Superconductivity in diamond

We survey methods of synthesis of boron doped diamond with high pressure-high temperature techniques. New route is proposed for synthesis of relatively large heavily boron doped diamond single crystals, which exhibit superconductivity. Superconducting boron-doped diamond samples were synthesized wit...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Diamond and related materials 2010-05, Vol.19 (5), p.351-357
Hauptverfasser: Sidorov, V.A., Ekimov, E.A.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 357
container_issue 5
container_start_page 351
container_title Diamond and related materials
container_volume 19
creator Sidorov, V.A.
Ekimov, E.A.
description We survey methods of synthesis of boron doped diamond with high pressure-high temperature techniques. New route is proposed for synthesis of relatively large heavily boron doped diamond single crystals, which exhibit superconductivity. Superconducting boron-doped diamond samples were synthesized with isotopes of 10B, 11B, 13C and 12C. We claim the presence of a carbon isotope effect on the superconducting transition temperature, which supports the “diamond–carbon”-related nature of superconductivity and the importance of the electron–phonon interaction as the mechanism of superconductivity in diamond. Isotope substitution permits us to relate almost all bands in the Raman spectra of heavily boron-doped diamond to the vibrations of carbon atoms. The 500 cm − 1 Raman band shifts with either carbon or boron isotope substitution and may be associated with vibrations of paired or clustered boron.
doi_str_mv 10.1016/j.diamond.2009.12.002
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_753749983</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0925963509003495</els_id><sourcerecordid>753749983</sourcerecordid><originalsourceid>FETCH-LOGICAL-c341t-6635de47044c3ddd774760b42e13752fc6d9ab2ffaf1d7095c1818fe9f97c0283</originalsourceid><addsrcrecordid>eNqFkMFLwzAUxoMoWKf_gcJunlrfS9KmOYkMp8LAg3oOXfICGVtbk3aw_96O7e7pXb7fj-99jD0gFAhYPW0KF5pd17qCA-gCeQHAL1iGtdI5QMUvWQaal7muRHnNblLaACDXEjN2_zX2FO0Ej3YI-zAc5qGdn3237Mo320R35ztjP8vX78V7vvp8-1i8rHIrJA55NWkdSQVSWuGcU0qqCtaSEwpVcm8rp5s1977x6BTo0mKNtSfttbLAazFjjydvH7vfkdJgdiFZ2m6blroxGVUKJbWuxZQsT0kbu5QiedPHsGviwSCY4xhmY87lzXEMg9xMY0zc84mj6Y19oGiSDdRaciGSHYzrwj-GP-CvaXo</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>753749983</pqid></control><display><type>article</type><title>Superconductivity in diamond</title><source>Elsevier ScienceDirect Journals</source><creator>Sidorov, V.A. ; Ekimov, E.A.</creator><creatorcontrib>Sidorov, V.A. ; Ekimov, E.A.</creatorcontrib><description>We survey methods of synthesis of boron doped diamond with high pressure-high temperature techniques. New route is proposed for synthesis of relatively large heavily boron doped diamond single crystals, which exhibit superconductivity. Superconducting boron-doped diamond samples were synthesized with isotopes of 10B, 11B, 13C and 12C. We claim the presence of a carbon isotope effect on the superconducting transition temperature, which supports the “diamond–carbon”-related nature of superconductivity and the importance of the electron–phonon interaction as the mechanism of superconductivity in diamond. Isotope substitution permits us to relate almost all bands in the Raman spectra of heavily boron-doped diamond to the vibrations of carbon atoms. The 500 cm − 1 Raman band shifts with either carbon or boron isotope substitution and may be associated with vibrations of paired or clustered boron.</description><identifier>ISSN: 0925-9635</identifier><identifier>EISSN: 1879-0062</identifier><identifier>DOI: 10.1016/j.diamond.2009.12.002</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Bands ; Boron ; Boron-doped diamond ; Carbon ; Isotope effect ; Isotopes ; Raman spectroscopy ; Single crystal ; Superconductivity ; Synthesis ; Transition temperature ; Vibration</subject><ispartof>Diamond and related materials, 2010-05, Vol.19 (5), p.351-357</ispartof><rights>2009 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c341t-6635de47044c3ddd774760b42e13752fc6d9ab2ffaf1d7095c1818fe9f97c0283</citedby><cites>FETCH-LOGICAL-c341t-6635de47044c3ddd774760b42e13752fc6d9ab2ffaf1d7095c1818fe9f97c0283</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0925963509003495$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Sidorov, V.A.</creatorcontrib><creatorcontrib>Ekimov, E.A.</creatorcontrib><title>Superconductivity in diamond</title><title>Diamond and related materials</title><description>We survey methods of synthesis of boron doped diamond with high pressure-high temperature techniques. New route is proposed for synthesis of relatively large heavily boron doped diamond single crystals, which exhibit superconductivity. Superconducting boron-doped diamond samples were synthesized with isotopes of 10B, 11B, 13C and 12C. We claim the presence of a carbon isotope effect on the superconducting transition temperature, which supports the “diamond–carbon”-related nature of superconductivity and the importance of the electron–phonon interaction as the mechanism of superconductivity in diamond. Isotope substitution permits us to relate almost all bands in the Raman spectra of heavily boron-doped diamond to the vibrations of carbon atoms. The 500 cm − 1 Raman band shifts with either carbon or boron isotope substitution and may be associated with vibrations of paired or clustered boron.</description><subject>Bands</subject><subject>Boron</subject><subject>Boron-doped diamond</subject><subject>Carbon</subject><subject>Isotope effect</subject><subject>Isotopes</subject><subject>Raman spectroscopy</subject><subject>Single crystal</subject><subject>Superconductivity</subject><subject>Synthesis</subject><subject>Transition temperature</subject><subject>Vibration</subject><issn>0925-9635</issn><issn>1879-0062</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqFkMFLwzAUxoMoWKf_gcJunlrfS9KmOYkMp8LAg3oOXfICGVtbk3aw_96O7e7pXb7fj-99jD0gFAhYPW0KF5pd17qCA-gCeQHAL1iGtdI5QMUvWQaal7muRHnNblLaACDXEjN2_zX2FO0Ej3YI-zAc5qGdn3237Mo320R35ztjP8vX78V7vvp8-1i8rHIrJA55NWkdSQVSWuGcU0qqCtaSEwpVcm8rp5s1977x6BTo0mKNtSfttbLAazFjjydvH7vfkdJgdiFZ2m6blroxGVUKJbWuxZQsT0kbu5QiedPHsGviwSCY4xhmY87lzXEMg9xMY0zc84mj6Y19oGiSDdRaciGSHYzrwj-GP-CvaXo</recordid><startdate>20100501</startdate><enddate>20100501</enddate><creator>Sidorov, V.A.</creator><creator>Ekimov, E.A.</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20100501</creationdate><title>Superconductivity in diamond</title><author>Sidorov, V.A. ; Ekimov, E.A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c341t-6635de47044c3ddd774760b42e13752fc6d9ab2ffaf1d7095c1818fe9f97c0283</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Bands</topic><topic>Boron</topic><topic>Boron-doped diamond</topic><topic>Carbon</topic><topic>Isotope effect</topic><topic>Isotopes</topic><topic>Raman spectroscopy</topic><topic>Single crystal</topic><topic>Superconductivity</topic><topic>Synthesis</topic><topic>Transition temperature</topic><topic>Vibration</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sidorov, V.A.</creatorcontrib><creatorcontrib>Ekimov, E.A.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Diamond and related materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sidorov, V.A.</au><au>Ekimov, E.A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Superconductivity in diamond</atitle><jtitle>Diamond and related materials</jtitle><date>2010-05-01</date><risdate>2010</risdate><volume>19</volume><issue>5</issue><spage>351</spage><epage>357</epage><pages>351-357</pages><issn>0925-9635</issn><eissn>1879-0062</eissn><abstract>We survey methods of synthesis of boron doped diamond with high pressure-high temperature techniques. New route is proposed for synthesis of relatively large heavily boron doped diamond single crystals, which exhibit superconductivity. Superconducting boron-doped diamond samples were synthesized with isotopes of 10B, 11B, 13C and 12C. We claim the presence of a carbon isotope effect on the superconducting transition temperature, which supports the “diamond–carbon”-related nature of superconductivity and the importance of the electron–phonon interaction as the mechanism of superconductivity in diamond. Isotope substitution permits us to relate almost all bands in the Raman spectra of heavily boron-doped diamond to the vibrations of carbon atoms. The 500 cm − 1 Raman band shifts with either carbon or boron isotope substitution and may be associated with vibrations of paired or clustered boron.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.diamond.2009.12.002</doi><tpages>7</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0925-9635
ispartof Diamond and related materials, 2010-05, Vol.19 (5), p.351-357
issn 0925-9635
1879-0062
language eng
recordid cdi_proquest_miscellaneous_753749983
source Elsevier ScienceDirect Journals
subjects Bands
Boron
Boron-doped diamond
Carbon
Isotope effect
Isotopes
Raman spectroscopy
Single crystal
Superconductivity
Synthesis
Transition temperature
Vibration
title Superconductivity in diamond
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-04T16%3A08%3A58IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Superconductivity%20in%20diamond&rft.jtitle=Diamond%20and%20related%20materials&rft.au=Sidorov,%20V.A.&rft.date=2010-05-01&rft.volume=19&rft.issue=5&rft.spage=351&rft.epage=357&rft.pages=351-357&rft.issn=0925-9635&rft.eissn=1879-0062&rft_id=info:doi/10.1016/j.diamond.2009.12.002&rft_dat=%3Cproquest_cross%3E753749983%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=753749983&rft_id=info:pmid/&rft_els_id=S0925963509003495&rfr_iscdi=true