</risdate><volume>120</volume><issue>1-2</issue><spage>195</spage><epage>208</epage><pages>195-208</pages><issn>0049-6979</issn><eissn>1573-2932</eissn><coden>WAPLAC</coden><abstract>The migration of vinyl chloride monomer (VCM) from unplasticizedpolyvinyl chloride (uPVC) pipes was investigated using locallymanufactured pipes. Specimens of 33 cm long were used throughoutthe research. The investigation was carried out under differentconditions of water temperature, pH and total dissolved solidsconcentration and at different durations of exposure. The VCMconcentration in the water was evaluated using the gaschromotography (GC)/head-space technique. A VCM concentration ofmore than 2.5 ppb was detected after 30 days of exposure at45 C. The initial VCM concentration in the uPVC pipewas predicted using equations derived from Fick's first law ofdiffusion. Water tenperature did not affect the migration ofVCM, unless it was raised to high values (i.e. 45 C).Total dissolved solids (TDS) and pH of water were found toaffect the release of VCM from uPVC pipes. Diffusion rate of VCMwas predicted as a function of pH or TDS values.</abstract><cop>Dordrecht</cop><pub>Springer</pub><doi>10.1023/A:1005249808374</doi><tpages>14</tpages></addata></record> |
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subjects | Applied sciences Chemical industry Chlorides Dissolution Drinking water and swimming-pool water. Desalination Environmental monitoring Exact sciences and technology Mathematical analysis Migration Monomers pH effects Pipe Pipes Pollution Polyvinyl chloride Soil pollution Total dissolved solids Vinyl chloride Water quality Water temperature Water treatment and pollution |
title | Effect of water quality parameters on the migration of vinyl chloride monomer from unplasticized PVC pipes |
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