An unusual cascade reaction of 4,5-dihydro-4,4-bis(trifluoromethyl)-2-phenyl-6,7-(4-chlorobenzo)[ e-1,3,2-dioxaphosphepin-5-one with chloral
The reaction of 4,5-dihydro-4,4-bis(trifluoromethyl)-2-phenyl-6,7-(4-chlorobenzo)[ e-1,3,2-dioxaphosphepin-5-one with chloral (1:2) proceeds with evolving hexafluoroacetone and gives spiro{2-oxo-4-trichloromethyl-4,5-dihydro-2-phenyl-6,7-(4-chlorobe n zo)[f]-1,3,2-dioxaphosphepine-5,2'-(3'...
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| Veröffentlicht in: | Mendeleev communications 2010-02, Vol.20 (1), p.44-4644-46 |
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| container_end_page | 4644-46 |
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| container_issue | 1 |
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| container_title | Mendeleev communications |
| container_volume | 20 |
| creator | Mironov, Vladimir F Borisova, Yuliya Yu Burnaeva, Liliya M Krivolapov, Dmitry B Litvinov, Igor A Zverev, Vladislav V Musin, Rashid Z Konovalova, Irina V |
| description | The reaction of 4,5-dihydro-4,4-bis(trifluoromethyl)-2-phenyl-6,7-(4-chlorobenzo)[ e-1,3,2-dioxaphosphepin-5-one with chloral (1:2) proceeds with evolving hexafluoroacetone and gives spiro{2-oxo-4-trichloromethyl-4,5-dihydro-2-phenyl-6,7-(4-chlorobe n zo)[f]-1,3,2-dioxaphosphepine-5,2'-(3'-trichloromethyl)oxirane} with a high stereoselectivity. Configuration of the four chiral centres (P super(2) sub(S)C super(4) sub(S)C super(5) sub(S)C super(3') sub(S) /P super(2) sub(R)C super(4) sub(R)C super(5) sub(R)C super(3') sub(R)) was determined by a single crystal X-ray diffraction. |
| doi_str_mv | 10.1016/j.mencom.2010.01.017 |
| format | Article |
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| ispartof | Mendeleev communications, 2010-02, Vol.20 (1), p.44-4644-46 |
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| source | Access via ScienceDirect (Elsevier) |
| subjects | Cascades Chloral Diffraction Single crystals Stereoselectivity X-rays |
| title | An unusual cascade reaction of 4,5-dihydro-4,4-bis(trifluoromethyl)-2-phenyl-6,7-(4-chlorobenzo)[ e-1,3,2-dioxaphosphepin-5-one with chloral |
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