Structures of δ-PdCl₂ and γ-PdCl₂: Phases with Negative Thermal Expansion in One Direction
Phase up to reality: In the tetramorphic PdCl2 system, three of the four phases show a negative thermal expansion in one direction. The two high‐temperature phases, α‐PdCl2 and δ‐PdCl2 (see picture; left), contain planar ribbons of edge‐connected PdCl4 squares. The low‐temperature phase, γ‐PdCl2 (ri...
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| Veröffentlicht in: | Angewandte Chemie (International ed.) 2010-08, Vol.49 (33), p.5677-5682 |
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| container_title | Angewandte Chemie (International ed.) |
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| creator | Evers, Jürgen Beck, Wolfgang Göbel, Michael Jakob, Stefanie Mayer, Peter Oehlinger, Gilbert Rotter, Marianne Klapötke, Thomas M |
| description | Phase up to reality: In the tetramorphic PdCl2 system, three of the four phases show a negative thermal expansion in one direction. The two high‐temperature phases, α‐PdCl2 and δ‐PdCl2 (see picture; left), contain planar ribbons of edge‐connected PdCl4 squares. The low‐temperature phase, γ‐PdCl2 (right), has corrugated layers of corner‐connected PdCl4 squares. It is a link between the ribbon structures (α and δ) and the cluster structure (β) which shows a normal thermal behavior. |
| doi_str_mv | 10.1002/anie.201000680 |
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| subjects | density functional calculations palladium phase transitions structure determination X-ray diffraction |
| title | Structures of δ-PdCl₂ and γ-PdCl₂: Phases with Negative Thermal Expansion in One Direction |
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