Quaternary Ammonium (Hypo)iodite Catalysis for Enantioselective Oxidative Cycloetherification

It is desirable to minimize the use of rare or toxic metals for oxidative reactions in the synthesis of pharmaceutical products. Hypervalent iodine compounds are environmentally benign alternatives, but their catalytic use, particularly for asymmetric transformations, has been quite limited. We repo...

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Veröffentlicht in:Science (American Association for the Advancement of Science) 2010-06, Vol.328 (5984), p.1376-1379
Hauptverfasser: Uyanik, Muhammet, Okamoto, Hiroaki, Yasui, Takeshi, Ishihara, Kazuaki
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Sprache:eng
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