Vermiculite-aliphatic amine interactions at the solid/liquid interface: a thermodynamic approach
Polar n -alkylmonoamines of general formula H 3 C(CH 2 ) n NH 2 ( n = 1, 3, 5) interacted with layered silicate vermiculite at the solid/liquid interface. The maximum amount of amine intercalated ( N f ) inside the interlamellar space were 0.62, 0.46, and 0.38 mmol g −1 , to give the following orde...
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| Veröffentlicht in: | Journal of thermal analysis and calorimetry 2009-08, Vol.97 (2), p.453-457 |
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| container_title | Journal of thermal analysis and calorimetry |
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| creator | da Fonseca, Maria G. Almeida, Ramon K. S. Wanderley, Albaneide F. Ferreira, Ulysses V. S. Arakaki, Luiza N. H. Simoni, José A. Airoldi, Claudio |
| description | Polar
n
-alkylmonoamines of general formula H
3
C(CH
2
)
n
NH
2
(
n
= 1, 3, 5) interacted with layered silicate vermiculite at the solid/liquid interface. The maximum amount of amine intercalated (
N
f
) inside the interlamellar space were 0.62, 0.46, and 0.38 mmol g
−1
, to give the following order of intercalation ethyl → butyl → hexylamines. The layered vermiculite solid was suspended in deionized water and calorimetrically titrated with this series of amines, to give favorable thermodynamic data, such as exothermic enthalpy, negative Gibbs free energy and positive entropy data. |
| doi_str_mv | 10.1007/s10973-009-0220-3 |
| format | Article |
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n
-alkylmonoamines of general formula H
3
C(CH
2
)
n
NH
2
(
n
= 1, 3, 5) interacted with layered silicate vermiculite at the solid/liquid interface. The maximum amount of amine intercalated (
N
f
) inside the interlamellar space were 0.62, 0.46, and 0.38 mmol g
−1
, to give the following order of intercalation ethyl → butyl → hexylamines. The layered vermiculite solid was suspended in deionized water and calorimetrically titrated with this series of amines, to give favorable thermodynamic data, such as exothermic enthalpy, negative Gibbs free energy and positive entropy data.</description><identifier>ISSN: 1388-6150</identifier><identifier>EISSN: 1588-2926</identifier><identifier>EISSN: 1572-8943</identifier><identifier>DOI: 10.1007/s10973-009-0220-3</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Amines ; Analytical Chemistry ; Calorimetry ; Chemistry ; Chemistry and Materials Science ; Deionization ; Entropy ; Exact sciences and technology ; General and physical chemistry ; Inorganic Chemistry ; Liquids ; Measurement Science and Instrumentation ; Physical Chemistry ; Polymer Sciences ; Silicates ; Solid-liquid interface ; Surface physical chemistry ; Thermodynamics ; Vermiculite</subject><ispartof>Journal of thermal analysis and calorimetry, 2009-08, Vol.97 (2), p.453-457</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2009</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c350t-8245766886c9e9bdb03df1af37a9552b61017f1ed5e4bf748f2b6dd4f6f91fe53</citedby><cites>FETCH-LOGICAL-c350t-8245766886c9e9bdb03df1af37a9552b61017f1ed5e4bf748f2b6dd4f6f91fe53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10973-009-0220-3$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10973-009-0220-3$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22075504$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>da Fonseca, Maria G.</creatorcontrib><creatorcontrib>Almeida, Ramon K. S.</creatorcontrib><creatorcontrib>Wanderley, Albaneide F.</creatorcontrib><creatorcontrib>Ferreira, Ulysses V. S.</creatorcontrib><creatorcontrib>Arakaki, Luiza N. H.</creatorcontrib><creatorcontrib>Simoni, José A.</creatorcontrib><creatorcontrib>Airoldi, Claudio</creatorcontrib><title>Vermiculite-aliphatic amine interactions at the solid/liquid interface: a thermodynamic approach</title><title>Journal of thermal analysis and calorimetry</title><addtitle>J Therm Anal Calorim</addtitle><description>Polar
n
-alkylmonoamines of general formula H
3
C(CH
2
)
n
NH
2
(
n
= 1, 3, 5) interacted with layered silicate vermiculite at the solid/liquid interface. The maximum amount of amine intercalated (
N
f
) inside the interlamellar space were 0.62, 0.46, and 0.38 mmol g
−1
, to give the following order of intercalation ethyl → butyl → hexylamines. The layered vermiculite solid was suspended in deionized water and calorimetrically titrated with this series of amines, to give favorable thermodynamic data, such as exothermic enthalpy, negative Gibbs free energy and positive entropy data.</description><subject>Amines</subject><subject>Analytical Chemistry</subject><subject>Calorimetry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Deionization</subject><subject>Entropy</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Inorganic Chemistry</subject><subject>Liquids</subject><subject>Measurement Science and Instrumentation</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Silicates</subject><subject>Solid-liquid interface</subject><subject>Surface physical chemistry</subject><subject>Thermodynamics</subject><subject>Vermiculite</subject><issn>1388-6150</issn><issn>1588-2926</issn><issn>1572-8943</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNp9kD1PwzAQhiMEElXpD2DLgphM7Ti2YzZU8SVVYgFW4zhnapSv2s7Qf4-rVIxMd7p73vd0b5ZdE3xHMBbrQLAUFGEsES4KjOhZtiCsqlAhC36eepp6Thi-zFYhuBoXBHPJKrnIvj7Bd85MrYuAdOvGnY7O5LpzPeSuj-C1iW7oQ65jHneQh6F1zbp1-8k1M2C1gftcH7e-G5pDn8TJYRz9oM3uKruwug2wOtVl9vH0-L55Qdu359fNwxYZynBEVVEywXlVcSNB1k2NaWOJtlRoyVhRc4KJsAQaBmVtRVnZNGua0nIriQVGl9nt7JvO7icIUXUuGGhb3cMwBSUY5ZISKhJJZtL4IQQPVo3eddofFMHqmKea81QpT3XMU9GkuTm562B0a73ujQt_wgQJxnCZuGLmQlr13-DVzzD5Pj3-j_kvNw6Gog</recordid><startdate>20090801</startdate><enddate>20090801</enddate><creator>da Fonseca, Maria G.</creator><creator>Almeida, Ramon K. S.</creator><creator>Wanderley, Albaneide F.</creator><creator>Ferreira, Ulysses V. S.</creator><creator>Arakaki, Luiza N. H.</creator><creator>Simoni, José A.</creator><creator>Airoldi, Claudio</creator><general>Springer Netherlands</general><general>Springer</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20090801</creationdate><title>Vermiculite-aliphatic amine interactions at the solid/liquid interface: a thermodynamic approach</title><author>da Fonseca, Maria G. ; Almeida, Ramon K. S. ; Wanderley, Albaneide F. ; Ferreira, Ulysses V. S. ; Arakaki, Luiza N. H. ; Simoni, José A. ; Airoldi, Claudio</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c350t-8245766886c9e9bdb03df1af37a9552b61017f1ed5e4bf748f2b6dd4f6f91fe53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Amines</topic><topic>Analytical Chemistry</topic><topic>Calorimetry</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Deionization</topic><topic>Entropy</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Inorganic Chemistry</topic><topic>Liquids</topic><topic>Measurement Science and Instrumentation</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Silicates</topic><topic>Solid-liquid interface</topic><topic>Surface physical chemistry</topic><topic>Thermodynamics</topic><topic>Vermiculite</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>da Fonseca, Maria G.</creatorcontrib><creatorcontrib>Almeida, Ramon K. S.</creatorcontrib><creatorcontrib>Wanderley, Albaneide F.</creatorcontrib><creatorcontrib>Ferreira, Ulysses V. S.</creatorcontrib><creatorcontrib>Arakaki, Luiza N. H.</creatorcontrib><creatorcontrib>Simoni, José A.</creatorcontrib><creatorcontrib>Airoldi, Claudio</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of thermal analysis and calorimetry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>da Fonseca, Maria G.</au><au>Almeida, Ramon K. S.</au><au>Wanderley, Albaneide F.</au><au>Ferreira, Ulysses V. S.</au><au>Arakaki, Luiza N. H.</au><au>Simoni, José A.</au><au>Airoldi, Claudio</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Vermiculite-aliphatic amine interactions at the solid/liquid interface: a thermodynamic approach</atitle><jtitle>Journal of thermal analysis and calorimetry</jtitle><stitle>J Therm Anal Calorim</stitle><date>2009-08-01</date><risdate>2009</risdate><volume>97</volume><issue>2</issue><spage>453</spage><epage>457</epage><pages>453-457</pages><issn>1388-6150</issn><eissn>1588-2926</eissn><eissn>1572-8943</eissn><abstract>Polar
n
-alkylmonoamines of general formula H
3
C(CH
2
)
n
NH
2
(
n
= 1, 3, 5) interacted with layered silicate vermiculite at the solid/liquid interface. The maximum amount of amine intercalated (
N
f
) inside the interlamellar space were 0.62, 0.46, and 0.38 mmol g
−1
, to give the following order of intercalation ethyl → butyl → hexylamines. The layered vermiculite solid was suspended in deionized water and calorimetrically titrated with this series of amines, to give favorable thermodynamic data, such as exothermic enthalpy, negative Gibbs free energy and positive entropy data.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10973-009-0220-3</doi><tpages>5</tpages></addata></record> |
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| identifier | ISSN: 1388-6150 |
| ispartof | Journal of thermal analysis and calorimetry, 2009-08, Vol.97 (2), p.453-457 |
| issn | 1388-6150 1588-2926 1572-8943 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_753693137 |
| source | Springer Online Journals |
| subjects | Amines Analytical Chemistry Calorimetry Chemistry Chemistry and Materials Science Deionization Entropy Exact sciences and technology General and physical chemistry Inorganic Chemistry Liquids Measurement Science and Instrumentation Physical Chemistry Polymer Sciences Silicates Solid-liquid interface Surface physical chemistry Thermodynamics Vermiculite |
| title | Vermiculite-aliphatic amine interactions at the solid/liquid interface: a thermodynamic approach |
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