Isolable Mixed P,S-Bis(ylide) as an Asymmetric Carbon Atom Source

Isolable Mixed P,S-Bis(ylide) as an Asymmetric Carbon Atom Source

Heart of carbon: The first stable asymmetric bis(ylide), N,N′‐(iPr2NCH2CH2NiPr)(Ph)PCSPh2, has been isolated (see picture; C black, N gray). The presence of the two different ligands causes this carbon(0) complex to behave as an asymmetric atomic carbon source.

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Veröffentlicht in:Angewandte Chemie (International ed.) 2010-09, Vol.49 (38), p.6798-6801
Hauptverfasser: Dellus, Nicolas, Kato, Tsuyoshi, Bagán, Xavier, Saffon-Merceron, Nathalie, Branchadell, Vicenç, Baceiredo, Antoine
Format: Artikel
Sprache:eng
Schlagworte:
carbon
phosphorus
reaction intermediates
sulfur
ylides
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Zusammenfassung:Heart of carbon: The first stable asymmetric bis(ylide), N,N′‐(iPr2NCH2CH2NiPr)(Ph)PCSPh2, has been isolated (see picture; C black, N gray). The presence of the two different ligands causes this carbon(0) complex to behave as an asymmetric atomic carbon source.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201002833