High-sensitivity and high-resolution low-energy ion scattering

Low-Energy Ion Scattering (LEIS or ISS) is used to selectively analyze the atomic composition of the outer atomic layer of surfaces. In addition, the spectrum gives (non-destructively) the in-depth distribution. Using a double toroidal energy analyzer with parallel energy detection and time-of-fligh...

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Veröffentlicht in:Vacuum 2010-03, Vol.84 (8), p.1005-1007
Hauptverfasser: Brongersma, Hidde H., Grehl, Thomas, van Hal, Paul A., Kuijpers, Niels C.W., Mathijssen, Simon G.J., Schofield, Emma R., Smith, Richard A.P., ter Veen, Hendrik R.J.
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container_end_page 1007
container_issue 8
container_start_page 1005
container_title Vacuum
container_volume 84
creator Brongersma, Hidde H.
Grehl, Thomas
van Hal, Paul A.
Kuijpers, Niels C.W.
Mathijssen, Simon G.J.
Schofield, Emma R.
Smith, Richard A.P.
ter Veen, Hendrik R.J.
description Low-Energy Ion Scattering (LEIS or ISS) is used to selectively analyze the atomic composition of the outer atomic layer of surfaces. In addition, the spectrum gives (non-destructively) the in-depth distribution. Using a double toroidal energy analyzer with parallel energy detection and time-of-flight filtering a high sensitivity and mass resolution of LEIS is achieved. This is demonstrated for a highly dispersed catalyst of Pt/Au on γ-alumina. The improved depth resolution is illustrated for self-assembled monolayers of alkanethiols (12–20 carbon atoms) on gold. Even for these low Z carbon atoms a clear shift of 8 eV/carbon atom is observed (using 1.5 keV 4He + ion scattering). This opens many new possibilities for studies of ultra-thin diffusion barriers, high-k dielectrics and biosensors.
doi_str_mv 10.1016/j.vacuum.2009.11.016
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source Elsevier ScienceDirect Journals
subjects Carbon
Depth resolution
Diffusion barriers
Energy use
Filtering
Gold
High sensitivity
International Space Station
Ion scattering
LEIS
Low energy ion scattering
Mass resolution
Quantitative
Self-assembled monolayer
title High-sensitivity and high-resolution low-energy ion scattering
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