Highly Enantioselective Hydrogenation of Quinoline and Pyridine Derivatives with Iridium-(P-Phos) Catalyst

The use of a chiral iridium catalyst generated in situ from the (cyclooctadiene)iridium chloride dimer, [Ir(COD)Cl]2, the P‐Phos ligand [4,4′‐bis(diphenylphosphino)‐2,2′,6,6′‐tetramethoxy‐3,3′‐bipyridine] and iodine (I2) for the asymmetric hydrogenation of 2,6‐substituted quinolines and trisubstitut...

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Veröffentlicht in:	Advanced synthesis & catalysis 2010-04, Vol.352 (6), p.1055-1062
Hauptverfasser:	Tang, Wei-Jun, Tan, Jing, Xu, Li-Jin, Lam, Kim-Hung, Fan, Qing-Hua, Chan, Albert S. C.
Format:	Artikel
Sprache:	eng
Schlagworte:	Additives asymmetric hydrogenation Asymmetry Catalysts Conversion Derivatives Hydrogenation iridium catalysis P-Phos Pyridines Quinoline quinolines
Online-Zugang:	Volltext
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