Formation Process and Microwave Dielectric Properties of the R2V2O7 (R=Ba, Sr, and Ca) Ceramics

Formation process and microwave dielectric properties of the R2V2O7 (R=Ba, Sr, and Ca) ceramics were investigated. Transient RV2O6 phases, which were formed at 300°∼500°C by the reaction of RCO3 and V2O5, interacted with remnant RCO3 to form the homogeneous triclinic R2V2O7 phases at 600°–700°C. The...

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Veröffentlicht in:Journal of the American Ceramic Society 2009-12, Vol.92 (12), p.3092-3094
Hauptverfasser: Joung, Mi-Ri, Kim, Jin-Seong, Song, Myung-Eun, Nahm, Sahn, Paik, Jong-Hoo
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container_end_page 3094
container_issue 12
container_start_page 3092
container_title Journal of the American Ceramic Society
container_volume 92
creator Joung, Mi-Ri
Kim, Jin-Seong
Song, Myung-Eun
Nahm, Sahn
Paik, Jong-Hoo
description Formation process and microwave dielectric properties of the R2V2O7 (R=Ba, Sr, and Ca) ceramics were investigated. Transient RV2O6 phases, which were formed at 300°∼500°C by the reaction of RCO3 and V2O5, interacted with remnant RCO3 to form the homogeneous triclinic R2V2O7 phases at 600°–700°C. The Sr2V2O7 and Ca2V2O7 ceramics sintered at 1000° and 950°C, respectively, for 10 h showed a dense microstructure with the microwave dielectric properties of ɛr=10.4–12.1, Q×f=15 200–19 520 GHz, and τf=−30.9–34.8 ppm/°C. However, the Ba2V2O7 ceramic was well sintered at 900°C for 10 h and it showed the good microwave dielectric properties of ɛr=10.1, Q×f=51 630 GHz, and τf=−26.5 ppm/°C.
doi_str_mv 10.1111/j.1551-2916.2009.03324.x
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subjects Ceramics
Dielectric properties
Microstructure
Microwaves
Phases
Sintering
Strontium
Vanadium pentoxide
title Formation Process and Microwave Dielectric Properties of the R2V2O7 (R=Ba, Sr, and Ca) Ceramics
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