In situ growth of copper sulfide nanoparticles on ordered mesoporous carbon and their application as nonenzymatic amperometric sensor of hydrogen peroxide
A simple and facile synthetic method to incorporate copper sulfide (Cu 2S) nanoparticles inside the mesopores of ordered mesoporous carbons (OMCs) is reported. The Cu 2S/OMCs nanocomposite was characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spect...
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| Veröffentlicht in: | Talanta (Oxford) 2010-04, Vol.81 (1), p.339-345 |
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| creator | Bo, Xiangjie Bai, Jing Wang, Lixia Guo, Liping |
| description | A simple and facile synthetic method to incorporate copper sulfide (Cu
2S) nanoparticles inside the mesopores of ordered mesoporous carbons (OMCs) is reported. The Cu
2S/OMCs nanocomposite was characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and nitrogen adsorption–desorption. The results show that the incorporation of Cu
2S nanoparticles inside the pores of OMCs does not change the highly ordered two-dimensional hexagonal mesostructure of OMCs matrix. Nonenzymatic amperometric sensor of hydrogen peroxide based on the Cu
2S/OMCs nanocomposite modified glassy carbon (GC) electrode is developed. Compared with the pristine OMCs modified electrode, the Cu
2S/OMCs modified electrode displays high electrocatalytic activity towards hydrogen peroxide and gives linear range from 1 to 3030
μM (
R
=
0.9986). The sensor also exhibits good ability of anti-interference to electroactive molecules. The combination of the unique properties of Cu
2S nanoparticles and the ordered mesostructure of OMCs matrix guarantee the excellent electrocatalysis for hydrogen peroxide. The good analytical performance and low-cost make Cu
2S/OMC nanocomposite promising for the development of effective sensor for hydrogen peroxide. |
| doi_str_mv | 10.1016/j.talanta.2009.12.007 |
| format | Article |
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2S) nanoparticles inside the mesopores of ordered mesoporous carbons (OMCs) is reported. The Cu
2S/OMCs nanocomposite was characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and nitrogen adsorption–desorption. The results show that the incorporation of Cu
2S nanoparticles inside the pores of OMCs does not change the highly ordered two-dimensional hexagonal mesostructure of OMCs matrix. Nonenzymatic amperometric sensor of hydrogen peroxide based on the Cu
2S/OMCs nanocomposite modified glassy carbon (GC) electrode is developed. Compared with the pristine OMCs modified electrode, the Cu
2S/OMCs modified electrode displays high electrocatalytic activity towards hydrogen peroxide and gives linear range from 1 to 3030
μM (
R
=
0.9986). The sensor also exhibits good ability of anti-interference to electroactive molecules. The combination of the unique properties of Cu
2S nanoparticles and the ordered mesostructure of OMCs matrix guarantee the excellent electrocatalysis for hydrogen peroxide. The good analytical performance and low-cost make Cu
2S/OMC nanocomposite promising for the development of effective sensor for hydrogen peroxide.</description><identifier>ISSN: 0039-9140</identifier><identifier>EISSN: 1873-3573</identifier><identifier>DOI: 10.1016/j.talanta.2009.12.007</identifier><identifier>PMID: 20188929</identifier><identifier>CODEN: TLNTA2</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Analytical chemistry ; Carbon - chemistry ; Catalysis ; Chemistry ; Chemistry Techniques, Analytical - instrumentation ; Chromatographic methods and physical methods associated with chromatography ; COMPOSITES ; Copper - chemistry ; COPPER SULFIDE ; Copper sulfides ; Electrochemical methods ; Electrochemistry ; ELECTRODES ; Exact sciences and technology ; Fluorocarbon Polymers - chemistry ; Gas chromatographic methods ; General, instrumentation ; Glass - chemistry ; HYDROGEN ; HYDROGEN PEROXIDE ; Hydrogen Peroxide - analysis ; Hydrogen Peroxide - chemistry ; In situ growth ; MICROSTRUCTURES ; Nanocomposites ; Nanocomposites - chemistry ; Nanomaterials ; Nanoparticles ; Nanoparticles - chemistry ; Nanostructure ; Nonenzymatic sensor ; Ordered mesoporous carbon ; Oxidation-Reduction ; OXIDES ; PARTICLES ; POROSITY ; Reproducibility of Results ; Sensors ; Spectrometric and optical methods ; SULFIDES ; Sulfides - chemistry</subject><ispartof>Talanta (Oxford), 2010-04, Vol.81 (1), p.339-345</ispartof><rights>2009 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><rights>(c) 2009 Elsevier B.V. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c426t-8a17f89013a31b12cf34ede8b045e2a9dec5a044483bb33b38bc427485f89f4b3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.talanta.2009.12.007$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3548,27922,27923,45993</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22559902$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/20188929$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Bo, Xiangjie</creatorcontrib><creatorcontrib>Bai, Jing</creatorcontrib><creatorcontrib>Wang, Lixia</creatorcontrib><creatorcontrib>Guo, Liping</creatorcontrib><title>In situ growth of copper sulfide nanoparticles on ordered mesoporous carbon and their application as nonenzymatic amperometric sensor of hydrogen peroxide</title><title>Talanta (Oxford)</title><addtitle>Talanta</addtitle><description>A simple and facile synthetic method to incorporate copper sulfide (Cu
2S) nanoparticles inside the mesopores of ordered mesoporous carbons (OMCs) is reported. The Cu
2S/OMCs nanocomposite was characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and nitrogen adsorption–desorption. The results show that the incorporation of Cu
2S nanoparticles inside the pores of OMCs does not change the highly ordered two-dimensional hexagonal mesostructure of OMCs matrix. Nonenzymatic amperometric sensor of hydrogen peroxide based on the Cu
2S/OMCs nanocomposite modified glassy carbon (GC) electrode is developed. Compared with the pristine OMCs modified electrode, the Cu
2S/OMCs modified electrode displays high electrocatalytic activity towards hydrogen peroxide and gives linear range from 1 to 3030
μM (
R
=
0.9986). The sensor also exhibits good ability of anti-interference to electroactive molecules. The combination of the unique properties of Cu
2S nanoparticles and the ordered mesostructure of OMCs matrix guarantee the excellent electrocatalysis for hydrogen peroxide. The good analytical performance and low-cost make Cu
2S/OMC nanocomposite promising for the development of effective sensor for hydrogen peroxide.</description><subject>Analytical chemistry</subject><subject>Carbon - chemistry</subject><subject>Catalysis</subject><subject>Chemistry</subject><subject>Chemistry Techniques, Analytical - instrumentation</subject><subject>Chromatographic methods and physical methods associated with chromatography</subject><subject>COMPOSITES</subject><subject>Copper - chemistry</subject><subject>COPPER SULFIDE</subject><subject>Copper sulfides</subject><subject>Electrochemical methods</subject><subject>Electrochemistry</subject><subject>ELECTRODES</subject><subject>Exact sciences and technology</subject><subject>Fluorocarbon Polymers - chemistry</subject><subject>Gas chromatographic methods</subject><subject>General, instrumentation</subject><subject>Glass - chemistry</subject><subject>HYDROGEN</subject><subject>HYDROGEN PEROXIDE</subject><subject>Hydrogen Peroxide - analysis</subject><subject>Hydrogen Peroxide - chemistry</subject><subject>In situ growth</subject><subject>MICROSTRUCTURES</subject><subject>Nanocomposites</subject><subject>Nanocomposites - chemistry</subject><subject>Nanomaterials</subject><subject>Nanoparticles</subject><subject>Nanoparticles - chemistry</subject><subject>Nanostructure</subject><subject>Nonenzymatic sensor</subject><subject>Ordered mesoporous carbon</subject><subject>Oxidation-Reduction</subject><subject>OXIDES</subject><subject>PARTICLES</subject><subject>POROSITY</subject><subject>Reproducibility of Results</subject><subject>Sensors</subject><subject>Spectrometric and optical methods</subject><subject>SULFIDES</subject><subject>Sulfides - chemistry</subject><issn>0039-9140</issn><issn>1873-3573</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkctu1DAUhi0EotPCI4C8QawSfJ3EK4QqKJUqsYG15dgnHY8SO9geyvAoPC2OZoBlV5bP-f5z-xF6RUlLCd2-27fFTCYU0zJCVEtZS0j3BG1o3_GGy44_RRtCuGoUFeQCXea8J4QwTvhzdMEI7XvF1Ab9vg04-3LA9yk-lB2OI7ZxWSDhfJhG7wAHE-JiUvF2goxjwDE5SODwDDkuMcVDxtakoWZMcLjswCdslmXy1hS_RjMOMUD4dZxrwGIz1_JxhpLqJ0PIMa1td0eX4j0EvGZ_1s4v0LPRTBlent8r9O3Tx6_Xn5u7Lze31x_uGivYtjS9od3YK0K54XSgzI5cgIN-IEICM8qBlYYIIXo-DJwPvB-qsBO9rKpRDPwKvT3VXVL8foBc9OyzhaleF-pyupO8451S7HGScyn4VshKyhNpU8w5waiX5GeTjpoSvfqn9_rsn17905Tp6l_VvT53OAwzuH-qv4ZV4M0ZMNmaaUwmWJ__c0xKpcg66vsTB_VyPzwkna2HYMH5BLZoF_0jo_wBDdS_wg</recordid><startdate>20100415</startdate><enddate>20100415</enddate><creator>Bo, Xiangjie</creator><creator>Bai, Jing</creator><creator>Wang, Lixia</creator><creator>Guo, Liping</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7QQ</scope><scope>7SR</scope><scope>8FD</scope><scope>H8G</scope><scope>JG9</scope></search><sort><creationdate>20100415</creationdate><title>In situ growth of copper sulfide nanoparticles on ordered mesoporous carbon and their application as nonenzymatic amperometric sensor of hydrogen peroxide</title><author>Bo, Xiangjie ; Bai, Jing ; Wang, Lixia ; Guo, Liping</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c426t-8a17f89013a31b12cf34ede8b045e2a9dec5a044483bb33b38bc427485f89f4b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Analytical chemistry</topic><topic>Carbon - chemistry</topic><topic>Catalysis</topic><topic>Chemistry</topic><topic>Chemistry Techniques, Analytical - instrumentation</topic><topic>Chromatographic methods and physical methods associated with chromatography</topic><topic>COMPOSITES</topic><topic>Copper - chemistry</topic><topic>COPPER SULFIDE</topic><topic>Copper sulfides</topic><topic>Electrochemical methods</topic><topic>Electrochemistry</topic><topic>ELECTRODES</topic><topic>Exact sciences and technology</topic><topic>Fluorocarbon Polymers - chemistry</topic><topic>Gas chromatographic methods</topic><topic>General, instrumentation</topic><topic>Glass - chemistry</topic><topic>HYDROGEN</topic><topic>HYDROGEN PEROXIDE</topic><topic>Hydrogen Peroxide - analysis</topic><topic>Hydrogen Peroxide - chemistry</topic><topic>In situ growth</topic><topic>MICROSTRUCTURES</topic><topic>Nanocomposites</topic><topic>Nanocomposites - chemistry</topic><topic>Nanomaterials</topic><topic>Nanoparticles</topic><topic>Nanoparticles - chemistry</topic><topic>Nanostructure</topic><topic>Nonenzymatic sensor</topic><topic>Ordered mesoporous carbon</topic><topic>Oxidation-Reduction</topic><topic>OXIDES</topic><topic>PARTICLES</topic><topic>POROSITY</topic><topic>Reproducibility of Results</topic><topic>Sensors</topic><topic>Spectrometric and optical methods</topic><topic>SULFIDES</topic><topic>Sulfides - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bo, Xiangjie</creatorcontrib><creatorcontrib>Bai, Jing</creatorcontrib><creatorcontrib>Wang, Lixia</creatorcontrib><creatorcontrib>Guo, Liping</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><jtitle>Talanta (Oxford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bo, Xiangjie</au><au>Bai, Jing</au><au>Wang, Lixia</au><au>Guo, Liping</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>In situ growth of copper sulfide nanoparticles on ordered mesoporous carbon and their application as nonenzymatic amperometric sensor of hydrogen peroxide</atitle><jtitle>Talanta (Oxford)</jtitle><addtitle>Talanta</addtitle><date>2010-04-15</date><risdate>2010</risdate><volume>81</volume><issue>1</issue><spage>339</spage><epage>345</epage><pages>339-345</pages><issn>0039-9140</issn><eissn>1873-3573</eissn><coden>TLNTA2</coden><abstract>A simple and facile synthetic method to incorporate copper sulfide (Cu
2S) nanoparticles inside the mesopores of ordered mesoporous carbons (OMCs) is reported. The Cu
2S/OMCs nanocomposite was characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and nitrogen adsorption–desorption. The results show that the incorporation of Cu
2S nanoparticles inside the pores of OMCs does not change the highly ordered two-dimensional hexagonal mesostructure of OMCs matrix. Nonenzymatic amperometric sensor of hydrogen peroxide based on the Cu
2S/OMCs nanocomposite modified glassy carbon (GC) electrode is developed. Compared with the pristine OMCs modified electrode, the Cu
2S/OMCs modified electrode displays high electrocatalytic activity towards hydrogen peroxide and gives linear range from 1 to 3030
μM (
R
=
0.9986). The sensor also exhibits good ability of anti-interference to electroactive molecules. The combination of the unique properties of Cu
2S nanoparticles and the ordered mesostructure of OMCs matrix guarantee the excellent electrocatalysis for hydrogen peroxide. The good analytical performance and low-cost make Cu
2S/OMC nanocomposite promising for the development of effective sensor for hydrogen peroxide.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><pmid>20188929</pmid><doi>10.1016/j.talanta.2009.12.007</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0039-9140 |
| ispartof | Talanta (Oxford), 2010-04, Vol.81 (1), p.339-345 |
| issn | 0039-9140 1873-3573 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_753737992 |
| source | MEDLINE; ScienceDirect Journals (5 years ago - present) |
| subjects | Analytical chemistry Carbon - chemistry Catalysis Chemistry Chemistry Techniques, Analytical - instrumentation Chromatographic methods and physical methods associated with chromatography COMPOSITES Copper - chemistry COPPER SULFIDE Copper sulfides Electrochemical methods Electrochemistry ELECTRODES Exact sciences and technology Fluorocarbon Polymers - chemistry Gas chromatographic methods General, instrumentation Glass - chemistry HYDROGEN HYDROGEN PEROXIDE Hydrogen Peroxide - analysis Hydrogen Peroxide - chemistry In situ growth MICROSTRUCTURES Nanocomposites Nanocomposites - chemistry Nanomaterials Nanoparticles Nanoparticles - chemistry Nanostructure Nonenzymatic sensor Ordered mesoporous carbon Oxidation-Reduction OXIDES PARTICLES POROSITY Reproducibility of Results Sensors Spectrometric and optical methods SULFIDES Sulfides - chemistry |
| title | In situ growth of copper sulfide nanoparticles on ordered mesoporous carbon and their application as nonenzymatic amperometric sensor of hydrogen peroxide |
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