The effect of anchoring group number on the performance of dye-sensitized solar cells

Novel dyes comprising a triphenylamine donor, thiophene conjugated bridge and different numbers of anchor groups (cyanoacrylic acid acceptor) were synthesized and employed as photosensitizers in dye-sensitized solar cells. The absorbance of the dyes in solution was red shifted and the first oxidatio...

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Veröffentlicht in:Dyes and pigments 2010-11, Vol.87 (3), p.249-256
Hauptverfasser: Shang, Huixia, Luo, Yanhong, Guo, Xiaozhi, Huang, Xiaoming, Zhan, Xiaowei, Jiang, Kejian, Meng, Qingbo
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container_end_page 256
container_issue 3
container_start_page 249
container_title Dyes and pigments
container_volume 87
creator Shang, Huixia
Luo, Yanhong
Guo, Xiaozhi
Huang, Xiaoming
Zhan, Xiaowei
Jiang, Kejian
Meng, Qingbo
description Novel dyes comprising a triphenylamine donor, thiophene conjugated bridge and different numbers of anchor groups (cyanoacrylic acid acceptor) were synthesized and employed as photosensitizers in dye-sensitized solar cells. The absorbance of the dyes in solution was red shifted and the first oxidation potential decreased with increasing butoxy group:anchor group ratio. Solar cells based on the dyes exhibited energy conversion efficiencies of 6.7–7.4% at 100 mW cm −2. Increasing butoxy group:anchor group ratio resulted in higher open-circuit voltage and higher efficiency.
doi_str_mv 10.1016/j.dyepig.2010.03.034
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source Elsevier ScienceDirect Journals
subjects Anchoring
Dye-sensitized solar cell
Dyes
Effect of anchoring group number
Electric potential
Energy conversion efficiency
Organic dye
Photovoltaic cells
Solar cells
Structure–property relationship
Synthesis
Thiophenes
Triphenylamine
Voltage
title The effect of anchoring group number on the performance of dye-sensitized solar cells
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