Photoluminescence and resonant Raman scattering in N-doped ZnO thin films

A combination of studies on photoluminescence and resonant Raman scattering in N-doped ZnO thin films were carried out at room temperature. In the photoluminescence spectra, a transformation of radiative recombination mechanism from free-exciton to donor–acceptor-pair transition was observed. An enh...

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Veröffentlicht in:Optics communications 2010-07, Vol.283 (13), p.2695-2699
Hauptverfasser: Zhu, Xiaming, Wu, Hui-Zhen, Qiu, Dong-Jiang, Yuan, Zijian, Jin, Guofen, Kong, Jinfang, Shen, Wenzhong
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container_end_page 2699
container_issue 13
container_start_page 2695
container_title Optics communications
container_volume 283
creator Zhu, Xiaming
Wu, Hui-Zhen
Qiu, Dong-Jiang
Yuan, Zijian
Jin, Guofen
Kong, Jinfang
Shen, Wenzhong
description A combination of studies on photoluminescence and resonant Raman scattering in N-doped ZnO thin films were carried out at room temperature. In the photoluminescence spectra, a transformation of radiative recombination mechanism from free-exciton to donor–acceptor-pair transition was observed. An enhancement of resonant Raman scattering processes as well as longitudinal optical (LO) phonon overtones up to the sixth order were observed in the Raman spectra. Also, the nature of the 1LO phonon underwent a transformation from a pure A 1(LO) mode to a quasimode with mixed A 1 and E 1 symmetry. The underlying mechanisms accounting for the influences of N doping on the optical properties of ZnO were related to the incorporation of extrinsic defects in the crystal lattice.
doi_str_mv 10.1016/j.optcom.2010.03.006
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subjects Accounting
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Exact sciences and technology
Fundamental areas of phenomenology (including applications)
Ii-vi semiconductors
N doping
Optical materials
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
Optics
Other nonlinear optical materials
photorefractive and semiconductor materials
Phonons
Photoluminescence
Physics
Raman scattering
Resonant Raman scattering
Spectra
Thin films
Transformations
Zinc oxide
ZnO
title Photoluminescence and resonant Raman scattering in N-doped ZnO thin films
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