Poly(oxazolines)s with Tapered Minidendritic Side Groups. The Simplest Cylindrical Models To Investigate the Formation of Two-Dimensional and Three-Dimensional Order by Direct Visualization

The synthesis of 2-[3,4-bis(n-alkan-1-yloxy)phenyl]-2-oxazolines with alkan = octan, decan, dodecan, and tridecan is presented. Their living cationic ring opening polymerization produces cylindrical macromolecules that self-organize in a hexagonal columnar two-dimensional phase. The structural analy...

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Veröffentlicht in:	Biomacromolecules 2001, Vol.2 (3), p.706-728
Hauptverfasser:	Percec, V, Holerca, M. N, Magonov, S. N, Yeardley, D. J. P, Ungar, G, Duan, H, Hudson, S. D
Format:	Artikel
Sprache:	eng
Schlagworte:	Calorimetry, Differential Scanning Macromolecular Substances Magnetic Resonance Spectroscopy Microscopy, Atomic Force Molecular Structure Oxazoles - chemical synthesis Oxazoles - chemistry Polymers - chemical synthesis Polymers - chemistry Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization Thermodynamics X-Ray Diffraction
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