Optimization of thickness and morphology of active layer for high performance of bulk-heterojunction organic solar cells

A two-dimensional model accounting for the effect of both the morphology of active layer and the layer configuration of multilayer-structured device on the device performance, is developed to optimize the device parameter for high performance of the bulk-heterojunction organic solar cells. When the...

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Veröffentlicht in:Solar energy materials and solar cells 2010-06, Vol.94 (6), p.1118-1124
Hauptverfasser: Min Nam, Young, Huh, June, Ho Jo, Won
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creator Min Nam, Young
Huh, June
Ho Jo, Won
description A two-dimensional model accounting for the effect of both the morphology of active layer and the layer configuration of multilayer-structured device on the device performance, is developed to optimize the device parameter for high performance of the bulk-heterojunction organic solar cells. When the photovoltaic properties of poly(3-hexylthiophene)/[6,6]-phenyl C61-butyric acid methyl ester solar cells are calculated as functions of device parameters by using the model, it is found that the optimum thickness of active layer is 80 nm and that the domain size in active layer is about 6 nm. Comparison of simulation with experiment reveals that the simulated short-circuit current as a function of active layer thickness is very consistent with experimental one.
doi_str_mv 10.1016/j.solmat.2010.02.041
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source ScienceDirect Journals (5 years ago - present)
subjects Applied sciences
Bulk-heterojunction
Drift-diffusion model
Energy
Exact sciences and technology
Natural energy
Organic solar cell
P3HT:PCBM
Photovoltaic conversion
Solar cells. Photoelectrochemical cells
Solar energy
Transfer matrix formalism
title Optimization of thickness and morphology of active layer for high performance of bulk-heterojunction organic solar cells
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