Asymmetric allylic alkylation in supercritical carbon dioxide using P-chiral diamidophosphite ligands

P*-Chiral diamidophosphite ligands in the Pd-catalyzed allylic alkylation of ( E)-1,3-diphenylallyl acetate in supercritical carbon dioxide provide enantioselectivities up to 90% ee. The catalytic performance is affected greatly by temperature, CO 2 pressures and structure of catalysts.

Bibliographische Detailangaben

Veröffentlicht in:	Mendeleev communications 2010-05, Vol.20 (3), p.143-144
Hauptverfasser:	Lyubimov, Sergey E., Kuchurov, Ilya V., Vasil’ev, Andrei A., Zlotin, Sergei G., Davankov, Vadim A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetates Alkylation Asymmetry Carbon dioxide Catalysis Catalysts Ligands Palladium
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!