Synthesis and crystal structure of new layered BaNaSc(BO sub(3)) sub(2) and BaNaY(BO sub(3)) sub(2) orthoborates

Synthesis and crystal structure of new layered BaNaSc(BO sub(3)) sub(2) and BaNaY(BO sub(3)) sub(2) orthoborates

Crystals of two new layered BaNaSc(BO sub(3)) sub(2) ( I) and BaNaY(BO sub(3)) sub(2) ( II) orthoborates are grown from the melt-solution by the spontaneous crystallization onto the platinum loop. Single crystal X-ray analysis showed that the compounds are isostructural with the space group R3-, a=5...

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Veröffentlicht in:Journal of solid state chemistry 2010-05, Vol.183 (5), p.1200-1204
Hauptverfasser: Seryotkin, Yurii V, Bakakin, Vladimir V, Kokh, Aleksandr E, Kononova, Nadezhda G, Svetlyakova, Tatyana N, Kokh, Konstantin A, Drebushchak, Tatyana N
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Crystal structure
Crystallization
Crystals
Packages
Scandium
Spontaneous
Synthesis
X-rays
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container_end_page 1204
container_issue 5
container_start_page 1200
container_title Journal of solid state chemistry
container_volume 183
creator Seryotkin, Yurii V
Bakakin, Vladimir V
Kokh, Aleksandr E
Kononova, Nadezhda G
Svetlyakova, Tatyana N
Kokh, Konstantin A
Drebushchak, Tatyana N
description Crystals of two new layered BaNaSc(BO sub(3)) sub(2) ( I) and BaNaY(BO sub(3)) sub(2) ( II) orthoborates are grown from the melt-solution by the spontaneous crystallization onto the platinum loop. Single crystal X-ray analysis showed that the compounds are isostructural with the space group R3-, a=5.23944(12) and 5.3338(2) Aa, and c=34.5919(11) and 35.8303(19) Aa for I and , respectively, Z=6. The distinctive feature of the structure is the close-packed composite anion-cation (Ba,Na)(BO sub(3)) layers. The layers are combined into the base building packages of two types: {M super(3+)[Ba super(2+)(BO sub(3)) super(3-)] sub(2)} super(+) and {M super(3+)[Na super(+)(BO sub(3)) super(3-)] sub(2)} super(-), where M is Sc or Y. Neutral-charge two-package (four-layer) blocks are stacked by the rhombohedral principle into twelve layers of the cubic packing.
doi_str_mv 10.1016/j.jssc.2010.03.005
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subjects Crystal structure
Crystallization
Crystals
Packages
Scandium
Spontaneous
Synthesis
X-rays
title Synthesis and crystal structure of new layered BaNaSc(BO sub(3)) sub(2) and BaNaY(BO sub(3)) sub(2) orthoborates
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