Lewis Acid Catalyzed Inverse Electron-Demand Diels−Alder Reaction of 1,2-Diazines

Lewis Acid Catalyzed Inverse Electron-Demand Diels−Alder Reaction of 1,2-Diazines

A systematic approach toward Lewis acid catalyzed inverse electron-demand Diels−Alder (IEDDA) reactions of 1,2-diazines is described. The general concept is first investigated by DFT calculations, supported by spectroscopic data, and finally proven in the experiment.

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Veröffentlicht in:Organic letters 2010-09, Vol.12 (18), p.4062-4065
Hauptverfasser: Kessler, Simon N, Wegner, Hermann A
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Electrons
Heterocyclic Compounds, 1-Ring - chemistry
Lewis Acids - chemistry
Models, Molecular
Molecular Structure
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Zusammenfassung:A systematic approach toward Lewis acid catalyzed inverse electron-demand Diels−Alder (IEDDA) reactions of 1,2-diazines is described. The general concept is first investigated by DFT calculations, supported by spectroscopic data, and finally proven in the experiment.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol101701z