Asymmetric allylic alkylation in supercritical carbon dioxide using P-chiral diamidophosphite ligands

P*-Chiral diamidophosphite ligands in the Pd-catalyzed allylic alkylation of ( E)-1,3-diphenylallyl acetate in supercritical carbon dioxide provide enantioselectivities up to 90% ee. The catalytic performance is affected greatly by temperature, CO 2 pressures and structure of catalysts.

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Veröffentlicht in:	Mendeleev communications 2010-05, Vol.20 (3), p.143-144
Hauptverfasser:	Lyubimov, Sergey E., Kuchurov, Ilya V., Vasil’ev, Andrei A., Zlotin, Sergei G., Davankov, Vadim A.
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Sprache:	eng
Schlagworte:	Acetates Alkylation Asymmetry Carbon dioxide Catalysis Catalysts Ligands Palladium
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creator	Lyubimov, Sergey E. Kuchurov, Ilya V. Vasil’ev, Andrei A. Zlotin, Sergei G. Davankov, Vadim A.
description	P*-Chiral diamidophosphite ligands in the Pd-catalyzed allylic alkylation of ( E)-1,3-diphenylallyl acetate in supercritical carbon dioxide provide enantioselectivities up to 90% ee. The catalytic performance is affected greatly by temperature, CO 2 pressures and structure of catalysts.
doi_str_mv	10.1016/j.mencom.2010.05.006
format	Article
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subjects	Acetates Alkylation Asymmetry Carbon dioxide Catalysis Catalysts Ligands Palladium
title	Asymmetric allylic alkylation in supercritical carbon dioxide using P-chiral diamidophosphite ligands
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