Evaluation of the Use of Performance Reference Compounds in an Oasis-HLB Adsorbent Based Passive Sampler for Improving Water Concentration Estimates of Polar Herbicides in Freshwater
Passive samplers such as the Polar Organic Chemical Integrative Sampler (POCIS) are useful tools for monitoring trace levels of polar organic chemicals in aquatic environments. The use of performance reference compounds (PRC) spiked into the POCIS adsorbent for in situ calibration may improve the se...
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| Veröffentlicht in: | Environmental science & technology 2010-03, Vol.44 (5), p.1713-1719 |
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| creator | Mazzella, Nicolas Lissalde, Sophie Moreira, Sylvia Delmas, François Mazellier, Patrick Huckins, James N |
| description | Passive samplers such as the Polar Organic Chemical Integrative Sampler (POCIS) are useful tools for monitoring trace levels of polar organic chemicals in aquatic environments. The use of performance reference compounds (PRC) spiked into the POCIS adsorbent for in situ calibration may improve the semiquantitative nature of water concentration estimates based on this type of sampler. In this work, deuterium labeled atrazine-desisopropyl (DIA-d5) was chosen as PRC because of its relatively high fugacity from Oasis HLB (the POCIS adsorbent used) and our earlier evidence of its isotropic exchange. In situ calibration of POCIS spiked with DIA-d5 was performed, and the resulting time-weighted average concentration estimates were compared with similar values from an automatic sampler equipped with Oasis HLB cartridges. Before PRC correction, water concentration estimates based on POCIS data sampling rates from a laboratory calibration exposure were systematically lower than the reference concentrations obtained with the automatic sampler. Use of the DIA-d5 PRC data to correct POCIS sampling rates narrowed differences between corresponding values derived from the two methods. Application of PRCs for in situ calibration seems promising for improving POCIS-derived concentration estimates of polar pesticides. However, careful attention must be paid to the minimization of matrix effects when the quantification is performed by HPLC-ESI-MS/MS. |
| doi_str_mv | 10.1021/es902256m |
| format | Article |
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The use of performance reference compounds (PRC) spiked into the POCIS adsorbent for in situ calibration may improve the semiquantitative nature of water concentration estimates based on this type of sampler. In this work, deuterium labeled atrazine-desisopropyl (DIA-d5) was chosen as PRC because of its relatively high fugacity from Oasis HLB (the POCIS adsorbent used) and our earlier evidence of its isotropic exchange. In situ calibration of POCIS spiked with DIA-d5 was performed, and the resulting time-weighted average concentration estimates were compared with similar values from an automatic sampler equipped with Oasis HLB cartridges. Before PRC correction, water concentration estimates based on POCIS data sampling rates from a laboratory calibration exposure were systematically lower than the reference concentrations obtained with the automatic sampler. Use of the DIA-d5 PRC data to correct POCIS sampling rates narrowed differences between corresponding values derived from the two methods. Application of PRCs for in situ calibration seems promising for improving POCIS-derived concentration estimates of polar pesticides. 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Before PRC correction, water concentration estimates based on POCIS data sampling rates from a laboratory calibration exposure were systematically lower than the reference concentrations obtained with the automatic sampler. Use of the DIA-d5 PRC data to correct POCIS sampling rates narrowed differences between corresponding values derived from the two methods. Application of PRCs for in situ calibration seems promising for improving POCIS-derived concentration estimates of polar pesticides. 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Sci. Technol</addtitle><date>2010-03-01</date><risdate>2010</risdate><volume>44</volume><issue>5</issue><spage>1713</spage><epage>1719</epage><pages>1713-1719</pages><issn>0013-936X</issn><eissn>1520-5851</eissn><coden>ESTHAG</coden><abstract>Passive samplers such as the Polar Organic Chemical Integrative Sampler (POCIS) are useful tools for monitoring trace levels of polar organic chemicals in aquatic environments. The use of performance reference compounds (PRC) spiked into the POCIS adsorbent for in situ calibration may improve the semiquantitative nature of water concentration estimates based on this type of sampler. In this work, deuterium labeled atrazine-desisopropyl (DIA-d5) was chosen as PRC because of its relatively high fugacity from Oasis HLB (the POCIS adsorbent used) and our earlier evidence of its isotropic exchange. In situ calibration of POCIS spiked with DIA-d5 was performed, and the resulting time-weighted average concentration estimates were compared with similar values from an automatic sampler equipped with Oasis HLB cartridges. Before PRC correction, water concentration estimates based on POCIS data sampling rates from a laboratory calibration exposure were systematically lower than the reference concentrations obtained with the automatic sampler. Use of the DIA-d5 PRC data to correct POCIS sampling rates narrowed differences between corresponding values derived from the two methods. Application of PRCs for in situ calibration seems promising for improving POCIS-derived concentration estimates of polar pesticides. However, careful attention must be paid to the minimization of matrix effects when the quantification is performed by HPLC-ESI-MS/MS.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>20108959</pmid><doi>10.1021/es902256m</doi><tpages>7</tpages></addata></record> |
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| identifier | ISSN: 0013-936X |
| ispartof | Environmental science & technology, 2010-03, Vol.44 (5), p.1713-1719 |
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| language | eng |
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| subjects | Adsorbents Adsorption Applied sciences Automation Calibration Chromatography, High Pressure Liquid Environmental Measurements Methods Environmental Monitoring - methods Environmental science Estimates Exact sciences and technology Fresh Water - analysis Herbicides Herbicides - analysis Kinetics Models, Theoretical Organic chemicals Organic Chemicals - analysis Pesticide Residues - analysis Pesticides - analysis Pollution Specimen Handling - methods Spectrometry, Mass, Electrospray Ionization Water Pollutants, Chemical - analysis Water quality |
| title | Evaluation of the Use of Performance Reference Compounds in an Oasis-HLB Adsorbent Based Passive Sampler for Improving Water Concentration Estimates of Polar Herbicides in Freshwater |
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